2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

Product Name: 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide
CAS No.: 572-09-8
Chemical Name: 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide
Synonyms: (2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate;ACETOBROMOGLUCOSE;2,3,4,6-tetra-o-acetyl-α-d-glucopyranosyl bromide;2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide;acetobromo-a-d-glucose;Acetobromglucose;Acetobromo-α-D-glucose;A-D-GLUCOPYRANOSYL BROMIDE;TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE;Acetobromo-α-D-glucose;Acetobromglucose;Tetraacetyl bromoglucose
CBNumber: CB9142437
Molecular Formula: C14H19BrO9
Formula Weight: 411.2
MOL File: 572-09-8.mol

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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Property

Melting point:: 86-89 °C
alpha: 194.5 º (c=2,chloroform)
Boiling point:: 0.125-30 °C(Press: 0.0005 Torr)
Density: 1.49±0.1 g/cm3(Predicted)
storage temp.: −20°C
solubility: Acetontrile (Very Slightly), Chloroform (Slightly), Methanol (Slightly)
form: Powder
color: White to beige
Water Solubility: decomposes
Sensitive: Moisture Sensitive
Merck: 14,60
BRN: 96669
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey: CYAYKKUWALRRPA-RGDJUOJXSA-N
CAS DataBase Reference: 572-09-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25-36-26
WGK Germany: -
F: 8-10-21
HS Code: 29329985

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: A1750
Product name: Acetobromo-α-D-glucose
Purity: ≥95% (TLC)
Packaging: 10g
Price: $165
Updated: 2024/03/01

Sigma-Aldrich

Product number: A1750
Product name: Acetobromo-α-D-glucose
Purity: ≥95% (TLC)
Packaging: 25g
Price: $354
Updated: 2024/03/01

TCI Chemical

Product number: T1961
Product name: 2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide (stabilized with CaCO3)
Purity: >98.0%(T)
Packaging: 5g
Price: $53
Updated: 2024/03/01

Alfa Aesar

Product number: L04151
Product name: Acetobromo-alpha-D-glucose, 97%, stab. with 2% calcium carbonate
Packaging: 10g
Price: $111
Updated: 2024/03/01

Alfa Aesar

Product number: L04151
Product name: Acetobromo-alpha-D-glucose, 97%, stab. with 2% calcium carbonate
Packaging: 50g
Price: $352
Updated: 2024/03/01

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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Chemical Properties,Usage,Production

Chemical Properties

White Fluffy Solid

Uses

An Intermediate in synthesis of ∫-glucosides

Uses

Acetobromo-α-D-glucose acts as an intermediate in the preparation of beta-glucosides. It is also used as a possible poly(ethylene terephthalate) surface modification reagent to enhance its blood compatibility.

Purification Methods

If nicely crystalline, recrystallise it from Et2O/pentane or pet ether (b 40-60o). Alternatively dissolve it in diisopropyl ether (dried over CaCl2 for 24hours, then over P2O5 for 24hours) by shaking and warming (for as short a period as possible), and filter warm. Cool to ca 45o, then slowly to room temperature and finally at 5o for more than 2hours. Collect the solid, wash it with cold dry diisopropyl ether and dry it in a vacuum over Ca(OH)2 and NaOH. Store it dry in a desiccator in the dark. Solutions can be stabilised with 2% CaCO3. [Redemann & Niemann Org Synth 65 236 1987, Coll Vol III 11 1955, Beilstein 17/6 V 368.]

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Suppliers

Austria 1 Belgium 2 Canada 3 China 227 Europe 1 Germany 10 India 20 Italy 3 Japan 6 Poland 1 Slovakia 1 Switzerland 6 United Kingdom 23 United States 45 Global 349

Tianjin Exceedbio Technology Co., Ltd.

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Jinan Samuel Pharmaceutical Co., Ltd.

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Beijing Minruida Technology Co., Ltd.

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J & K SCIENTIFIC LTD.

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INTATRADE GmbH

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3B Pharmachem (Wuhan) International Co.,Ltd.

