Benzimidazole anthelmintics Aofendazuo Chemical Properties Uses Production method
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Fenbendazole

Benzimidazole anthelmintics Aofendazuo Chemical Properties Uses Production method
Product Name
Fenbendazole
CAS No.
43210-67-9
Chemical Name
Fenbendazole
Synonyms
fenbendazol;Febendazole;5-(phenylthio)-2-benzimidazolecarbamic acid methyl ester;Methyl (6-(phenylthio)-1H-benzo[d]iMidazol-2-yl)carbaMate;[5-(Phenylthio)-1H-benzimidazol-2-yl]carbonic acid, Methyl ester;hoe881;Axilur;Fenbion;PANACUR;HOE-881V
CBNumber
CB9154575
Molecular Formula
C15H13N3O2S
Formula Weight
299.35
MOL File
43210-67-9.mol
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Fenbendazole Property

Melting point:
233°C
Density 
1.2767 (rough estimate)
refractive index 
1.6740 (estimate)
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
solubility 
DMSO:16.67(Max Conc. mg/mL);55.69(Max Conc. mM)
DMF:10.0(Max Conc. mg/mL);33.41(Max Conc. mM)
pka
10.80±0.10(Predicted)
form 
Solid
color 
White to Light yellow
Merck 
14,3960
BRN 
759077
InChI
InChI=1S/C15H13N3O2S/c1-20-15(19)18-14-16-12-8-7-11(9-13(12)17-14)21-10-5-3-2-4-6-10/h2-9H,1H3,(H2,16,17,18,19)
InChIKey
HDDSHPAODJUKPD-UHFFFAOYSA-N
SMILES
C(OC)(=O)NC1NC2=CC(SC3=CC=CC=C3)=CC=C2N=1
CAS DataBase Reference
43210-67-9(CAS DataBase Reference)
EPA Substance Registry System
Carbamic acid, N-[6-(phenylthio)-1H-benzimidazol-2-yl]-, methyl ester (43210-67-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
2
RTECS 
DD6520500
HS Code 
29339900
Toxicity
dog,LD50,oral,> 500mg/kg (500mg/kg),Pesticide Science. Vol. 8, Pg. 550, 1977.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
35032
Product name
Fenbendazole
Purity
VETRANAL , analytical standard
Packaging
100mg
Price
$62.5
Updated
2024/03/01
Sigma-Aldrich
Product number
1269403
Product name
Fenbendazole
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
100mg
Price
$1350
Updated
2024/03/01
TCI Chemical
Product number
F0812
Product name
Fenbendazole
Purity
>98.0%(HPLC)(N)
Packaging
25g
Price
$135
Updated
2024/03/01
Cayman Chemical
Product number
19687
Product name
Fenbendazole
Purity
≥98%
Packaging
5g
Price
$62
Updated
2024/03/01
Cayman Chemical
Product number
19687
Product name
Fenbendazole
Purity
≥98%
Packaging
10g
Price
$92
Updated
2024/03/01
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Fenbendazole Chemical Properties,Usage,Production

Benzimidazole anthelmintics

Fenbendazole is a benzimidazole anthelmintic with a broad spectrum,high efficiency and low toxicity ,in the structure,it has a strong affinity with the parasite tubulin ,by influencing cell transport and energy metabolism,it plays a role in preventing the polymerization of micro tubes, which ultimately destroys the integrity of parasite cells and energy transmission.
Fenbendazole is used to drive and to kill the animal gastrointestinal parasites, it not only has a highly anthelmintic activity on animal gastrointestinal roundworms, hookworms, whipworms, some tapeworms and nematodes , but also has a preferred effect on the part of the bronchial tree and lung parasites (Aelurostrongylus abstrutus and lung fluke) .

Aofendazuo

Aofendazuo is a benzimidazole anthelmintic, also known as the Austrian phenol metronidazole, oxfendazole, benzene etomidate sulfoxide, benzene sulfur oxygen imidazole ,it is the sulfoxide form of Fenbendazole , white or off-white powder at room temperature, slight special smell, it can damage the microtubules of the worms epithelial cells of the gastrointestinal tract, and inhibit the worms uptake of glucose from the intestine.
Aofendazuo is used for the treatment and control of gastrointestinal adults and larvae, it has a good effect on the treatment of in vivo roundworms and lung worms in pigs and sheep , including Oster nematodes (Ostertagia), Haemonchus , Trichostrongylus, Nematodirus , Cooper nematode (Cooperia), capillary nematodes (Capillaria), toothed Oesophagostomum (Oesophagostomum), Chabertia, Trichuris nematodes form (Trichuris) and dictyocaulasis ( Dictyocaulus) and so on.
The above information is edited by the chemicalbook of Tian Ye.

Chemical Properties

Gray light brown crystalline powder. Melting point 233 ℃ (decomposition). Soluble in dimethyl sulfoxide (DMSO), slightly soluble in common organic solvents, insoluble in water. Odorless, tasteless.

