ACETYL IODIDE Property

Boiling point:

108°C

Density 

d420 2.0674

refractive index 

nD20 1.5491

form 

clear liquid to cloudy liquid

color 

Red to Dark red to Brown

Merck 

14,94

LogP

0.892 (est)

CAS DataBase Reference

507-02-8(CAS DataBase Reference)

EPA Substance Registry System

Acetyl iodide (507-02-8)

Safety

Risk Statements 

34

Safety Statements 

26-36/37/39

RIDADR 

1898

HazardClass 

8

PackingGroup 

II

HS Code 

2914790090

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P234Keep only in original container.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P390Absorb spillage to prevent material damage.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

ACETYL IODIDE Chemical Properties,Usage,Production

Description

Acetyl iodide is a colourless, fuming liquid with a pungent odour. It is soluble in benzene and ether. Acetyl iodide is toxic, corrosive, and reacts with water or steam to produce toxic and corrosive fumes. The vapours of acetyl iodide are irritating to the eyes and mucous membranes. Vapour causes pulmonary oedema. It is corrosive to metals and skin. Acetyl iodide turns brown on exposure to air as it reacts exothermically with moisture in the air to give hydrogen iodide (hydroiodic acid), a strong irritant. It decomposes in water to give acidic products. Inhalation, ingestion, or contact of the skin and the eyes with vapours, dusts, or substance may cause severe injury, burns, or death. Contact with molten form of acetyl iodide causes severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive, or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive, and/ or toxic gases. Run-off from fire control or dilution water may be corrosive and/or toxic and cause pollution.

General Description

A colorless, fuming liquid with a pungent odor. Soluble in benzene and ether (Merck 11th ed., 1989). Vapors are irritating to the eyes and mucous membranes. Vapor causes pulmonary edema. Corrosive to metals and skin.

Air & Water Reactions

Turns brown on exposure to air as ACETYL IODIDE reacts exothermically with moisture in the air to give hydrogen Iodide (hydroiodic acid), a strong irritant. Decomposes in water to give acidic products.

Reactivity Profile

ACETYL IODIDE decomposes exothermically in water or alcohol. Reacts vigorously and exothermically with bases. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A toxic, corrosive material. Reacts with water or steam to produce toxic and corrosive fumes. Dangerous to use. When heated to decomposition it emits toxic fumes of I-. See also IODIDES.

Purification Methods

Purify it by fractional distillation. [Beilstein 2 H 174, 2 I 80, 2 II 177, 2 III 393, 2 IV 399.] TOXIC and LACHRYMATORY.