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NICKELOCENE

Product Name
NICKELOCENE
CAS No.
1271-28-9
Chemical Name
NICKELOCENE
Synonyms
Nickelocene,99%;BIS(CYCLOPENTADIENYL)NICKEL;di(cyclopenta-1,3-dien-1-yl)nickel;bis(B7;Nikelocen;NICKELOCENE;Nickelocene>Nickelocene(NiCp2);nickelbiscyclopentadiene;DI(CYCLOPENTADIENYL)NICKEL
CBNumber
CB9136861
Molecular Formula
C10H10Ni10*
Formula Weight
188.88
MOL File
1271-28-9.mol
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NICKELOCENE Property

Melting point:
171-173 °C(lit.)
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
crystal
color 
dark green
Sensitive 
Air & Moisture Sensitive
CAS DataBase Reference
1271-28-9(CAS DataBase Reference)
NIST Chemistry Reference
Nickelocene(1271-28-9)
EPA Substance Registry System
Nickelocene (1271-28-9)
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Safety

Hazard Codes 
F,T
Risk Statements 
49-11-22-43
Safety Statements 
53-36/37/39-45
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
RTECS 
QR6500000
F 
10-23
TSCA 
Yes
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090
Toxicity
mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H302Harmful if swallowed

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
N7524
Product name
Bis(cyclopentadienyl)nickel(II)
Packaging
5g
Price
$71.6
Updated
2024/03/01
TCI Chemical
Product number
D1574
Product name
Nickelocene
Purity
>98.0%(T)
Packaging
1g
Price
$52
Updated
2024/03/01
TCI Chemical
Product number
D1574
Product name
Nickelocene
Purity
>98.0%(T)
Packaging
5g
Price
$147
Updated
2024/03/01
Alfa Aesar
Product number
087899
Product name
Bis(cyclopentadienyl)nickel, dry
Packaging
2g
Price
$44
Updated
2024/03/01
Alfa Aesar
Product number
087899
Product name
Bis(cyclopentadienyl)nickel, dry
Packaging
50g
Price
$301.65
Updated
2024/03/01
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NICKELOCENE Chemical Properties,Usage,Production

Chemical Properties

GREEN TO DARK GREEN CRYSTALS OR CRYST. POWDER

Chemical Properties

Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.

Uses

Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.

Uses

This metal alkyl may be used to synthesize hybrid organic-inorganic polymeric molecular layer deposition (MLD). Bis(cyclopentadienyl) nickel (Cp 2 Ni) may be used as a Ni precursor for the atomic layer deposition (ALD) of NiO/carbon nanotubes hybrids.

Uses

Catalyst, complexing agent.

General Description

Dark liquid in an 8-10% solution in toluene. Insoluble in water.

Air & Water Reactions

Highly flammable. The neat material is sensitive to air. . Insoluble in water.

Reactivity Profile

Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.

Hazard

Toxic by inhalation and skin contact, a carcinogen (OSHA).

Health Hazard

ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.

Fire Hazard

NICKELOCENE is flammable.

reaction suitability

core: nickel
reagent type: catalyst

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.

Purification Methods

Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]

NICKELOCENE Preparation Products And Raw materials

Raw materials

Preparation Products

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NICKELOCENE Suppliers

Americas 1 Belgium 2 China 111 Europe 2 Finland 1 France 2 Germany 6 India 2 Japan 6 Russia 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 7 United States 34 Global 179
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View Lastest Price from NICKELOCENE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Nickelocene 1271-28-9
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-24
Shaanxi Dideu Medichem Co. Ltd
Product
Nickelocene 1271-28-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10000KG
Release date
2024-08-13
Career Henan Chemical Co
Product
NICKELOCENE 1271-28-9
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-16

1271-28-9, NICKELOCENERelated Search:

MOLECULAR SIEVES Azobenzene Ferrous chloride PETROLEUM ETHER Boron nitride BIS(CYCLOPENTADIENYL)MAGNESIUM Diethylzinc BIS(CYCLOPENTADIENYL)RUTHENIUM Ferrocene BIS(CYCLOPENTADIENYL)MANGANESE [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) BIS(METHYLCYCLOPENTADIENYL)NICKEL BIS(TETRAMETHYLCYCLOPENTADIENYL)NICKEL BIS(PENTAMETHYLCYCLOPENTADIENYL)NICKEL BIS(ETHYLCYCLOPENTADIENYL)NICKEL NICKELOCENE BIS(I-PROPYLCYCLOPENTADIENYL)NICKEL CYCLOPENTADIENYL NICKEL CARBONYL DIMER

  • Nickelocene,99%
  • Dicyclopentadienyl nickel 1g [1271-28-9]
  • Bis(cyclopentadienyl)nickel(II),Di(cyclopentadienyl)nickel(II), Nickelocene
  • bis(cyclopentadienyl)nickel(II)
  • bis(eta<sup>5</sup>-Cyclopentadienyl) nickel
  • bis(η5-2,4-cyclopentadien-1-yl)nickel
  • Di-pi-cyclopentadienylnickel
  • Nickel, bis(eta<sup>5</sup>-cyclopentadienyl)-
  • Nickel, bis(eta5-2,4-cyclopentadien-1-yl)-
  • Nickel, compd with pi-cyclopentadienyl (1:2)
  • Nickel, dicyclopentadienyl-
  • Nickel, di-pi-cyclopentadienyl-
  • nickel,bis(η5-2,4-cyclopentadien-1-yl)-
  • nickel,compdwithpi-cyclopentadienyl(1:2)
  • Bis(cyclopentadienyl)nickel,98% Cp2Ni
  • di(cyclopenta-1,3-dien-1-yl)nickel
  • Bis(cyclopentadienyl)nickel(Ⅱ)
  • Bis(cyclopentadienyl)nickel,Cp2Ni
  • nickelbiscyclopentadiene
  • Nikelocen
  • pi-Cyclopentadienyl compd. with nickel
  • pi-cyclopentadienylcompd.withnickel
  • NICKELOCENE
  • BIS(CYCLOPENTADIENYL)NICKEL
  • BIS(1,5-CYCLOPENTADIENYL)NICKEL
  • DI(CYCLOPENTADIENYL)NICKEL
  • DICYCLOPENTADIENYLNICKEL(II)
  • bis(eta5-2,4-cyclopentadien-1-yl)nickel
  • Bis(cyclopentadienyl)nickel, (Nickelocene)
  • Bis(cyclopentadienyl)nickel,99%(Nickelocene)
  • bis(cyclopentadienyl)nickel, dry
  • di-a-cyclopentadienylnickel
  • Bis(cyclopentadienyl)nickel,99%
  • Di(cyclopentadienyl)nickel(II), Nickelocene
  • Nickelocene&gt
  • NICKELOCENE ISO 9001：2015 REACH
  • 5-2,4-cyclopentadien-1-yl)nickel
  • bis(B7
  • Nickelocene(NiCp2)
  • nickel(2+) dicyclopenta-2,4-dienide
  • 1271-28-9
  • C5H52Ni
  • C10H10Ni
  • NiC5H52
  • Catalysis and Inorganic Chemistry
  • Metallocenes
  • Transition Metal Compounds
  • Ni (Nickel) Compounds
  • Classes of Metal Compounds
  • Titanocene, etc.
  • Classes of Metal Compounds
  • Metallocenes
  • Ni (Nickel) Compounds
  • Titanocene, etc.
  • Transition Metal Compounds
  • Ni
  • metallocene