Cyclohexene oxide

Product Name: Cyclohexene oxide
CAS No.: 286-20-4
Chemical Name: Cyclohexene oxide
Synonyms: 7-OXABICYCLO[4.1.0]HEPTANE;1,2-EPOXYCYCLOHEXANE;1,2-epoxy-cyclohexan;EPOXYCYCLOHEXANE;(1R,6S)-7-Oxabicyclo[4.1.0]heptane;HXO;Ccho;ohexene oxide;7-Oxanorcarane;Cyclohexenoxide
CBNumber: CB9244511
Molecular Formula: C6H10O
Formula Weight: 98.14
MOL File: 286-20-4.mol

More

Less

Cyclohexene oxide Property

Melting point:: -40 °C
Boiling point:: 129-130 °C(lit.)
Density: 0.97 g/mL at 25 °C(lit.)
vapor pressure: 12 hPa (20 °C)
refractive index: n20/D 1.452(lit.)
Flash point:: 81 °F
storage temp.: Store below +30°C.
form: Liquid
color: Clear colorless to yellow
explosive limit: 1.2-6.5%(V)
Water Solubility: INSOLUBLE
BRN: 383568
CAS DataBase Reference: 286-20-4(CAS DataBase Reference)
NIST Chemistry Reference: Cyclohexene oxide(286-20-4)
EPA Substance Registry System: Cyclohexene oxide (286-20-4)

More

Less

Safety

Hazard Codes: C
Risk Statements: 10-20/21/22-34
Safety Statements: 26-36/37/39-45-16
RIDADR: UN 2924 3/PG 3
WGK Germany: 1
RTECS: RN7175000
Autoignition Temperature: 703 °F
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 29109000
Hazardous Substances Data: 286-20-4(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 1060 mg/kg LD50 dermal Rabbit 612 mg/kg

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C102504
Product name: Cyclohexene oxide
Purity: 98%
Packaging: 25ml
Price: $50.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: C102504
Product name: Cyclohexene oxide
Purity: 98%
Packaging: 100ml
Price: $57.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.21862
Product name: Epoxycyclohexane
Purity: for synthesis
Packaging: 50mL
Price: $41.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.21862
Product name: Epoxycyclohexane
Purity: for synthesis
Packaging: 250ML
Price: $86.9
Updated: 2024/03/01

TCI Chemical

Product number: O0071
Product name: 1,2-Epoxycyclohexane
Purity: >98.0%(GC)
Packaging: 25mL
Price: $27
Updated: 2024/03/01

More

Less

Cyclohexene oxide Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

Cyclohexene oxide has been patented for use as an insecticidal fumigant.
Cyclohexene oxide is an important intermediate in the organic industry. It is employed in the manufacture of medicines, pesticides, dyes, and perfumes. In addition, cyclohexene oxide can be used as a monomer in polymerization, chain-cutting agent, flame retardant and diluting agent among other uses.
Cyclohexene oxide is useful as a monomer in polymerization with CO2 for production of cyclic carbonates and polycarbonates in the presence of different catalysts.

Uses

It is an important raw material and intermediate used in organic synthesis, dyestuffs and in agrochemical industries. It is used in medicine. Cyclohexene oxide (epoxycyclohexane) is an useful monomer in polymerization and coating industry. It is used in the synthesis of alicyclic target materials including pharmaceuticals, perfumery and dyestuffs. It is used as a monomer in photopolymerizations, with carbonmonoxide to yield aromatic polycarbonates which has minimum impurities.

Synthesis Reference(s)

The Journal of Organic Chemistry, 38, p. 1251, 1973 DOI: 10.1021/jo00946a053
Tetrahedron Letters, 29, p. 2967, 1988 DOI: 10.1016/0040-4039(88)85059-7

Flammability and Explosibility

Flammable

Safety Profile

Moderately toxic by ingestion, skin contact, intraperitoneal, and intramuscular routes. Mildly toxic by inhalation. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A flammable liquid and dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritant fumes.

Purification Methods

Fractionate the oxide through an efficient column. The main impurity is probably H2O. Dry it over MgSO4, filter and distil it several times (b 129-134o/760mm). The residue is sometimes hard to remove from the distilling flask. To avoid this difficulty, add a small amount of a mixture of ground NaCl and Celite (1:1) to help break up the residue particularly if H2O is added. [Osterberg Org Synth Coll Vol I 185 1948, Beilstein 17 H 21, 17/1 V 203.]

Cyclohexene oxide Preparation Products And Raw materials

Raw materials

Boron oxide TRIMETHYLANTIMONY Cyclohexene Hydrogen peroxide Diglyme 1,4-Dioxane Tungsten hexacarbonyl

Preparation Products

Propargite E.C. Propargite 2-(4-TERT-BUTYLPHENOXY)CYCLOHEXANOL

More

Less

Cyclohexene oxide Suppliers

Americas 1 Belgium 4 China 165 China Hong Kong 1 Czech Republic 1 Europe 1 Germany 10 India 4 Italy 1 Japan 8 South Korea 1 Switzerland 2 Ukraine 3 United Kingdom 9 United States 34 Global 246

Dexin chemical (Shandong) Co. , Ltd.

