[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid

Application

Product Name: [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid
CAS No.: 867044-33-5
Chemical Name: [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid
Synonyms: (4-(2-Phenyl-1H-benzo[d]imidazol-1-yl);3-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl;acid,B-[4-(2-phenyl-1H-benzimidazol-1-yl)phenyl]-;[4-(2-Phenyl-1H-benzimidazol-1-yphenyl]boronic acid;4-(2-Phenyl-1H-benzimidazol-1-yl)benzeneboronic Acid;[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid;4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenylboronic acid;[4-(2-phenyl-1H-1,3-benzodiazol-1-yl)phenyl]boronic acid;(4-(2-Phenyl-1H-benzo[d]iMidazol-1-yl)phenyl)boronic acid;Boronic acid,B-[4-(2-phenyl-1H-benziMidazol-1-yl)phenyl]-
CBNumber: CB91514817
Molecular Formula: C19H15BN2O2
Formula Weight: 314.15
MOL File: 867044-33-5.mol

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[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid Property

Boiling point:: 572.6±60.0 °C(Predicted)
Density: 1.21
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: powder to crystal
pka: 8.37±0.16(Predicted)
color: White to Almost white

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Safety

HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical

Product number: P2282
Product name: 4-(2-Phenyl-1H-benzimidazol-1-yl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1G
Price: $183
Updated: 2025/07/31

Chem-Impex

Product number: 40378
Product name: 4-(2-Phenyl-1H-benzimidazol-1-yl)phenylboronicacid,98-105%(Assaybytitration)
Purity: 98-105%(Assaybytitration)
Packaging: 1G
Price: $223.64
Updated: 2021/12/16

Matrix Scientific

Product number: 090473
Product name: (4-(2-Phenyl-1H-benzo[d]imidazol-1-yl)phenyl)boronic acid
Purity: 95+%
Packaging: 250mg
Price: $341
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0006712
Product name: (4-(2-PHENYL-1H-BENZO[D]IMIDAZOL-1-YL)PHENYL)BORONIC ACID
Purity: 95.00%
Packaging: 5MG
Price: $505.12
Updated: 2021/12/16

Matrix Scientific

Product number: 090473
Product name: (4-(2-Phenyl-1H-benzo[d]imidazol-1-yl)phenyl)boronic acid
Purity: 95+%
Packaging: 1g
Price: $756
Updated: 2021/12/16

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[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid Chemical Properties,Usage,Production

Application

[4-(2-phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid is an organic synthesis intermediate and a pharmaceutical intermediate that can be used in laboratory research and development processes and chemical production processes.

Synthesis

760212-58-6

867044-33-5

Under argon protection, 10 g (29 mmol) of 1-(4-bromophenyl)-2-phenyl-1H-benzimidazole was dissolved in 100 mL of anhydrous tetrahydrofuran and the solution was cooled to -78 °C. Subsequently, 20 mL of n-butyllithium solution (1.6 mol/L, dissolved in hexane) was added slowly and dropwise. The reaction mixture was continuously stirred at -78 °C for 1 h and then warmed up to 0 °C. The mixture was again cooled to -78 °C and 9.7 mL (87 mmol) of trimethoxyborane was added dropwise. The mixture continued to be stirred at -78 °C for 1 hour, followed by 2 hours at room temperature. Upon completion of the reaction, 100 mL of 10% (w/w) hydrochloric acid solution was added and stirred for 1 hr, followed by filtration. The organic layer was separated, washed with saturated sodium chloride solution and dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure and the residue was purified by silica gel column chromatography to give 4.2 g of [4-(2-phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid in 46% yield.

References

[1] Patent: EP1734038, 2006, A1. Location in patent: Page/Page column 49

[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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[4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid Suppliers

China 115 China Hong Kong 1 India 2 Japan 1 United States 7 Global 126

Shanghai Longsheng chemical Co.,Ltd.

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View Lastest Price from [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid 867044-33-5
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-06-13

Henan Aochuang Chemical Co.,Ltd.

Product: [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid 867044-33-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-10-17

Zhengzhou Anbu Chem Co.,Ltd

Product: [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acid 867044-33-5
Price: US $0.00/KG
Min. Order: 0.1KG
Purity: 98%
Supply Ability: 1000KGS
Release date: 2023-04-14

867044-33-5, [4-(2-Phenyl-1H-benzimidazol-1-yl)phenyl]boronic acidRelated Search:

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4-(2-Phenyl-1H-benzimidazol-1-yl)phenylboronic Acid (contains varying amounts of Anhydride)

(4-(2-Phenyl-1H-benzo[d]imidazol-1-yl)

3-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl

4-(2-Phenyl-1H-benzimidazol-1-yl)benzeneboronic Acid

[4-(2-Phenyl-1H-benzimidazol-1-yphenyl]boronic acid

acid,B-[4-(2-phenyl-1H-benzimidazol-1-yl)phenyl]-

867044-33-5

952514-79-1

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