NICKELOCENE

ChemicalBook > CAS DataBase List > NICKELOCENE

Product Name: NICKELOCENE
CAS No.: 1271-28-9
Chemical Name: NICKELOCENE
Synonyms: Nickelocene,99%;BIS(CYCLOPENTADIENYL)NICKEL;di(cyclopenta-1,3-dien-1-yl)nickel;bis(B7;Nikelocen;NICKELOCENE;Nickelocene>Nickelocene(NiCp2);nickelbiscyclopentadiene;DI(CYCLOPENTADIENYL)NICKEL
CBNumber: CB9136861
Molecular Formula: C10H10Ni10*
Formula Weight: 188.88
MOL File: 1271-28-9.mol

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NICKELOCENE Property

Melting point:: 171-173 °C(lit.)
storage temp.: 2-8°C
Water Solubility: Insoluble in water
form: crystal
color: dark green
Sensitive: Air & Moisture Sensitive
CAS DataBase Reference: 1271-28-9(CAS DataBase Reference)
NIST Chemistry Reference: Nickelocene(1271-28-9)
EPA Substance Registry System: Nickelocene (1271-28-9)

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Safety

Hazard Codes: F,T
Risk Statements: 49-11-22-43
Safety Statements: 53-36/37/39-45
RIDADR: UN 1325 4.1/PG 2
WGK Germany: 3
RTECS: QR6500000
F: 10-23
TSCA: Yes
HazardClass: 4.2
PackingGroup: I
HS Code: 29319090
Toxicity: mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H302Harmful if swallowed

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: N7524
Product name: Bis(cyclopentadienyl)nickel(II)
Packaging: 5g
Price: $71.6
Updated: 2024/03/01

TCI Chemical

Product number: D1574
Product name: Nickelocene
Purity: >98.0%(T)
Packaging: 1g
Price: $52
Updated: 2024/03/01

TCI Chemical

Product number: D1574
Product name: Nickelocene
Purity: >98.0%(T)
Packaging: 5g
Price: $147
Updated: 2024/03/01

Alfa Aesar

Product number: 087899
Product name: Bis(cyclopentadienyl)nickel, dry
Packaging: 2g
Price: $44
Updated: 2024/03/01

Alfa Aesar

Product number: 087899
Product name: Bis(cyclopentadienyl)nickel, dry
Packaging: 50g
Price: $301.65
Updated: 2024/03/01

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NICKELOCENE Chemical Properties,Usage,Production

Chemical Properties

GREEN TO DARK GREEN CRYSTALS OR CRYST. POWDER

Chemical Properties

Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.

Uses

Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.

Uses

This metal alkyl may be used to synthesize hybrid organic-inorganic polymeric molecular layer deposition (MLD). Bis(cyclopentadienyl) nickel (Cp 2 Ni) may be used as a Ni precursor for the atomic layer deposition (ALD) of NiO/carbon nanotubes hybrids.

Uses

Catalyst, complexing agent.

General Description

Dark liquid in an 8-10% solution in toluene. Insoluble in water.

Air & Water Reactions

Highly flammable. The neat material is sensitive to air. . Insoluble in water.

Reactivity Profile

Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.

Hazard

Toxic by inhalation and skin contact, a carcinogen (OSHA).

Health Hazard

ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.

Fire Hazard

NICKELOCENE is flammable.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.

Purification Methods

Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]

NICKELOCENE Preparation Products And Raw materials

Raw materials

Preparation Products

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NICKELOCENE Suppliers

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View Lastest Price from NICKELOCENE manufacturers

Career Henan Chemical Co

Product: NICKELOCENE 1271-28-9
Price: US $7.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-16

1271-28-9, NICKELOCENERelated Search:

MOLECULAR SIEVES Azobenzene Ferrous chloride PETROLEUM ETHER Boron nitride BIS(CYCLOPENTADIENYL)MAGNESIUM Diethylzinc BIS(CYCLOPENTADIENYL)RUTHENIUM Ferrocene BIS(CYCLOPENTADIENYL)MANGANESE [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) BIS(METHYLCYCLOPENTADIENYL)NICKEL BIS(TETRAMETHYLCYCLOPENTADIENYL)NICKEL BIS(PENTAMETHYLCYCLOPENTADIENYL)NICKEL BIS(ETHYLCYCLOPENTADIENYL)NICKEL NICKELOCENE BIS(I-PROPYLCYCLOPENTADIENYL)NICKEL CYCLOPENTADIENYL NICKEL CARBONYL DIMER

Nickelocene,99%

Dicyclopentadienyl nickel 1g [1271-28-9]

Bis(cyclopentadienyl)nickel(II),Di(cyclopentadienyl)nickel(II), Nickelocene

bis(cyclopentadienyl)nickel(II)

bis(eta<sup>5</sup>-Cyclopentadienyl) nickel

bis(η5-2,4-cyclopentadien-1-yl)nickel

Di-pi-cyclopentadienylnickel

Nickel, bis(eta<sup>5</sup>-cyclopentadienyl)-

Nickel, bis(eta5-2,4-cyclopentadien-1-yl)-

Nickel, compd with pi-cyclopentadienyl (1:2)

Nickel, dicyclopentadienyl-

Nickel, di-pi-cyclopentadienyl-

nickel,bis(η5-2,4-cyclopentadien-1-yl)-

nickel,compdwithpi-cyclopentadienyl(1:2)

Bis(cyclopentadienyl)nickel,98% Cp2Ni

di(cyclopenta-1,3-dien-1-yl)nickel

Bis(cyclopentadienyl)nickel(Ⅱ)

Bis(cyclopentadienyl)nickel,Cp2Ni

nickelbiscyclopentadiene

Nikelocen

pi-Cyclopentadienyl compd. with nickel

pi-cyclopentadienylcompd.withnickel

NICKELOCENE

BIS(CYCLOPENTADIENYL)NICKEL

BIS(1,5-CYCLOPENTADIENYL)NICKEL

DI(CYCLOPENTADIENYL)NICKEL

DICYCLOPENTADIENYLNICKEL(II)

bis(eta5-2,4-cyclopentadien-1-yl)nickel

Bis(cyclopentadienyl)nickel, (Nickelocene)

Bis(cyclopentadienyl)nickel,99%(Nickelocene)

bis(cyclopentadienyl)nickel, dry

di-a-cyclopentadienylnickel

Bis(cyclopentadienyl)nickel,99%

Di(cyclopentadienyl)nickel(II), Nickelocene

Nickelocene&gt

NICKELOCENE ISO 9001：2015 REACH

5-2,4-cyclopentadien-1-yl)nickel

bis(B7

Nickelocene(NiCp2)

1271-28-9

C5H52Ni

C10H10Ni

NiC5H52

Catalysis and Inorganic Chemistry

Metallocenes

Transition Metal Compounds

Ni (Nickel) Compounds

Classes of Metal Compounds

Titanocene, etc.

Classes of Metal Compounds

Metallocenes

Ni (Nickel) Compounds

Titanocene, etc.

Transition Metal Compounds

metallocene