ChemicalBook > CAS DataBase List > Methyl 4-chlorosalicylate

Methyl 4-chlorosalicylate

Product Name
Methyl 4-chlorosalicylate
CAS No.
22717-55-1
Chemical Name
Methyl 4-chlorosalicylate
Synonyms
Nsc300575;Methyl 4-chlorosalicylate;Methyl 4-chloro-2-hydroxybenzoate;4-Chloro-2-hydroxy-benzoic acid Methyl ester;Benzoic acid, 4-chloro-2-hydroxy-, Methyl ester;JR-13528, Methyl 4-chloro-2-hydroxybenzoate, 97%
CBNumber
CB91457619
Molecular Formula
C8H7ClO3
Formula Weight
186.59
MOL File
22717-55-1.mol
More
Less

Methyl 4-chlorosalicylate Property

Boiling point:
127 °C(Press: 15 Torr)
Density 
1.354±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
8.79±0.10(Predicted)
form 
solid
color 
tan
More
Less

Safety

Hazard Codes 
Xi
HS Code 
2916399090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
M340405
Product name
Methyl4-Chloro-2-hydroxybenzoate
Packaging
100mg
Price
$60
Updated
2021/12/16
Apolloscientific
Product number
OR59351
Product name
Methyl4-chloro-2-hydroxybenzoate
Packaging
1g
Price
$96
Updated
2021/12/16
SynQuest Laboratories
Product number
2629-5-15
Product name
Methyl 4-chloro-2-hydroxybenzoate
Packaging
1g
Price
$106
Updated
2021/12/16
AK Scientific
Product number
7746AD
Product name
Methyl4-chloro-2-hydroxybenzoate
Packaging
10g
Price
$107
Updated
2021/12/16
Matrix Scientific
Product number
083369
Product name
Methyl 4-chloro-2-hydroxybenzoate
Purity
95%
Packaging
1g
Price
$194
Updated
2021/12/16
More
Less

Methyl 4-chlorosalicylate Chemical Properties,Usage,Production

Synthesis

5106-98-9

22717-55-1

1. Synthesis of methyl 4-chloro-2-hydroxybenzoate (2f): 4-chloro-2-hydroxybenzoic acid (200 g, 1.16 mol) was mixed with 40 ml of concentrated hydrochloric acid and added to 400 ml of methanol, followed by addition of sulfuric acid. The reaction mixture was heated to reflux for 20 hours. After completion of the reaction, the solvent was removed by evaporation under reduced pressure. The residue was poured into saturated aqueous Na2CO3 solution and extracted with ether (3 x 500 ml). The organic layers were combined, dried with anhydrous Na2SO4 and the solvent was evaporated to give the crude product 2f (191.6 g, 88.6% yield) as an oil. The product was used for subsequent reactions without further purification.IR (pure) showed absorption peaks: 3150 (OH), 1728 (C=O) and 1678 (C=O) cm-1.1H NMR (CDCl3) δ: 10.27 (br s, 1H, OH), 7.47 (d, 1H, J=8Hz, Ar-H), 6.80 (d, 1H, J=2Hz, Ar-H). 2Hz, Ar-H), 6.63 (d, 1H, Ar-H), 3.85 (s, 3H, OCH3).

References

[1] Patent: US4888353, 1989, A
[2] Patent: EP234872, 1991, B1
[3] Patent: US6313310, 2001, B1
[4] Patent: US5484763, 1996, A
[5] Patent: US4420476, 1983, A

Methyl 4-chlorosalicylate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl 4-chlorosalicylate Suppliers

