Diisopropylchlorosilane

Product Name: Diisopropylchlorosilane
CAS No.: 2227-29-4
Chemical Name: Diisopropylchlorosilane
Synonyms: CHLORODIISOPROPYLSILANE;Diisopropylsilyl chloride;DK677;DK220;DKFELEX0170;DIISOPROPYLCHLOROSILANE;Chlorodiisopropylsilane >chlorobis(propan-2-yl)silane;chloro-di(propan-2-yl)silicon;Silane, chlorobis(1-methylethyl)-
CBNumber: CB9249415
Molecular Formula: C6H15ClSi
Formula Weight: 150.72
MOL File: 2227-29-4.mol

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Diisopropylchlorosilane Property

Boiling point:: 58-60 °C50 mm Hg(lit.)
Density: 0.883 g/mL at 25 °C(lit.)
refractive index: n20/D 1.429(lit.)
Flash point:: 72 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: generally sol organic solvents; reacts with alcohols, ammonia,and water.
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.883
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 2231355
InChI: InChI=1S/C6H15ClSi/c1-5(2)8(7)6(3)4/h5-6,8H,1-4H3
InChIKey: CGXYLRTYLIHXEE-UHFFFAOYSA-N
SMILES: [SiH](Cl)(C(C)C)C(C)C
CAS DataBase Reference: 2227-29-4(CAS DataBase Reference)
EPA Substance Registry System: Silane, chlorobis(1-methylethyl)- (2227-29-4)

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Safety

Hazard Codes: C
Risk Statements: 10-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2986 8/PG 2
WGK Germany: 3
F: 10-21
TSCA: Yes
HazardClass: 3.1
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 375896
Product name: Chlorodiisopropylsilane
Purity: 99%
Packaging: 5g
Price: $107
Updated: 2023/06/20

Sigma-Aldrich

Product number: 375896
Product name: Chlorodiisopropylsilane
Purity: 99%
Packaging: 25g
Price: $381
Updated: 2023/06/20

TCI Chemical

Product number: C1492
Product name: Chlorodiisopropylsilane
Purity: >95.0%(GC)
Packaging: 5mL
Price: $106
Updated: 2024/03/01

TCI Chemical

Product number: C1492
Product name: Chlorodiisopropylsilane
Purity: >95.0%(GC)
Packaging: 25mL
Price: $514
Updated: 2024/03/01

TRC

Product number: C602298
Product name: Chlorodiisopropylsilane
Packaging: 2.5mg
Price: $75
Updated: 2021/12/16

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Diisopropylchlorosilane Chemical Properties,Usage,Production

Physical properties

bp 150–153°C,bp 54–55°C/45 mmHg; d 0.872 gmL?1

Uses

Intramolecular hydrosilylation is also possible within β-diisopropylsilyloxy esters (13), constituting an exceptionally mild method for reducing ester groups to the aldehyde oxidation level (eq 4).The derivatives (13) may be synthesized from β-hydroxy esters (12) as described above for the analogous ketones. Treatment with fluoride ions (but not Lewis acids) induces hydride transfer to give alkoxysiladioxanes (14) in excellent yields (≥95%). Although usually performed in dichloromethane, the hydrosilylation may also be accomplished with ethyl acetate as solvent, providing strong evidence for intramolecularity.

Preparation

obtained by reaction of trichlorosilane with isopropylmagnesium chloride;the original yield of 45% may be raised to 70–80% by employing conc hydrochloric acid to quench the reaction.

Application

Used in a silylation-reduction-allylation sequence of β-hydroxy esters to homoallylic-substituted 1,3-diols. Used in the silylation-hydrosilation-oxidation of allyl alcohols to 1,3-diols. Reaction carried out in diastereoselective manner. Reduces β-hydroxy ketones to anti-1,3 diols.

Purification Methods

Impurities can be readily detected by 1H NMR. Purify it by fractional distillation [Gilman & Clark J Am Chem Soc 69 1499 1947, Allen et al. J Chem Soc 3668 1957].

Diisopropylchlorosilane Preparation Products And Raw materials

Raw materials

Preparation Products

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Diisopropylchlorosilane Suppliers

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View Lastest Price from Diisopropylchlorosilane manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: DIISOPROPYLCHLOROSILANE 2227-29-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1000KG /month
Release date: 2021-11-26

Career Henan Chemical Co

Product: DIISOPROPYLCHLOROSILANE 2227-29-4
Price: US $3.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2020-01-30

2227-29-4, DiisopropylchlorosilaneRelated Search:

tert-Butylchlorodiphenylsilane Dichloromethane N-OCTYLDIISOPROPYLCHLOROSILANE DI-TERT-BUTYLDICHLOROSILANE 1,3-DICHLORO-1,1,3,3-TETRAISOPROPYLDISILOXANE DIISOPROPYLCHLOROSILANE Triisopropylsilyl chloride 1,1,3,3-TETRACYCLOPENTYLDICHLORODISILOXANE DI-TERT-BUTYLCHLOROSILANE 3-CYANOPROPYLDIISOPROPYLCHLOROSILANE DI-T-BUTYLMETHYLCHLOROSILANE DIISOPROPYLDICHLOROSILANE BIPHENYLDIISOPROPYLSILYL CHLORIDE PHENETHYLDIISOPROPYLCHLOROSILANE Dicyclopentyldichlorosilane DICYCLOHEXYLDICHLOROSILANE PHENYLETHENYLDIISOPROPYLCHLOROSILANE DICYCLOHEXYLMETHYLCHLOROSILANE

chloro(2,3-dimethylbutan-2-yl)silicon

Silane, chlorobis(1-methylethyl)-

CHLORODIISOPROPYLSILANE

DIISOPROPYLCHLOROSILANE

Diisopropylsilyl chloride

chloro-di(propan-2-yl)silicon

Chlorodiisopropylsilane &gt

chlorobis(propan-2-yl)silane

C6H15ClSi DIISOPROPYLCHLOROSILANE 2227-29-4

DK220

DK677

DKFELEX0170

2227-29-4

CH32CH2SiHCl

Silicon-Based

Synthetic Reagents

Protection and Derivatization

Protecting and Derivatizing Reagents

Monochlorosilanes

Reduction

Si-H Compounds

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Si-Cl Compounds

Pharmaceutical Intermediates

Monochlorosilanes

Reduction

Si (Classes of Silicon Compounds)

Si-Cl Compounds

Si-H Compounds

Silicon Compounds (for Synthesis)

Synthetic Organic Chemistry