ChemicalBook > CAS DataBase List > (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide

Product Name
(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
CAS No.
361342-51-0
Chemical Name
(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
Synonyms
(11br);SF110009;-2,6-Di(anthracen-9-yl);1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide;(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d;]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one;-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diylhydrogenphosphate;(R)-3,3-Bis(9-Antracenyl)-1,1'-binaphthyl-2,2'-yldiyl-hydrogenphosphate;(R)-3,3′-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
CBNumber
CB92098112
Molecular Formula
C48H29O4P
Formula Weight
700.72
MOL File
361342-51-0.mol
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(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide Property

Melting point:
288-292 °C (D)
Density 
1.46±0.1 g/cm3(Predicted)
storage temp. 
-20°C
pka
1.11±0.20(Predicted)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29199000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695718
Product name
(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Purity
95%
Packaging
100mg
Price
$230
Updated
2024/03/01
Sigma-Aldrich
Product number
695718
Product name
(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Purity
95%
Packaging
500mg
Price
$1090
Updated
2024/03/01
Matrix Scientific
Product number
118713
Product name
(R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
Purity
97.6%
Packaging
500mg
Price
$1313
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0004331
Product name
(R)-3,3'-BIS(9-ANTHRACENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
Purity
95.00%
Packaging
250MG
Price
$1360.8
Updated
2021/12/16
AK Scientific
Product number
4556AB
Product name
(11br)-2,6-Di(anthracen-9-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Packaging
500mg
Price
$1822
Updated
2021/12/16
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(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide Chemical Properties,Usage,Production

Uses

Catalyst used in asymmetric direct alkylation of α-diazoester via C-H bond cleavage.

(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide Suppliers

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361342-51-0, (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxideRelated Search:

R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-2,6-bis([1,1'-biphenyl]-4-yl)-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate R-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-3,3'-Bis(3,5-diphenyl)phenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate S-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

  • SF110009
  • (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
  • (R)-3,3μ-Bis(9-anthracenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 2,6-di-9-anthracenyl-4-hydroxy-, 4-oxide, (11bR)-
  • (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (2r)-2,6-di(anthracen-9-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (11br)
  • -2,6-Di(anthracen-9-yl)
  • -4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (R)-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.
  • (R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate,(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
  • (11Br)-2,6-Di(anthracen-9-yl)-4-hydroxydinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (R)-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%
  • (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
  • 1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
  • (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d
  • ]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
  • (R)-3,3-Bis(9-Antracenyl)-1,1'-binaphthyl-2,2'-yldiyl-hydrogenphosphate
  • (11bR)-2,6-Di(anthracen-9-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (R)-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diylhydrogenphosphate
  • (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (R)-3,3′-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • 361342-51-0
  • 36948-67-4
  • C48H29O4P