China 68 India 3 United Kingdom 1 United States 14 Global 86
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1542
Advantage
55
Wuhan Fortuna Chemical Co., Ltd
Tel
027-59207852 13308628970
Fax
QQ3130921841
Email
buy@fortunachem.com
Country
China
ProdList
2744
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
SuZhou ShiYa Biopharmaceuticals, Inc.
Tel
86(512)5235 8471 17715136450
Fax
86(512)5235 6881
Email
sales@shiyabiopharm.com
Country
China
ProdList
4169
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Nanjing Duolong Bio-tech Co.,Ltd.
Tel
18905173768
Fax
025-83263139
Email
52513593@qq.com
Country
China
ProdList
2331
Advantage
50
Zhengzhou Guancheng Laboratory equipment Sales
Tel
0371-88888888 272369594
Fax
QQ:272369594
Email
2723695949@qq.com
Country
China
ProdList
4955
Advantage
50
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6498
Advantage
58
Chengdu Research Accelerators Technology Co., Ltd.
Tel
028-64353063
Fax
028-64353063 QQ:784253935
Email
reacchemical@163.com
Country
China
ProdList
5253
Advantage
58
Wuhan Chemwish Technology Co.， Ltd
Tel
027-67849912
Fax
027-87531808
Email
sales@chemwish.com
Country
China
ProdList
9148
Advantage
60
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Shanghai SuperLan Chemcial Technique Centre
Tel
0-2022843681 15618226720
Fax
+86-21-51601218
Email
chaolaichem@foxmail.com
Country
China
ProdList
10410
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Shanghai Qianlai Medical Technology Co., Ltd.
Tel
482109853
Fax
021-37288278
Email
info@qianlaiyiyao.com
Country
China
ProdList
406
Advantage
58
Shanghai CR Corporation Limited
Tel
13062833949; 4006653949 4006653949
Fax
QQ: 2136646215
Email
fred.wen@crcorporation.cn
Country
China
ProdList
9754
Advantage
58
Dalian lichuang Chemical Co., Ltd
Tel
0411-0411-00000000 13644282108
Fax
-
Email
3500508746@qq.com
Country
China
ProdList
2896
Advantage
55
Hangzhou Molcore Biopharmatech Co.,Ltd
Tel
400-711-5280 86-571-81025280
Fax
86-571-85806285
Email
sales@molcore.com
Country
China
ProdList
9967
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Xinyi Kangda Biological Technology Co., Ltd.
Tel
13013943931 15152133928
Email
xinyikangda@163.com
Country
China
ProdList
610
Advantage
58
Xinyi Kaiwu Chemical Technology Co., Ltd.
Tel
0516-0516-88997009 18651776937
Email
4164357@qq.com
Country
China
ProdList
3204
Advantage
58
Henan Weituxi Chemical Technology Co., Ltd.
Tel
0371-63284658 18135795563
Fax
QQ:2885349392
Email
2885349392@qq.com
Country
China
ProdList
9989
Advantage
58
Changzhou Kangrui Pharmaceutical Technology Co., Ltd.
Tel
+86-0519-85485169 +86-13961161173
Email
sales@kangruipharm.com
Country
China
ProdList
260
Advantage
58
Chongqing Chemdad Co., Ltd
Tel
+86-023-6139-8061 +86-86-13650506873
Email
sales@chemdad.com
Country
China
ProdList
39927
Advantage
58
Wuhan Chemwish Technology Co., Ltd
Tel
027-67849912
Email
sales@chemwish.com
Country
CHINA
ProdList
10821
Advantage
58
Xinyi Huaju Pharmaceutical Technology Co., Ltd.
Tel
13761372795
Email
huajupharm@163.com
Country
China
ProdList
806
Advantage
58
Hubei Xinkang Pharmaceutical Chemical Co., Ltd
Tel
027-027-59308705 18871579363
Fax
027-59308705
Email
1248680011@qq.com
Country
China
ProdList
9847
Advantage
58
Hubei Guangao Biotechnology Co., Ltd
Tel
027-02702759223056 18162699093
Fax
027-59223056
Email
1208480011@qq.com
Country
China
ProdList
9875
Advantage
58
Hubei Co-prosperity Medicine Technonlogy Co., Ltd
Tel
2383948258 19172820304
Email
2383948258@qq.com
Country
China
ProdList
12987
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
R.R Scientific, LLC.
Tel
15010167677
Email
zhiyuu1218@163.com
Country
China
ProdList
876
Advantage
58
Suzhou Daolan Biomedical Technology Co., Ltd.
Tel
15952404857
Email
sales@dolanpharm.com
Country
China
ProdList
2919
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
AAB-PHARMA LIMITED
Tel
02566880956
Email
3325708371@qq.com
Country
China
ProdList
7869
Advantage
58
Shandong Mingde Biotechnology Co., Ltd
Tel
15553348166
Email
m15553348166@163.com
Country
China
ProdList
9967
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29784
Advantage
58
Shandong Hydrocarbon Bio-Chemical Co. LTD
Tel
15508610597
Email
levi@lihengpharm.com
Country
China
ProdList
993
Advantage
58
Zhengzhou Hong Sheng Pharmaceutical Technology Co. Ltd.
Tel
0371-55695890 15637198702
Email
1677336983@qq.com
Country
China
ProdList
13191
Advantage
58
Hubei DAHAO Chemical Co., Ltd.
Tel
027-027-59106191 13986034860
Email
1400828855@qq.com
Country
China
ProdList
8919
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
18621169109
Email
market03@meryer.com
Country
China
ProdList
27987
Advantage
58
Henan Evonik Biotechnology Co. LTD
Tel
16650615803
Email
2224986086@qq.com
Country
China
ProdList
4754
Advantage
58
Anhui Henuo Biotechnology Co., Ltd
Tel
18455579438
Country
China
ProdList
16684
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
Zhuhai Aobokai Biomedical Technology Co., Ltd.
Tel
400-0628126 15697567703
Email
sales-team@aobchem.com.cn
Country
China
ProdList
49999
Advantage
58
Shaanxi kelkai Pharmaceutical Technology Co., Ltd
Tel
029-2148545164 17392779578
Email
2148545164@qq.com
Country
China
ProdList
1144
Advantage
58
Shandong Mingde Biotechnology Co., Ltd.
Tel
18560864701
Email
643971@qq.com
Country
China
ProdList
6098
Advantage
58
Hangzhou Bingochem Co., Ltd.
Tel
0571-8512-5372
Email
sales@bingochem.com
Country
China
ProdList
21669
Advantage
58
More
Less