Uses

Anthelmintic. Broad-spectrum, high efficiency, low toxicity, antiparasitic. It has a strong killing effect on Roundworm, nematodes, tapeworms, cysticercosis , Fasciola and other parasites, not only killing worms, especially having a great effect on Transitional larvae ehich are hazardous to the liver, lungs and intestines .Fenbendazole is a benzimidazole anthelmintic, not only having a highly anthelmintic activity for gastrointestinal nematodes adults and larvae , but also having a good effect on dictyocaulasis, flukes and tapeworms, in addition,it has a strong killing eggs effect.

Production method

5-chloro-2-nitroaniline reacts with benzene thiol, to thereby obtain 5-phenylthio-2-nitroaniline in 91% yield.Generate 3-phenylthio-o-phenylenediamine by ferrous sulfate-iron reduction in 90% yield. Finally, cyclize it with the S-methyl-melamine Methyl to obtain fenbendazole.

Description

Fenbendazole is a benzimidazole anthelmintic. It is active against Giardia in vitro (IC50 = 0.3 μM). Fenbendazole (20 mg/kg) prevents infiltration of parasites into the brain in a rabbit model of E. cuniculi infection. Fenbendazole also activates HIF-1α and prevents oxidative stress-induced death in primary neurons in vitro.

Chemical Properties

Off-White Solid

Originator

Panacur,Hoechst,W. Germany,1980

Uses

Fenbendazole is a benzimidazole anthelmintic that is metabolised in mammals to a series of other benzimidazoles including oxfendazole. It is used for the control of gastrointestinal roundworms, lung worms, Nematodes and tape worms. It is the only benzimidazole approved for use in organic livestock production.

Uses

Fenbendazole is a medication used to treat parasites, mainly in dogs. However, studies have found that in a group of mice treated with a combination of fenbendazole and vitamins, tumor growth inhibition was unexpected It may be because it interferes with the uptake of glucose by cancer cells, which is essential for tumor growth and proliferation. It prevents cancer cells from obtaining the glucose needed to grow and divide to inhibit the growth of cancer cells. Studies have found that fenbendazole can kill cancer cells and promote tumor regression in patients with metastatic large B-cell lymphoma, and also plays a role in other metastatic malignant tumors such as bladder cancer and renal cell carcinoma. It is currently being treated in combination with other anti-cancer drugs to study its anti-cancer potential[1-3].

Definition

ChEBI: Fenbendazole is a member of the class of benzimidazoles that is 1H-benzimidazole which is substituted at positons 2 and 5 by (methoxycarbonyl)amino and phenylsulfanediyl groups, respectively. A broad-spectrum anthelmintic, it is used, particularly in veterinary medicine, for the treatment of nematodal infections. It has a role as an antinematodal drug. It is a member of benzimidazoles, a carbamate ester and an aryl sulfide.

Manufacturing Process

20.9 g of S-methyl-thiourea were dissolved in 27 ml of water with 13.5 ml of chloroformic acid methyl ester. Then, 45.7 ml of 25% sodium hydroxide solution were added dropwise, while stirring, at a temperature of 5°C to 10°C. After having stirred for 20 minutes, the reaction mixture was combined with 27 ml of glacial acetic acid, 100 ml of water and 29 g of 3,4-diaminodiphenyl- thioether. Stirring was continued for 90 minutes at a temperature of 85°C, during which time methyl-mercaptan was separated. After having allowed the whole to cool and stand overnight, the 5-phenylmercaptobenzimidazole- 2-methyl-carbamate that had formed was filtered off with suction. After recrystallization from a mixture of glacial acetic acid and methanol, 14 g of 4-phenylmercapto-benzimidazole-2-methyl-carbamate melting at 233°C were obtained.

brand name

Panacur (Hoechst-Roussel).

Therapeutic Function

Anthelmintic

General Description

Fenbendazole is a thio substituted benzimidazole, which belongs to the group of anthelmintics. It can be widely used in veterinary medicine particularly, in the treatment of helminth infections.

Side effects

According to the results of toxicological studies, fenbendazole appears to be a safe drug, but up to 5% of people may experience stomach pain or diarrhea if taken in large amounts without interruption. People with severe renal failure or liver failure have a reduced level of drug excretion, and since fenbendazole powder is metabolized mainly in the liver, long-term heavy use can cause an asymptomatic increase in liver enzymes.

