TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE

Product Name: TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE
CAS No.: 187283-17-6
Chemical Name: TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE
Synonyms: 4-(BroMoMethyl)benzylcarbaMate;4-(Boc-aMinoMethyl)benzylbroMide;N-BOC-4-(BROMOMETHYL)BENZYLAMINE;benzyl 4-(bromomethyl)benzylcarbamate;TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE;4-(tert-Butoxycarbonylaminomethyl)benzyl bromide;(4-BroMoMethyl-benzyl)-carbaMic acid tert-butyl ester;tert-butyl N-[[4-(bromomethyl)phenyl]methyl]carbamate;Carbamic acid, N-[[4-(bromomethyl)phenyl]methyl]-, 1,1-dimethylethyl ester
CBNumber: CB92467354
Molecular Formula: C13H18BrNO2
Formula Weight: 300.19
MOL File: 187283-17-6.mol

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TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to light yellow Solid

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Safety

HS Code: 2921490090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC

Product number: B129570
Product name: tert-Butyl4-(Bromomethyl)benzylcarbamate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB140213
Product name: tert-Butyl 4-(Bromomethyl)benzylcarbamate
Packaging: 500mg
Price: $55
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB140213
Product name: tert-Butyl 4-(Bromomethyl)benzylcarbamate
Packaging: 1g
Price: $93
Updated: 2021/12/16

Matrix Scientific

Product number: 073837
Product name: tert-Butyl 4-(bromomethyl)benzylcarbamate
Purity: 95+%
Packaging: 500mg
Price: $144
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB140213
Product name: tert-Butyl 4-(Bromomethyl)benzylcarbamate
Packaging: 2g
Price: $161
Updated: 2021/12/16

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TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE Chemical Properties,Usage,Production

Synthesis

123986-64-1

187283-17-6

General procedure for the synthesis of tert-butyl 4-(bromomethyl)benzylcarbamate from tert-butyl 4-(hydroxymethyl)benzylcarbamate: 4-(N-tert-butoxycarbonylaminomethyl)benzyl alcohol (250 mg, 1.1 mmol) was dissolved in tetrahydrofuran (5 mL) and cooled down to -78 °C. At this temperature, phosphorotriamine (30 μL, 0.32 mmol) was slowly added and the reaction lasted for 2 hours. Upon completion of the reaction, solid sodium bicarbonate (50 mg) was added to quench the reaction. The solid insoluble material was removed by filtration and the filtrate was subsequently evaporated to afford the target product 4-(tert-butoxycarbonylaminomethyl)benzyl bromide (300 mg, 95% yield).

References

[1] Patent: US6680311, 2004, B1. Location in patent: Page/Page column 151
[2] Journal of Medicinal Chemistry, 2009, vol. 52, # 1, p. 33 - 47
[3] Patent: WO2006/117549, 2006, A1. Location in patent: Page/Page column 155
[4] Chemical Science, 2017, vol. 8, # 12, p. 7947 - 7953

TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE Suppliers

China 80 Germany 1 India 1 United Kingdom 2 United States 7 Global 91

Wuhan Henruixintai Biological Co., Ltd.

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Wuhan Kaymke Chemical Co., Ltd.,

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View Lastest Price from TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE manufacturers

Career Henan Chemical Co

Product: tert-Butyl 4-(bromomethyl)benzylcarbamate 187283-17-6
Price: US $10.00-100.00/KG
Min. Order: 1KG
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2020-03-06

187283-17-6, TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATERelated Search:

4-Bromomethypiperidine-1-carboxylic acid tert-butyl ester TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE tert-butyl 4-(bromomethyl)-1H-indole-1-carboxylate 2-(tert-Butylamino)ethyl methacrylate

TERT-BUTYL 4-(BROMOMETHYL)BENZYLCARBAMATE

4-(BroMoMethyl)benzylcarbaMate

N-BOC-4-(BROMOMETHYL)BENZYLAMINE

4-(Boc-aMinoMethyl)benzylbroMide

(4-BroMoMethyl-benzyl)-carbaMic acid tert-butyl ester

Carbamic acid, N-[[4-(bromomethyl)phenyl]methyl]-, 1,1-dimethylethyl ester

tert-butyl N-[[4-(bromomethyl)phenyl]methyl]carbamate

benzyl 4-(bromomethyl)benzylcarbamate

4-(tert-Butoxycarbonylaminomethyl)benzyl bromide

187283-17-6