(TRIMETHYLSILYL)METHYLLITHIUM

Product Name: (TRIMETHYLSILYL)METHYLLITHIUM
CAS No.: 1822-00-0
Chemical Name: (TRIMETHYLSILYL)METHYLLITHIUM
Synonyms: Lithiomethyltrimethylsilane;RIMETHYLSILYL)METHYLLITHIUM;methanidyl(trimethyl)silane;Trimethyl(lithiomethyl)silane;Lithio(trimethylsilyl)methane;(TRIMETHYLSILYL)METHYLLITHIUM;Trimethylsiloxy-Methyllithium;Lithium, (trimethylsilyl)methyl-;lithium,methanidyl(trimethyl)silane;(trimethylsilyl)methyllithiumsolution
CBNumber: CB9164114
Molecular Formula: C4H11LiSi
Formula Weight: 94.16
MOL File: 1822-00-0.mol

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(TRIMETHYLSILYL)METHYLLITHIUM Property

Melting point:: 112-117 °C (decomp)
Boiling point:: 35-36 °C
Density: 0.65 g/mL at 25 °C
Flash point:: −57 °F
storage temp.: 2-8°C
solubility: Sol ethereal solvents; reacts with protic solvents.
Specific Gravity: 0.66
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 4123225

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Safety

Hazard Codes: F,C,N,F+
Risk Statements: 11-14-34-51/53-65-66-67-12-2
Safety Statements: 16-26-33-36/37/39-43-45-61-62
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 10
HazardClass: 4.2
PackingGroup: I
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H224Extremely flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 297054
Product name: (Trimethylsilyl)methyllithium solution
Purity: 1.0 M in pentane
Packaging: 50ml
Price: $112
Updated: 2024/03/01

Sigma-Aldrich

Product number: 297054
Product name: (Trimethylsilyl)methyllithium solution
Purity: 1.0 M in pentane
Packaging: 4x25ml
Price: $210
Updated: 2024/03/01

Sigma-Aldrich

Product number: 297054
Product name: (Trimethylsilyl)methyllithium solution
Purity: 1.0 M in pentane
Packaging: 600ml
Price: $751
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ORS0003659
Product name: TRIMETHYLSILYLMETHYLLITHIUM
Purity: 95.00%
Packaging: 100ML
Price: $237.8
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0003659
Product name: TRIMETHYLSILYLMETHYLLITHIUM
Purity: 95.00%
Packaging: 5MG
Price: $499.77
Updated: 2021/12/16

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(TRIMETHYLSILYL)METHYLLITHIUM Chemical Properties,Usage,Production

Chemical Properties

Clear light yellow liquid

Physical properties

mp 112 °C.

Uses

Trimethylsilylmethyllithium is a reagent used in the methylenation of carbonyl compounds; reacts with carboxylic acid derivatives to provide α-silyl ketones; synthesis of allylsilanes. It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Other Electrophiles, etc.

Uses

Initiates polymerization and copolymerization of cyclosiloxanes. Alkylates metal complexes.

Uses

Initiates polymerization and copolymerization of cyclosiloxanes.1 Alkylates metal complexes.2

Preparation

Trimethylsilylmethyllithium is obtained by reaction of (chloromethyl)- trimethylsilane with lithium metal in an inert solvent. It is also available by displacement of a heteroatom group based on sulfur, silicon, or tin.

(TRIMETHYLSILYL)METHYLLITHIUM Preparation Products And Raw materials

Raw materials

Preparation Products

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(TRIMETHYLSILYL)METHYLLITHIUM Suppliers

Belgium 1 CHINA 114 France 2 Germany 1 India 4 Japan 2 Singapore 2 Switzerland 1 United Kingdom 3 United States 8 Global 138

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FMC Lithium

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View Lastest Price from (TRIMETHYLSILYL)METHYLLITHIUM manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (Trimethylsilyl)methyllithium solution 1.0 M in pentane 1822-00-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: lithium,methanidyl(trimethyl)silane 1822-00-0
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-25

1822-00-0, (TRIMETHYLSILYL)METHYLLITHIUMRelated Search:

LITHIUM METHOXIDE ISOBUTYLLITHIUM tert-Butyllithium Lithium bis(trimethylsilyl)amide SEC-BUTYLLITHIUM Methyllithium n-Butyllithium N-HEXYLLITHIUM Lithium diisopropylamide Lithium hexamethyldisilazide METHYLLITHIUM AS COMPLEX WITH LITHIUM Lithium hydride Lithium silicon (TRIMETHYLSILYL)METHYLLITHIUM Lithium TRIMETHYLSILANE Bis(trimethylsilyl)methyllithium Diazo(trimethylsilyl)methyllithium

(TRIMETHYLSILYLMETHYL)LITHIUM , 1.0M SOL UTION IN PENTANE

Lithium, (trimethylsilyl)methyl-

Lithio(trimethylsilyl)methane

Lithiomethyltrimethylsilane

Trimethyl(lithiomethyl)silane

(Trimethylsilyl)methyllithium,0.8M (12 wt%) solution in hexanes

((trimethylsilyl)methyl)lithium 1.0M in pentane

(Trimethylsilyl)methyllithium, 0.8M (12 wt%) solution in hexanes, AcroSeal§3

(Trimethylsilyl)methyllithium, 0.8M (12 wt%) solution in hexanes, AcroSeal

(TriMethylsilyl)MethyllithiuM, 0.7M (10 wt%) solution in hexanes, AcroSeal

TRIMETHYLSILYLMETHYLLITHIUM, 1M in hexane

(TriMethylsilyl) MethyllithiuM, 1.0 M solution in pentane, SpcSeal

(trimethylsilyl)methyllithiumsolution

(TRIMETHYLSILYL)METHYLLITHIUM

(TriMethylsilyl)MethyllithiuM solution in Hexane

(TriMethylsilyl)MethyllithiuM solution 1.0 M in pentane

(TriMethylsilyl) MethyllithiuM, 0.56 M solution in hexanes, SpcSeal

trimethylsilylmethyllithium, 1m in hexane (13-14 wt %)

lithium,methanidyl(trimethyl)silane

lithium(1+) ion (trimethylsilyl)methanide

(Trimethylsilyl)methyllithium, 0.55 M solution in hexanes, J&KSeal

(TRIMETHYLSILYL)METHYLLITHIUM SOLUTION, ~1 M IN PENTANE

(TRIMETHYLSILYL)METHYLLITHIUM ISO 9001：2015 REACH

RIMETHYLSILYL)METHYLLITHIUM

Trimethylsiloxy-Methyllithium

methanidyl(trimethyl)silane

1822-00-0

C4H11LiSi

CH33SiCH2Li

Organolithium

Organometallic Reagents

Alkyl

Chemical Synthesis

Organometallic Reagents

Alkyl

Organolithium

Organometallic Reagents