Methyl 4-chlorosalicylate

Product Name: Methyl 4-chlorosalicylate
CAS No.: 22717-55-1
Chemical Name: Methyl 4-chlorosalicylate
Synonyms: Nsc300575;Methyl 4-chlorosalicylate;Methyl 4-chloro-2-hydroxybenzoate;4-Chloro-2-hydroxy-benzoic acid Methyl ester;Benzoic acid, 4-chloro-2-hydroxy-, Methyl ester;JR-13528, Methyl 4-chloro-2-hydroxybenzoate, 97%
CBNumber: CB91457619
Molecular Formula: C8H7ClO3
Formula Weight: 186.59
MOL File: 22717-55-1.mol

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Methyl 4-chlorosalicylate Property

Boiling point:: 127 °C(Press: 15 Torr)
Density: 1.354±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: 8.79±0.10(Predicted)
form: solid
color: tan

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Safety

Hazard Codes: Xi
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M340405
Product name: Methyl4-Chloro-2-hydroxybenzoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Apolloscientific

Product number: OR59351
Product name: Methyl4-chloro-2-hydroxybenzoate
Packaging: 1g
Price: $96
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2629-5-15
Product name: Methyl 4-chloro-2-hydroxybenzoate
Packaging: 1g
Price: $106
Updated: 2021/12/16

AK Scientific

Product number: 7746AD
Product name: Methyl4-chloro-2-hydroxybenzoate
Packaging: 10g
Price: $107
Updated: 2021/12/16

Matrix Scientific

Product number: 083369
Product name: Methyl 4-chloro-2-hydroxybenzoate
Purity: 95%
Packaging: 1g
Price: $194
Updated: 2021/12/16

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Methyl 4-chlorosalicylate Chemical Properties,Usage,Production

Synthesis

5106-98-9

22717-55-1

1. Synthesis of methyl 4-chloro-2-hydroxybenzoate (2f): 4-chloro-2-hydroxybenzoic acid (200 g, 1.16 mol) was mixed with 40 ml of concentrated hydrochloric acid and added to 400 ml of methanol, followed by addition of sulfuric acid. The reaction mixture was heated to reflux for 20 hours. After completion of the reaction, the solvent was removed by evaporation under reduced pressure. The residue was poured into saturated aqueous Na2CO3 solution and extracted with ether (3 x 500 ml). The organic layers were combined, dried with anhydrous Na2SO4 and the solvent was evaporated to give the crude product 2f (191.6 g, 88.6% yield) as an oil. The product was used for subsequent reactions without further purification.IR (pure) showed absorption peaks: 3150 (OH), 1728 (C=O) and 1678 (C=O) cm-1.1H NMR (CDCl3) δ: 10.27 (br s, 1H, OH), 7.47 (d, 1H, J=8Hz, Ar-H), 6.80 (d, 1H, J=2Hz, Ar-H). 2Hz, Ar-H), 6.63 (d, 1H, Ar-H), 3.85 (s, 3H, OCH3).

References

[1] Patent: US4888353, 1989, A
[2] Patent: EP234872, 1991, B1
[3] Patent: US6313310, 2001, B1
[4] Patent: US5484763, 1996, A
[5] Patent: US4420476, 1983, A

Methyl 4-chlorosalicylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-chlorosalicylate Suppliers

China 68 India 3 United Kingdom 1 United States 14 Global 86

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Energy Chemical

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Fax: 021-58436166
Email: sales8178@energy-chemical.com
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ProdList: 44801
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Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
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Beijing Taiya Jie Technology Development Co., Ltd.

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Email: postmaster@tyjchem.cn
Country: China
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Wuhan Fortuna Chemical Co., Ltd

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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

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SuZhou ShiYa Biopharmaceuticals, Inc.

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9ding chemical ( Shanghai) Limited

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Bide Pharmatech Ltd.

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Nanjing Duolong Bio-tech Co.,Ltd.

Tel: 18905173768
Fax: 025-83263139
Email: 52513593@qq.com
Country: China
ProdList: 2331
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View Lastest Price from Methyl 4-chlorosalicylate manufacturers

Honest Joy Holdings Limited

Product: methyl4-chloro-2-hydroxybenzoate 22717-55-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.2%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: 22717-55-1 22717-55-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-24

22717-55-1, Methyl 4-chlorosalicylateRelated Search:

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Nsc300575

4-Chloro-2-hydroxy-benzoic acid Methyl ester

Benzoic acid, 4-chloro-2-hydroxy-, Methyl ester

Methyl 4-chloro-2-hydroxybenzoate

Methyl 4-chlorosalicylate

JR-13528, Methyl 4-chloro-2-hydroxybenzoate, 97%

22717-55-1

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