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2-Acetyl-6-bromonaphthalene

Product Name
2-Acetyl-6-bromonaphthalene
CAS No.
1590-25-6
Chemical Name
2-Acetyl-6-bromonaphthalene
Synonyms
6-BROMO-2-ACETONAPHTHONE;1-(6-bromo-2-naphthyl)ethanone;(6-bromo-2-naphthalenyl)ethanone;1-(6-Bromonaphthalen-2-yl)ethanone;1-(6-bromonaphthalen-2-yl)ethan-1-one;Ethanone, 1-(6-bromo-2-naphthalenyl)-
CBNumber
CB91451107
Molecular Formula
C12H9BrO
Formula Weight
249.1
MOL File
1590-25-6.mol
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2-Acetyl-6-bromonaphthalene Property

Melting point:
96 °C
Boiling point:
357.1±15.0 °C(Predicted)
Density 
1.454±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to light brown Solid
InChI
InChI=1S/C12H9BrO/c1-8(14)9-2-3-11-7-12(13)5-4-10(11)6-9/h2-7H,1H3
InChIKey
UZDOTHVVSQOCJO-UHFFFAOYSA-N
SMILES
C(=O)(C1=CC=C2C(=C1)C=CC(Br)=C2)C
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

ChemScene
Product number
CS-0041458
Product name
1-(6-Bromonaphthalen-2-yl)ethanone
Purity
>97.0%
Packaging
100mg
Price
$70
Updated
2021/12/16
ChemScene
Product number
CS-0041458
Product name
1-(6-Bromonaphthalen-2-yl)ethanone
Purity
>97.0%
Packaging
250mg
Price
$112
Updated
2021/12/16
ChemScene
Product number
CS-0041458
Product name
1-(6-Bromonaphthalen-2-yl)ethanone
Purity
>97.0%
Packaging
1g
Price
$279
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0108835
Product name
1-(6-BROMO-2-NAPHTHYL)ETHANONE
Purity
95.00%
Packaging
5MG
Price
$504.64
Updated
2021/12/16
Matrix Scientific
Product number
171626
Product name
1-(6-Bromonaphthalen-2-yl)ethanone
Purity
95%
Packaging
2.500g
Price
$1650
Updated
2021/12/16
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2-Acetyl-6-bromonaphthalene Chemical Properties,Usage,Production

Synthesis

861880-64-0

75-16-1

1590-25-6

Under nitrogen protection, 6-bromo-N-methoxy-N-methyl-2-naphthalenecarboxamide (82.9 g, 282 mmol, 1.0 eq.) was dissolved in tetrahydrofuran (600 mL) in a four-necked flask. The reaction mixture was cooled in an ice bath at a controlled temperature in the range of 10-15 °C. Methylmagnesium bromide (3.2 M in methyltetrahydrofuran, 197 mL, 2.2 eq.) was added slowly dropwise over a period of 1 hour. After the dropwise addition was completed, the reaction mixture continued to be stirred in an ice bath for 30 minutes. Subsequently, aqueous 2M hydrochloric acid (100 mL) was carefully added dropwise to quench the reaction under cooling in the ice bath. After the organic solvent was removed by evaporation, the precipitated product was extracted with dichloromethane (500 mL). The organic phases were combined, dried over anhydrous sodium sulfate, filtered and concentrated. The resulting solid residue was dried under vacuum at 40 °C to give 1-(6-bromonaphthalen-2-yl)ethanone (70.6 g, 99% yield).

References

[1] Patent: WO2011/54834, 2011, A1. Location in patent: Page/Page column 39
[2] Patent: WO2011/91446, 2011, A1. Location in patent: Page/Page column 11
[3] Patent: US2017/253614, 2017, A1. Location in patent: Paragraph 0574; 0575
[4] Patent: US2011/64695, 2011, A1. Location in patent: Page/Page column 94
[5] Patent: US2011/64697, 2011, A1. Location in patent: Page/Page column 85

2-Acetyl-6-bromonaphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Acetyl-6-bromonaphthalene Suppliers

China 71 India 1 United States 3 Global 75
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 2-Acetyl-6-bromonaphthalene manufacturers

Nanjing Fred Technology Co., Ltd
Product
1-(6-Bromonaphthalen-2-yl)ethanone 1590-25-6
Price
US $0.00/kg
Min. Order
0.1kg
Purity
98%HPLC
Supply Ability
100kg
Release date
2023-11-27
Career Henan Chemical Co
Product
2-Acetyl-6-bromonaphthalene 1590-25-6
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1 ton
Release date
2018-08-20

1590-25-6, 2-Acetyl-6-bromonaphthaleneRelated Search:


  • 6-BROMO-2-ACETONAPHTHONE
  • 1-(6-Bromonaphthalen-2-yl)ethanone
  • (6-bromo-2-naphthalenyl)ethanone
  • Ethanone, 1-(6-bromo-2-naphthalenyl)-
  • 1-(6-bromonaphthalen-2-yl)ethan-1-one
  • 1-(6-bromo-2-naphthyl)ethanone
  • 1590-25-6