ChemicalBook > CAS DataBase List > Propargyl-3-sulfopropyl ether sodium salt

Propargyl-3-sulfopropyl ether sodium salt

Product Name
Propargyl-3-sulfopropyl ether sodium salt
CAS No.
30290-53-0
Chemical Name
Propargyl-3-sulfopropyl ether sodium salt
Synonyms
POPS;popsliquid;Propargyl-3-Sulfopropyl;Propargyl (3-sulfopropyl) ether;Propargyl-3-sulfopropyl ether sodium;Propargyl-3-sulfopropyl ether,Na salt;Sodium propargyl ether propane sulfonate;SODIUM 3-(PROP-2-YNYLOXY)PROPANE-1-SULFONATE;PROPARGYL (3-SULFOPROPYL) ETHER, SODIUM SALT;Sodium 3-(prop-2-yn-1-yloxy)propane-1-sulfonate
CBNumber
CB9228896
Molecular Formula
C6H11NaO4S
Formula Weight
202.2
MOL File
30290-53-0.mol
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Propargyl-3-sulfopropyl ether sodium salt Property

Density 
1.21 at 20℃
vapor pressure 
0-2992.94Pa at 25℃
form 
Liquid
InChI
InChI=1S/C6H10O4S.Na.H/c1-2-4-10-5-3-6-11(7,8)9;;/h1H,3-6H2,(H,7,8,9);;
InChIKey
QZGFGSLFVLDKEY-UHFFFAOYSA-N
SMILES
C(S(O)(=O)=O)CCOCC#C.[NaH]
LogP
-4.1
Surface tension
72.53-72.79mN/m at 1g/L and 19.9℃
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ING0006683
Product name
PROPARGYL-3-SULFOPROPYL ETHER SODIUM SALT
Purity
95.00%
Packaging
100MG
Price
$1188.5
Updated
2021/12/16
Crysdot
Product number
CD00004897
Product name
Sodium3-(prop-2-yn-1-yloxy)propane-1-sulfonate
Purity
97%
Packaging
100g
Price
$60
Updated
2021/12/16
Crysdot
Product number
CD00004897
Product name
Sodium3-(prop-2-yn-1-yloxy)propane-1-sulfonate
Purity
97%
Packaging
500g
Price
$180
Updated
2021/12/16
Crysdot
Product number
CD00004897
Product name
Sodium3-(prop-2-yn-1-yloxy)propane-1-sulfonate
Purity
97%
Packaging
1000g
Price
$270
Updated
2021/12/16
Alichem
Product number
30290530
Product name
Sodium3-(prop-2-yn-1-yloxy)propane-1-sulfonate
Packaging
1000g
Price
$400
Updated
2021/12/16
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Propargyl-3-sulfopropyl ether sodium salt Chemical Properties,Usage,Production

Description

Propargyl-3-sulfopropyl ether sodium salt is a sulfonate used as a co-brightener with glycerol in the electroplating industry. It is also used as an alkaline industrial chemical that can be used to remove tellurium from glass and ceramics. Propargyl-3-sulfopropyl ether sodium salt is prepared by reacting propargyl alcohol with sodium sulfite and ethylene diamine. This reaction produces propargyl sulfonic acid, which reacts with ethylene oxide to form the desired product.

Uses

Propargyl-3-sulfopropyl ether sodium salt is a sulfonate used as a co-brightener with glycerol in the electroplating industry. It is also used as an alkaline industrial chemical for removing tellurium from glass and ceramics.

Synthesis

Propargyl-3-sulfopropyl ether sodium salt is prepared by the reaction of 1,3-propanesultone and propargyl alcohol. The specific synthesis steps are as follows:
To a chilled (5 °C) slurry of NaH (60% in mineral oil, 1.60 g, 40.9 mmol, 1.0 equiv.) in dry DMF (30 mL) was added dropwise a solution of propargyl alcohol (2.4 mL, 40.9 mmol, 1.0 equiv.) in dry DMF (30 mL) over a ten minute period. I ,3-Propanesultone (5.0 g, 40.9 minol, 1.0 equiv.) was dissolved in dry DMF (30mL), and the resulting solution added dropwise over a five minute period to the chilled sodium propargylate solution. After stirring for ten minutes in the ice bath, the flask was transferred to an oil bath and heated at 60°C for three hours. Most of the DMF was then removed by rotavap, and the remaining oil was triturated with 200 mL diethyl ether to yield a white solid, which was collected by vacuum filtration. The product was driedunder vacuum to provide Propargyl-3-sulfopropyl ether sodium salt as a white powder (7.4 g, 90%).

Propargyl-3-sulfopropyl ether sodium salt Preparation Products And Raw materials

Raw materials

Preparation Products

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