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Fluroxypyr

Product Name
Fluroxypyr
CAS No.
69377-81-7
Chemical Name
Fluroxypyr
Synonyms
ADVANCE;4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid;((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci;ff4014;ef-689;FLUROXYPYR;Advance(TM);Fluroxypyr(Starane);Fluroxypyr Solution;Fluroxypyr Standard
CBNumber
CB8389671
Molecular Formula
C7H5Cl2FN2O3
Formula Weight
255.03
MOL File
69377-81-7.mol
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Fluroxypyr Property

Melting point:
57.5°C
Boiling point:
399.4±37.0 °C(Predicted)
Density 
1.3
storage temp. 
Sealed in dry,2-8°C
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
2.22±0.10(Predicted)
color 
White to Off-White
Merck 
13,4229
BRN 
7136185
LogP
3.160 (est)
CAS DataBase Reference
69377-81-7(CAS DataBase Reference)
NIST Chemistry Reference
Fluroxypyr(69377-81-7)
EPA Substance Registry System
Fluroxypyr (69377-81-7)
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Safety

Risk Statements 
52/53
Safety Statements 
61
RIDADR 
UN3077(solid)
WGK Germany 
2
RTECS 
AF2500000
Hazardous Substances Data
69377-81-7(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 2405 mg/kg; i.p. in male, female rats: 458, 519 mg/kg; percutaneous in rabbits >5000 mg/kg (Paul)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45758
Product name
Fluroxypyr
Purity
PESTANAL?, analytical standard
Packaging
100mg
Price
$79.8
Updated
2024/03/01
TRC
Product number
F598780
Product name
Fluroxypyr
Packaging
250mg
Price
$205
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000137
Product name
FLUROXYPYR
Purity
95.00%
Packaging
500MG
Price
$721.88
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000137
Product name
FLUROXYPYR
Purity
95.00%
Packaging
5G
Price
$1299.38
Updated
2021/12/16
Atlantic Research Chemicals
Product number
CA002427
Product name
[(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]aceticacid(Fluroxypyr)
Purity
95%
Packaging
250mgs:
Price
$130.78
Updated
2021/12/16
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Fluroxypyr Chemical Properties,Usage,Production

Chemical Properties

White crystalline solid.

Uses

Fluroxypyr is a systemic and selective herbicide. Fluroxypyr is used for the control of broad-leaved weeds in small grain cereals, maize, pastures, range land and turf. Fluroxypyr is a synthetic auxin .

Uses

Fluroxypyr is a systemic and selective herbicide. Fluroxypyr is used for the control of broad-leaved weeds in small grain cereals, maize, pastures, range land and turf. Fluroxypyr is a synthetic auxin.

Definition

ChEBI: An aminopyridine that is pyridin-4-amine substituted by chloro groups at positions 3 and 5, a fluoro group at position 6 and a carboxymethoxy group at position 2.

Trade name

methyl ester: AGROSTAR; BOFIX FFC®; CABADEX®; CASCADE®; DOWCO® 433 MHE; FOREFRONT®; GALAXY GL184®; PARADIGM®; PASTUREGARD®; STARANE®; TOMAHAWK®; VISTA®; WIDEMATCH®, (fluroxypyr + clopyralid); XRM-5084®

Potential Exposure

Those who manufacture, distribute or use this pyridinecarboxylic acid/pyridine herbicide.

Environmental Fate

The DT50 in soil is relatively short, ranging from 5 to 9 days in experiments conducted in the laboratory. This rapid degradation is due to microbes.Because of its rapid soil degradation, little fluroxypyr is available for other dissipation processes, e.g., leaching.

Metabolism

Fluroxypyr is stable under acidic conditions and moderately stable in alkaline conditions; e.g., the DT50 in water at pH 9 is 185 days. Degradation occurs at temperatures above its melting point. Fluroxypyr is stable in light.
Plant. The metabolism of fluroxypyr has not been fully described. Conjugates of fluroxypyr have been observed in tolerant plants.
Soil. Fluroxypyr is rapidly metabolized by soil microbes via the removal of the carboxyl group or acetic acid group, yielding 4-amino-3,5-dichloro-6-fluoro- 2-methoxypyridine, and 4-amino-3,5-dichloro-6-fluoro-2- pyridinol, respectively.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.

Toxicity evaluation

Mammalian Toxicity. Fluroxypyr appears to be rapidly excreted, unmodified, in the urine of animals. The acute oral LD50 for rat is 2405 mg/kg.
Weed Resistance/Modified Crop Tolerance. Fuerst et al. (48) reported fluroxypyr resistance in yellow starthistle (Centaurea solstitialis). No crops with modified tolerance toward fluroxypyr are currently in production.

Incompatibilities

May not be compatible with nitrates. Moisture may cause hydrolysis or other forms of decompo sition; forming a strong acid. Temperatures above 250℃ can cause decomposition. Methyl ester: Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is suffi ciently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solu tions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Waste Disposal

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an after burner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti cide containers.

Fluroxypyr Preparation Products And Raw materials

Raw materials

Preparation Products

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Fluroxypyr Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
15421
Advantage
60
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7815
Advantage
57
Shanghai Fuhe Chemistry Technology Co., Ltd.
Tel
0086-21-67651709
Fax
0086-21-67651705
Email
cfx759@hotmail.com
Country
China
ProdList
410
Advantage
57
BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14059
Advantage
65
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Nanjing Sunlida Biological Technology Co., Ltd.
Tel
025-57798810
Fax
025-57019371
Email
sales@sunlidabio.com
Country
China
ProdList
3750
Advantage
55
TargetMol Chemicals Inc.
Tel
021-33632979 15002134094
Fax
021-33632979
Email
marketing@targetmol.com
Country
China
ProdList
7934
Advantage
58
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9986
Advantage
55
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View Lastest Price from Fluroxypyr manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Fluroxypyr 69377-81-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2023-02-06
Longyan Tianhua Biological Technology Co., Ltd
Product
Fluroxypyr 69377-81-7
Price
US $40.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-10-29
Career Henan Chemical Co
Product
Fluroxypyr 69377-81-7
Price
US $11.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KG
Release date
2018-08-16

69377-81-7, FluroxypyrRelated Search:


  • ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci
  • 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid
  • ff4014
  • [(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]acetic acid
  • 2-[(4-AMino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic Acid
  • Fluroxypyr Solution, 1000ppm
  • 2-((4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy)acetic acid
  • Aceticacid, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]-
  • 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid octan-2-yl ester
  • ADVANCE
  • ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)acetic acid
  • ef-689
  • FLUROXYPYR
  • 4,5-amino-3,5-dichloro-6-fluoro-2-pyridinyloxyacetic acid
  • fluroxypyr 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid
  • 2-(4-Amino-3,5-dichloro-6-fluoropyrin-2-yl)oxyacetic acid
  • Fluroxypyr(Starane)
  • FLUROXYPYR PESTANAL (4-AMINO-3,5-DI CHLO
  • Acetic acid, (4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy-
  • fluroxypyr (bsi,iso)
  • Advance(TM)
  • Fluroxypyr Solution
  • Fluroxypyr Standard
  • Fluroxypyr @100 μg/mL in MeOH
  • Commercial Fluroxypyr 250g/L EC Selective Broadleaf Herbicide 69377-81-7
  • 69377-81-7
  • C7H5CI2FN2O3
  • C7H5Cl2FN2O3
  • Alpha sort
  • E-GAlphabetic
  • F
  • FA - FLPesticides&Metabolites
  • Herbicides
  • Pesticides&Metabolites
  • Pyridine