View Lastest Price from Methyl 4-chlorosalicylate manufacturers

Honest Joy Holdings Limited
Product
methyl4-chloro-2-hydroxybenzoate 22717-55-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98.2%
Supply Ability
100 tons
Release date
2022-01-14
Career Henan Chemical Co
Product
22717-55-1 22717-55-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kg
Release date
2018-12-24

22717-55-1, Methyl 4-chlorosalicylateRelated Search:

Methyl 3,5-dibromo-4-chlorosalicylate Methyl 5-bromo-4-chloro-2-hydroxybenzoate Methyl 4-chloro-2-methoxybenzoate Methyl 4-chlorosalicylate METHYL 3-CHLORO-4-HYDROXYBENZOATE Methyl 3-amino-5-chloro-2-hydroxybenzoate METHYL 5-CHLOROSALICYLATE 97%,METHYL 5-CHLOROSALICYLATE Methyl 5-borono-4-chloro-2-methoxybenzoate 4-Chloro-2-methoxy-5-nitro-benzoic acid methyl ester OXALIC ACID BIS[2,4,5-TRICHLORO-6-(PENTYLOXYCARBONYL)PHENYL] ESTER Methyl 5-bromo-4-chloro-2-methoxybenzoate ethyl 4-chloro-2-methoxy-5-methylbenzoate methyl 3-chlorosalicylate AURORA KA-6314 AURORA KA-6250 3-Amino-4-chloro-2-methoxy-benzoic acid methyl ester AURORA KA-6316 AURORA KA-6263

  • Nsc300575
  • 4-Chloro-2-hydroxy-benzoic acid Methyl ester
  • Benzoic acid, 4-chloro-2-hydroxy-, Methyl ester
  • Methyl 4-chloro-2-hydroxybenzoate
  • Methyl 4-chlorosalicylate
  • JR-13528, Methyl 4-chloro-2-hydroxybenzoate, 97%
  • 22717-55-1
  • blocks
  • Carboxes