ChemicalBook > CAS DataBase List > 1-Hydroxy-2,1-benzoxaborolane

1-Hydroxy-2,1-benzoxaborolane

Product Name
1-Hydroxy-2,1-benzoxaborolane
CAS No.
5735-41-1
Chemical Name
1-Hydroxy-2,1-benzoxaborolane
Synonyms
AKOS BRN-0113;Boronophthalide;2,1-Benzoxaborol-1(3H)-ol;1-HYDROXY-2,1-BENZOXABOROLANE;1-Hydroxy-1,2-benzoxaborolane;2-(Hydroxymethyl)Phenylboronic;1-hydroxy-3H-2,1-benzoxaborole;Benzo[c][1,2]oxaborol-1(3H)-ol;1,3-Dihydro-1-hydroxybenzoxaborole;1,3-Dihydro-1-hydroxy-2,1-benzoxaborole
CBNumber
CB9222511
Molecular Formula
C7H7BO2
Formula Weight
133.94
MOL File
5735-41-1.mol
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1-Hydroxy-2,1-benzoxaborolane Property

Melting point:
95-100 °C
Boiling point:
237.2±43.0 °C(Predicted)
Density 
1.18±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,2-8°C
pka
7.01±0.20(Predicted)
form 
powder to crystal
color 
White to Almost white
BRN 
4333
CAS DataBase Reference
5735-41-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
Hazard Note 
Irritant/Keep Cold
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
682071
Product name
2-(Hydroxymethyl)phenylboronic acid cyclic monoester
Purity
97%
Packaging
1g
Price
$77.6
Updated
2024/03/01
Sigma-Aldrich
Product number
682071
Product name
2-(Hydroxymethyl)phenylboronic acid cyclic monoester
Purity
97%
Packaging
5g
Price
$108.4
Updated
2024/03/01
TCI Chemical
Product number
H1280
Product name
2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester
Packaging
1g
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
H1280
Product name
2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester
Packaging
5g
Price
$216
Updated
2024/03/01
TRC
Product number
H972563
Product name
2-Hydroxymethylphenylboronicacid,dehydrated
Packaging
1g
Price
$75
Updated
2021/12/16
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1-Hydroxy-2,1-benzoxaborolane Chemical Properties,Usage,Production

Chemical Properties

Solid

Uses

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.

Definition

ChEBI: 1-hydroxy-2,1-benzoxaborole is a member of the class of benzoxaboroles that is 2,1-benzoxaborole in which the hydrogen attached to the boron atom is replaced by a hydroxy group.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 835, 1958 DOI: 10.1021/ja01537a021

1-Hydroxy-2,1-benzoxaborolane Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Hydroxy-2,1-benzoxaborolane Suppliers

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View Lastest Price from 1-Hydroxy-2,1-benzoxaborolane manufacturers

LY Global chemicals co.,ltd .
Product
1-Hydroxy-2,1-benzoxaborolane 5735-41-1
Price
US $0.00/kg
Min. Order
1kg
Purity
98.0%min
Supply Ability
100kg
Release date
2023-03-19
Career Henan Chemical Co
Product
1-Hydroxy-2,1-benzoxaborolane 5735-41-1
Price
US $1.00/g
Min. Order
1g
Purity
96%-98%
Supply Ability
1000KGS
Release date
2019-12-20

5735-41-1, 1-Hydroxy-2,1-benzoxaborolaneRelated Search:

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  • AKOS BRN-0113
  • 2-(HYDROXYMETHYL)BENZENEBORONIC ACID CYCLIC MONOESTER
  • (2-HYDROXYMETHYL)BENZENEBORONIC ACID DEHYDRATE
  • 2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER
  • 2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYCLIC MONOESTER
  • (2-HYDROXYMETHYLPHENYL)BORONIC ACID DEHYDRATE
  • 2-(HYDROXYMETHYL)PHENYLBORONIC ACID, DIHYDRATE
  • 1-HYDROXY-2,1-BENZOXABOROLANE
  • 1-Hydroxy-2,1-benzoxaborolane~2-(Hydroxymethyl)phenylboronic acid cyclic monoester
  • 2,1-Benzoxaborol-1(3H)-ol
  • 2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYC&
  • 1-Hydroxy-1,2-benzoxaborolane
  • 2-(Hydroxymethyl)Phenylboronic
  • 2-(Hydroxymethyl)benzeneboronic acid dehydrate 98%
  • 1-Hydroxy-2,1-benzoxaborolane, Alt cas [87199-14-2]
  • 2-Hydroxymethylphenylboronic acid, dehydrated
  • 1,3-Dihydro-1-hydroxy-2,1-benzoxaborole, 2-(Hydroxymethyl)phenylboronic acid hemiester
  • 1-hydroxy-3H-2,1-benzoxaborole
  • Benzo[c][1,2]oxaborol-1(3H)-ol
  • 1,3-Dihydro-1-hydroxy-2,1-benzoxaborole
  • 2,1-Benzoxaborole, 1,3-dihydro-1-hydroxy-
  • 2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER, 98+%
  • 1,3-Dihydro-1-hydroxybenzoxaborole
  • Boronophthalide
  • 5735-41-1
  • C7H7BO2
  • BORONIC ACID
  • blocks
  • BoronicAcids