Tel: 15853369661
Email: 1092794701@qq.com
Country: China
ProdList: 121
Advantage: 58

Zhengzhou KeYulong chemical products Co., Ltd

Tel: 17319789407
Fax: 0371-53335504
Email: Keyulongchem@163.com
Country: China
ProdList: 1993
Advantage: 55

Yikang Chemical（Hubei）Co.， LTD

Tel: 027-18971353-902 18971353902
Email: 2242508613@qq.com
Country: China
ProdList: 7871
Advantage: 58

Shanghai Wohua Chemical Co., Ltd.

Tel: 021-57681602-802 17302146015
Fax: 57683062-808
Email: 2851602437@qq.com
Country: China
ProdList: 289
Advantage: 58

Jinan Junhe Pharmaceutical Co., Ltd

Tel: 18560864701 18560864701
Email: 957395144@qq.com
Country: China
ProdList: 1583
Advantage: 58

Hubei Xinjiecheng Chemical Technology Co., Ltd

Tel: 13554075426
Email: 1014723310@qq.com
Country: China
ProdList: 3004
Advantage: 58

Qingdao Baiyi Chemical Co., Ltd

Tel: 13053388919; 13053388919
Email: 1454485610@qq.com
Country: China
ProdList: 511
Advantage: 58

shandongbaqianhehuagong

Tel: 15865655795
Email: 263501023@qq.com
Country: China
ProdList: 43
Advantage: 58

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

More

Less

View Lastest Price from Cyclohexene oxide manufacturers

Henan Fengda Chemical Co., Ltd

Product: Cyclohexene oxide 286-20-4
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-25

Honest Joy Holdings Limited

Product: 7-oxabicyclo[4.1.0]heptane 286-20-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.7%
Supply Ability: 100 tons
Release date: 2022-02-18

Career Henan Chemical Co

Product: Cyclohexene oxide 286-20-4
Price: US $10.00/KG/Tin
Min. Order: 1KG
Purity: 99%
Supply Ability: 100
Release date: 2019-06-28

286-20-4, Cyclohexene oxideRelated Search:

Iron oxide Rutile Methylcyclohexane Cyclohexene Cyclohexanecarboxylic acid Magnesium oxide Zirconium dioxide Heptane ETHYLENE OXIDE NITRIC OXIDE Calcium hydroxide Calcium oxide Zinc oxide Cyclohexane Iron oxide black 2-Cyclohexen-1-one Ethylcyclohexane Chlorocyclohexane

1,2-epoxy-cyclohexan

2,3-tetramethyleneoxirane

7-oxabicyclo(3.1.0)heptane

Bicyclo[4.1.0]heptane, 7-oxa-

Ccho

cis-1,2-epoxycyclohexane

Cyclohexane, 1,2-epoxy-

cyclohexane,1,2-epoxy-

cyclohexaneoxide

Cyclohexene 1-oxide

Cyclohexene epoxide

cyclohexene-1-oxide

cyclohexene1-oxide

cyclohexeneepoxide

Cyclohexylene oxide

cyclohexyleneoxide

Tetramethyleneoxirane

EPOXYCYCLOHEXANE

HXO

CYCLOHEXENE OXIDE

1,2-CYCLOHEXENEEPOXIDE

1，2-Cyclohexene oxide

1,2-EPOXYCYCLOHEXANE

7-OXABICYCLO[4.1.0]HEPTANE

ohexene oxide

Cyclohexene oxide, 98+%

CYCLOGEXANEOXIDE

1,2-Epoxycyclohexane, 7-Oxabicyclo[4.1.0]heptane

(1R)-1β,2β-Epoxycyclohexane

(1R,1β,6β)-7-Oxabicyclo[4.1.0]heptane

(1R,6S)-7-Oxabicyclo[4.1.0]heptane

(1S,6R)-7-Oxabicyclo[4.1.0]heptane

(1β,6β)-7-Oxabicyclo[4.1.0]heptane

7-Oxanorcarane

Cyclohexene oxide,1,2-Epoxycyclohexane, 7-Oxabicyclo[4.1.0]heptane

Cyclohexenoxide

Cyclohexene oxide, 1,2-Epoxycyclohexane

Cyclohexene oxide, 98% 100ML

Cyclohexene Oxide 7-Oxabicyclo[4.1.0]heptane

Cyclohexene oxide 98%

1,2-Epoxycyclohexane 7-Oxabicyclo[4.1.0]heptane Epoxycyclohexane

Epoxycyclohexane for synthesis

1,2-Epoxycyclohexane&gt

Cyclohexene oxide ISO 9001：2015 REACH

cyclohexene oxide radical cation

286-20-4

286-30-4

110838

Oxygen Compounds

Organic Building Blocks

Epoxides

Building Blocks

Alcohol& Phenol& Ethers

Pharmaceutical Intermediates

K00001