2-AMINO-5-IODOBENZOTRIFLUORIDE
- Product Name
- 2-AMINO-5-IODOBENZOTRIFLUORIDE
- CAS No.
- 97760-97-9
- Chemical Name
- 2-AMINO-5-IODOBENZOTRIFLUORIDE
- Synonyms
- 4-IODO-2-(TRIFLUOROMETHYL)ANILINE;ASISCHEM Z25859;2-AMINO-5-IODOBENZOTRIFLUORIDE;2-Amino-5-iodobenzotrifluoride98%;2-Amino-5-iodobenzotrifluoride 98%;4-Iodo-2-trifluoromethylphenylamine;4-iodo-2-(trifluoromethyl)benzenamine;2-amino-5-iodo-trifluoromethylbenzene;Benzenamine, 4-iodo-2-(trifluoromethyl)-;2-AMino-5-iodobenzotrifluoride[4-iodo-2-(trifluoroMethyl)aniline]
- CBNumber
- CB9138698
- Molecular Formula
- C7H5F3IN
- Formula Weight
- 287.02
- MOL File
- 97760-97-9.mol
2-AMINO-5-IODOBENZOTRIFLUORIDE Property
- Boiling point:
- 262℃
- Density
- 1.948
- Flash point:
- 112℃
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- form
- liquid
- pka
- 0.67±0.10(Predicted)
- color
- Clear, brown
Safety
- Hazard Codes
- Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39
- HazardClass
- IRRITANT
- HS Code
- 2921420090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- I724785
- Product name
- 4-Iodo-2-trifluoromethylaniline
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- I724785
- Product name
- 4-Iodo-2-trifluoromethylaniline
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 066903
- Product name
- 2-Amino-5-iodobenzotrifluoride
- Purity
- 98%
- Packaging
- 1g
- Price
- $19
- Updated
- 2021/12/16
- Product number
- PC2012
- Product name
- 2-Amino-5-iodobenzotrifluoride
- Purity
- 98%
- Packaging
- 1g
- Price
- $21
- Updated
- 2021/12/16
- Product number
- 3830-K-X0
- Product name
- 2-Amino-5-iodobenzotrifluoride
- Purity
- 98%
- Packaging
- 1g
- Price
- $23
- Updated
- 2021/12/16
2-AMINO-5-IODOBENZOTRIFLUORIDE Chemical Properties,Usage,Production
Uses
4-Iodo-2-trifluoromethylaniline
Synthesis
887144-94-7
540-37-4
97760-97-9
The general procedure for synthesizing 2-amino-5-iodobenzotrifluoride from 1-(trifluoromethyl)-1,2-phenyliodonyl-3(1H)-one and p-iodoaniline is as follows: in this embodiment, p-iodoaniline was used as the aromatic amine, and the rest of the reaction conditions and post-processing steps were the same as in Example 28. The specific reaction conditions were as follows: 1-(trifluoromethyl)-1,2-phenyliodono-3(1H)-one (0.5 mmol, 1.0 eq.), p-iodoaniline (1.5 mmol, 3.0 eq.), nickel hydroxide (10 μmol), and potassium carbonate (1.5 mmol, 3.0 eq.) were used as bases, and DMSO (2 mL) was used as a solvent, and the temperature of the reaction was 35 °C. The reaction time was 2 hours. After the reaction was completed, post-treatment was carried out according to the method of Example 1.
References
[1] Organic Letters, 2018, vol. 20, # 13, p. 3732 - 3735
[2] Patent: CN108503552, 2018, A. Location in patent: Paragraph 0240-0244
[3] Patent: CN103553857, 2016, B. Location in patent: Paragraph 0021-0022
[4] Organic Letters, 2014, vol. 16, # 6, p. 1768 - 1771
2-AMINO-5-IODOBENZOTRIFLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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