2-BROMO-4-METHYL-6-NITROANILINE
- Product Name
- 2-BROMO-4-METHYL-6-NITROANILINE
- CAS No.
- 827-24-7
- Chemical Name
- 2-BROMO-4-METHYL-6-NITROANILINE
- Synonyms
- 2-BROMO-4-METHYL-6-NITROANILINE;2-BROMO-4-METHYL-6-NITROBENZENAMINE;2-BROMO-4-METHYL-6-NITRO-PHENYLAMINE;Benzenamine, 2-bromo-4-methyl-6-nitro-;4-Amino-3-bromo-5-nitrotoluene, 2-Bromo-6-nitro-p-toluidine
- CBNumber
- CB9231193
- Molecular Formula
- C7H7BrN2O2
- Formula Weight
- 231.05
- MOL File
- 827-24-7.mol
2-BROMO-4-METHYL-6-NITROANILINE Property
- Melting point:
- 64-66
- Boiling point:
- 329.1±37.0 °C(Predicted)
- Density
- 1.698±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- -1.74±0.25(Predicted)
- Appearance
- Light brown to orange Solid
- InChI
- InChI=1S/C7H7BrN2O2/c1-4-2-5(8)7(9)6(3-4)10(11)12/h2-3H,9H2,1H3
- InChIKey
- VFPKZASVVCBVMG-UHFFFAOYSA-N
- SMILES
- C1(N)=C([N+]([O-])=O)C=C(C)C=C1Br
- CAS DataBase Reference
- 827-24-7(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
- HS Code
- 2921420090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B677970
- Product name
- 2-Bromo-4-methyl-6-nitroaniline
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4755-9-X0
- Product name
- 2-Bromo-4-methyl-6-nitroaniline
- Packaging
- 5G
- Price
- $52
- Updated
- 2021/12/16
- Product number
- V7891
- Product name
- 2-Bromo-4-methyl-6-nitroaniline
- Packaging
- 25g
- Price
- $94
- Updated
- 2021/12/16
- Product number
- 4755-9-X0
- Product name
- 2-Bromo-4-methyl-6-nitroaniline
- Packaging
- 25g
- Price
- $180
- Updated
- 2021/12/16
- Product number
- 045534
- Product name
- 2-Bromo-4-methyl-6-nitroaniline
- Purity
- >95%
- Packaging
- 500mg
- Price
- $181
- Updated
- 2021/12/16
2-BROMO-4-METHYL-6-NITROANILINE Chemical Properties,Usage,Production
Synthesis
89-62-3
827-24-7
4-Methyl-2-nitroaniline (131.2 g, 862 mmol) was used as a raw material and suspended in glacial acetic acid (1.25 L). Bromine (54 mL, 1.05 mol) was added slowly over 1 h at ambient temperature. After addition, the reaction mixture was continued to be stirred for 1 hour. Subsequently, the reaction solution was poured into water (7.5 L) and the suspension was stirred for 30 minutes. The solid product was collected by filtration, washed thoroughly with water (5 x 1 L) and dried to give 2-bromo-4-methyl-6-nitroaniline (187.2 g, 94%) as an orange solid. Its 1H NMR (CDCl3) data were as follows: δ 7.94 (1H, s), 7.56 (1H, s), 6.47 (2H, br s), 2.27 (3H, s).
References
[1] Organic Letters, 2006, vol. 8, # 22, p. 4989 - 4992
[2] Chemistry - A European Journal, 2015, vol. 21, # 52, p. 18915 - 18920
[3] Journal of Labelled Compounds and Radiopharmaceuticals, 1995, vol. 36, # 3, p. 281 - 288
[4] Journal of Antibiotics, 1994, vol. 47, # 12, p. 1456 - 1465
[5] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 20, p. 6026 - 6032
2-BROMO-4-METHYL-6-NITROANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
2-BROMO-4-METHYL-6-NITROANILINE Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 2-BROMO-4-METHYL-6-NITROANILINE manufacturers
- Product
- 2-BROMO-4-METHYL-6-NITROANILINE 827-24-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-09