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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View Lastest Price from 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide manufacturers

Henan Fengda Chemical Co., Ltd

Product: 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price: US $5.00-2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-16

Hebei Mojin Biotechnology Co., Ltd

Product: 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-15

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2021-11-24

572-09-8, 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromideRelated Search:

BETA-GLUCOSIDASE Rocuronium bromide Acetoxyacetic acid Sodium triacetoxyborohydride Acetyl coenzyme A sodium salt 2,5-DIDEOXY-2,5-IMINO-D-MANNITOL Ethidium bromide Acetylacetone SILICON TETRAACETATE Allyl bromide Sodium bromate Centchroman Polydextrose Acetyl chloride AMYLOGLUCOSIDASE 2,3,4,6-Tetra-O-acetyl-alpha-D-galactopyranosyl bromide ACETOBROMO-ALPHA-D-GLUCURONIC ACID METHYL ESTER 2,5-Dimethoxyacetoacetanilide

BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE

BROMO 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE

BROMO 2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSE

2,3,4,6-O-tetraacetyl-α-D-glucopyranosyl bromide

Acetobromglucose

Acetobromo-α-D-glucose;Acetobromglucose;Tetraacetyl bromoglucose

Tetraacetyl bromoglucose

ACETOBROMO-ALPHA-D-GLUCOSE, STAB.

ACETOBROMO-A-D-GLUCOSE CRYSTALLINE

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosideBro

A-D-GLUCOPYRANOSYL BROMIDE

1-BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE

1-BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOSE

D-(+)-ALPHA-ACETOBROMOGLUCOSE (STABILISED)

ALPHA-BROMOGLUCOSE TETRAACETATE

ALPHA-D-ACETOBROMOGLUCOSE

ALPHA-D-ACETOBROMOGLUCOPYRANOSIDE

Tetraacetyl-α-D-galactopyranosyl bromide

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, stab., 98.50%

Bromo 2,3,4,6-Tetra-O-acetyl-a-D-glucopyranoside

2,3,4,6-tetra-o-acetyl-à-d-glucopyranosyl bromide

2,3,4,6-tetra-o-acetyl-α-d-glucopyranosyl bromide

acetobromo-à-d-glucose

2,3,4,6-tetra-O-acetyl-α-D-glycopyranosyl bromide

2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE STABILIZED 98.5%

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl broMide, stabilized, 98.5% 10GR

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl BroMide (stabilized with CaCO3)

2,3,4,6-Tetra-O-acetyl-1-bromo-1-deoxy-alpha-D-glucopyranose min. 99%

Acetobromo-alpha-D-glucose, 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, alpha-D-Glucopyranosyl bromide tetraacetate

2,3,4,6-Tetra-O-acetyl-&alpha

-D-glucopyranosylBroMide

Acetobromo-

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, stab. with 2% calcium carbonat

Acetobromo-alpha-D-glucose, stabilized with 2% calcium carbonate

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl bromide, Stabilized

ucopyranosyL

pha-D-g

[(2R,3R,4S,5R,6R)-3,4,5-TRIS(ACETYLOXY)-6-BROMOOXAN-2-YL]METHYL ACETATE

Acetobromo-D-glucose - 2% CaCO3

2,3,4,6-tetra-O-acetyl-D-mannopyranosyl bromide

Reaxys ID: 1692090

Reaxys ID: 6074286

Reaxys ID: 6074287

tetra-O-acetyl-glucopyranosyl bromide

α-D-Tetramethylbromglucose

Tetra-O-pivaloyl-&alpha

acetobromo-a-d-glucose

alpha-d-glucopyranosylbromide,tetraacetate

α-D-Glucopyranosylbromide,tetraacetate

TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE

TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-TETRA-O-ACETYL-1-DEOXY-ALPHA-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE BROMIDE

2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL

2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE

2,3,4,6-TETRA-O-ACETYLGLUCOSYLROMIDE

2,3,4,6-TETRA-O-ACETYL-DEOXY-A-D-GLUCOPYRANOSYL BROMIDE