Reaction
ChemicalBook > CAS DataBase List > Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]

Reaction
Product Name
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
CAS No.
944451-14-3
Chemical Name
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
Synonyms
(S)-[(RuCl(DM-SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-DM-SEGPHOS))2(Μ-CL)3];[NH2Me2][(RuCl((S)-dm-segphos[R]))2(μ-Cl)3];[NH2Me2][(RuCl((S)-dm-segphos(regR)))2(μ-Cl)3];[NH2Me2][(RuCl((S)-dm-segphos(regR)))2(mu-Cl)3];Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dM-segphos)}2(μ-Cl)3];Dimethylammonium dichlorotri(mu-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos)}2(mu-Cl)3;Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3]
CBNumber
CB92512474
Molecular Formula
C94H100Cl5NO8P4Ru2
Formula Weight
1875.12
MOL File
944451-14-3.mol
More
Less

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
light brown
Sensitive 
air sensitive
More
Less

Safety

Hazard Codes 
F
Risk Statements 
11
RIDADR 
UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all
WGK Germany 
3
HS Code 
2843.90.0000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
N1024
Product name
[NH2Me2][(RuCl((S)-dm-segphos[R]))2(μ-Cl)3]
Packaging
200mg
Price
$66
Updated
2024/03/01
TCI Chemical
Product number
N1024
Product name
[NH2Me2][(RuCl((S)-dm-segphos[R]))2(μ-Cl)3]
Packaging
1g
Price
$223
Updated
2024/03/01
Strem Chemicals
Product number
44-0521
Product name
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3]
Packaging
250mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
44-0521
Product name
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3]
Packaging
1g
Price
$190
Updated
2024/03/01
Strem Chemicals
Product number
44-0521
Product name
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3]
Packaging
5g
Price
$474
Updated
2024/03/01
More
Less

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Chemical Properties,Usage,Production

Reaction

  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters. 
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. 

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Suppliers

TCI EUROPE N.V.
Tel
--
Fax
--
Email
sales@tcieurope.be
Country
Belgium
ProdList
2200
Advantage
66

944451-14-3, Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]Related Search:


  • Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
  • DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dM-segphos)}2(μ-Cl)3]
  • (S)-[(RuCl(DM-SEGPHOS))2(μ-Cl)3][NH2Me2]
  • [NH2Me2][(RuCl((S)-dm-segphos(regR)))2(mu-Cl)3]
  • [NH2ME2][(RUCL((S)-DM-SEGPHOS))2(Μ-CL)3]
  • Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3]
  • [NH2Me2][(RuCl((S)-dm-segphos[R]))2(μ-Cl)3]
  • Dimethylammonium dichlorotri(mu-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos)}2(mu-Cl)3
  • Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)
  • [NH2Me2][(RuCl((S)-dm-segphos(regR)))2(μ-Cl)3]
  • 944451-14-3
  • C94H99Cl5NO8P4Ru2