Reaction
ChemicalBook > CAS DataBase List > (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

Reaction
Product Name
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
CAS No.
192139-90-5
Chemical Name
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Synonyms
RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro);[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)];RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
CBNumber
CB91569347
Molecular Formula
C31H30ClN2O2RuS
Formula Weight
631.17
MOL File
192139-90-5.mol
More
Less

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Property

Melting point:
>175 °C
alpha 
178o (C=0.5 IN CHLOROFORM)
storage temp. 
2-8°C
solubility 
soluble in Chloroform, DCM, Ethyl Acetate
form 
solid
color 
yellow to dark brown
optical activity
[α]20/D +178°, c = 0.5 in chloroform
Sensitive 
air sensitive
InChI
InChI=1/C21H20N2O2S.C10H10.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-22H,1H3;8H,1-3H3;1H;/q-2;;;+3/p-1/t20-,21-;;;/s3
InChIKey
DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES
[Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
24/25
WGK Germany 
3
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
703915
Product name
RuCl(p-cymene)[(S,S)-Ts-DPEN]
Packaging
100mg
Price
$48.3
Updated
2024/03/01
Sigma-Aldrich
Product number
703915
Product name
RuCl(p-cymene)[(S,S)-Ts-DPEN]
Packaging
500mg
Price
$136
Updated
2024/03/01
TCI Chemical
Product number
R0124
Product name
RuCl[(S,S)-Tsdpen](p-cymene)
Purity
>90%(HPLC)
Packaging
200mg
Price
$55
Updated
2024/03/01
TCI Chemical
Product number
R0124
Product name
RuCl[(S,S)-Tsdpen](p-cymene)
Purity
>90%(HPLC)
Packaging
1g
Price
$177
Updated
2024/03/01
Strem Chemicals
Product number
44-0149
Product name
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
Packaging
250mg
Price
$53
Updated
2024/03/01
More
Less

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemical Properties,Usage,Production

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Solid

Uses

Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut

Uses

Catalyst involved in:

  • Asymmetric transfer hydrogenation of imines and ketones
  • Intramolecular asymmetric reductive amination
  • Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

General Description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Suppliers

China 165 India 7 Japan 1 Switzerland 1 Ukraine 1 United States 8 Global 183
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Protheragen-ING
Tel
+16313385890
Email
info@protheragen-ing.com
Country
United States
ProdList
3868
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52925
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
More
Less

View Lastest Price from (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
RuCl[(S,S)-Tsdpen](p-cymene) 192139-90-5
Price
US $0.00/G
Min. Order
50G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-08
Hangzhou ICH Biofarm Co., Ltd
Product
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2023-06-28
XINXIANG RUNYU MATERIAL CO., LTD.
Product
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
Price
US $0.00-0.00/g
Min. Order
1g
Purity
98%
Supply Ability
500
Release date
2023-02-14

192139-90-5, (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)Related Search:

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Cumene 1,2-Diphenylethane (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (P-CYMENE)RUTHENIUM(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

  • -1,2-diphenylethanediamine(chloro)
  • -N-(p-Toluenesulfonyl)
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
  • RuCl(p-cymene)[(S,S)-Ts-DPEN] Chloro{[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [(1S,2S)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide,chlororuthenium(1+),1-methyl-4-propan-2-ylbenzene
  • [N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-
  • Ruthenium,[N-[(1S,2S)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
  • RuCl(p-cymene)[(S,S)-Ts-DPEN]
  • Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-<br />cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II)
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene)
  • [RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)]
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene)
  • RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
  • [(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride]
  • RuCl[(S,S)- Tsdpen](p-cyMene)
  • (S,S)-N-(p-ToL
  • ethanediamine(chL
  • oro)(p-cymene)ruthenium(II)
  • )-1,2-diphenyL
  • [(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)
  • Chloro(p-cymene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ISO 9001：2015 REACH
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro...
  • [(1S,2S)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide
  • [((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)
  • RuCl[(S,S)-Tsdpen](p-cymene)/Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • ((S,S)-2-Amino-1,2-Diphenylethyl)[(4-Tolyl)Sulfonyl]Amido](P-Cymene)Ruthenium (II)Chloride
  • N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium (ACI)
  • 192139-90-5
  • C32H44ClN2O2RuS
  • organometallic complex
  • Ru