Veterinary Drugs and Treatments

Fenbendazole is indicated (labeled) for the removal of the following parasites in dogs: ascarids (Toxocara canis, T. leonina), Hookworms (Ancylostoma caninum, Uncinaria stenocephala), whipworms (Trichuris vulpis), and tapeworms (Taenia pisiformis). It is not effective against Dipylidium caninum. Fenbendazole has also been used clinically to treat Capillaria aerophilia, Filaroides hirthi, and Paragonimus kellicotti infections in dogs.
Fenbendazole is indicated (labeled) for the removal of the following parasites in cattle: Adult forms of: Haemonchus contortus, Ostertagia ostertagi, Trichostrongylus axei, Bunostomum phlebotomum, Nematodirus helvetianus, Cooperia spp., Trichostrongylus colubriformis, Oesophagostomum radiatum, and Dictyocaulus vivaparus. It is also effective against most immature stages of the above listed parasites. Although not approved, it has good activity against Moniezia spp., and arrested 4th stage forms of Ostertagia ostertagi. Fenbendazole is indicated (labeled) for the removal of the following parasites in horses: large strongyles (S. edentatus, S. equinus, S. vulgaris), small strongyles (Cyathostomum spp., Cylicocylus spp., Cylicostephanus spp., Triodontophorus spp.), and pinworms (Oxyuris equi).
Fenbendazole is indicated (labeled) for the removal of the following parasites in swine: large roundworms (Ascaris suum), lungworms (Metastrongylus pair), nodular worms (Oesphagostomum dentatum, O. quadrispinolatum), small stomach worms (Hyostrongylus rubidus), whipworms (Trichuris suis), and kidney worms (Stephanurus dentatus; both mature and immature).
Although not approved, fenbendazole has been used in cats, sheep, goats, pet birds, and llamas.

Mode of action

Fenbendazole is a benzimidazole antiparasitic drug that works at the sub-cellular level preventing cell division. Benzimidazoles bind to the β-tubulin, inhibiting the cell’s microtubule assembly responsible for intracellular transport and required for mitotic cellular division. In effect, it starves the parasite by causing intestinal cell disruption.

References

[1] Gao P, et al. Unexpected antitumorigenic effect of fenbendazole when combined with supplementary vitamins. Journal of the American Association for Laboratory Animal Science : JAALAS, 2008.
[2] Park D, et al. Anti-cancer effects of fenbendazole on 5-fluorouracil-resistant colorectal cancer cells. The Korean Journal of Physiology Pharmacology, 2022; 26: 377-387.[3] Shin Y, et al. Anticancer Evaluation of Methoxy Poly(Ethylene Glycol)-b-Poly(Caprolactone) Polymeric Micelles Encapsulating Fenbendazole and Rapamycin in Ovarian Cancer. International Journal of Nanomedicine, 2023; 2023: 2209—2223.

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View Lastest Price from Fenbendazole manufacturers

Henan Suikang Pharmaceutical Co.,Ltd.
Product
Fenbendazole 43210-67-9
Price
US $0.00/kg
Min. Order
25kg
Purity
98.0%~101.0%
Supply Ability
10tons
Release date
2024-04-26
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Fenbendazole 43210-67-9
Price
US $85.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-24
Hebei Zhuanglai Chemical Trading Co Ltd
Product
Antiparasitic Fenbendazole 43210-67-9
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2024-12-05

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  • FENBENDAZOLE USP STANDARD
  • FENBENDAZOLE IMPURITY AMETHYL(1H-BENZIMIDAZOL-2-YL)CARBAMATE EP STANDARD
  • FENBENDAZOLE RELATED COMPOUND BMETHYL [5(6)CHLOROBENZIMIDAZOLE-2-YL) CARBAMATE USP STANDARD
  • FENBENDAZOLE RELATED COMPOUND AMETHYL (1H-BENZIMIDAZOLE-2-YL) CARBAMATE USP STANDARD
  • [5-(Phenylthio)-1H-benzimidazol-2-yl]carbamic Acid, Methyl Ester, HOE-881v, Panacur, Safegard,
  • [5-(PHENYLTHIO)-1H-BENZIMIDAZOL-2-YL]CARBAMIC ACID, METHYL ESTER
  • HOE-881V
  • FENBENDAZOLE
  • METHYL 5-(PHENYLTHIO)-2-BENZIMIDAZOLECARBAMATE
  • SAFEGARD
  • PANACUR
  • (5-(phenylthio)-1h-benzimidazol-2-yl)-carbamicacimethylester
  • 5-(phenylthio)-2-benzimidazolecarbamicacimethylester
  • fenbendazole,FBZ,Panacur
  • CarbaMicacid, N-[6-(phenylthio)-1H-benziMidazol-2-yl]-, Methyl ester
  • Fenbendazole >=98%
  • Fenbendazole SynonyMs [5-(phenylthio)-1H-benziMidazol-2-yl]carbaMic acid Methyl ester
  • Fenbendazole 0
  • Fenbendazole Related CoMpound B
  • fenbendazole Solution, 100ppm
  • Fenbenzaole
  • fenbendazol fenbendazole
  • methyl N-(5-phenylsulfanyl-3H-benzoimidazol-2-yl)carbamate
  • Fenbendazole&gt
  • Fenbendazole CRS
  • Fenbenazol
  • Phenbendasol
  • FelypressinFenbendazole
  • Oxfendazole EP Impurity A
  • Febantel EP Impurity C
  • Febantel Impurity 3(Febantel EP Impurity C)