Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)

Application Reaction

Product Name: Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
CAS No.: 12131-44-1
Chemical Name: Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Synonyms: Cinnamylpalladium chloride dimer;PalladiuM(II)(π-cinnaMyl) Chloride DiMer;adium(π-cinnamyL;Palladium(π-cinnamyl;Di-mu-chlorobis[(1,2,3-η;BIS[CINNAMYL PALLADIUM(II) CHLORIDE];Palladium(pi-cinnamyl) chloride dimer;Palladium(II)(2-cinnamyl) Chloride Dimer;PalladiuM(II)(pi-cinnaMyl) Chloride DiMer;PalladiuM(pi-cinnaMyl) chloride diMer 97%
CBNumber: CB92521021
Molecular Formula: C18H12Cl2Pd2
Formula Weight: 512.03
MOL File: 12131-44-1.mol

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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Property

Melting point:: 218-220°C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystal
color: yellow
Sensitive: air sensitive

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Safety

Hazard Codes: T
Risk Statements: 23-43
Safety Statements: 36/37-45
RIDADR: UN 2811 6.1 / PGIII
WGK Germany: 3
HS Code: 2843909000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H331Toxic if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 720526
Product name: Palladium(π-cinnamyl) chloride dimer
Purity: 97%
Packaging: 1g
Price: $158
Updated: 2024/03/01

TCI Chemical

Product number: P2017
Product name: Palladium(II)(π-cinnamyl) Chloride Dimer
Purity: >97.0%(T)
Packaging: 200mg
Price: $73
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0295
Product name: Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98%
Packaging: 500mg
Price: $74
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0295
Product name: Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98%
Packaging: 2g
Price: $224
Updated: 2024/03/01

TRC

Product number: D438900
Product name: Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium
Packaging: 100mg
Price: $70
Updated: 2021/12/16

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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Chemical Properties,Usage,Production

Application

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.

Reaction

Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .

Uses

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:

Ammonia cross-coupling reactions to synthesize arylamines.
Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Suppliers

China 130 India 3 Japan 1 United Kingdom 3 United States 8 Global 145

Shaanxi Rock New Materials Co., Ltd.

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View Lastest Price from Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-16

henan kanbei chemical co.,ltd

Product: Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Longyan Tianhua Biological Technology Co., Ltd

Product: Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-10

12131-44-1, Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)Related Search:

polymer CROTYLPALLADIUM CHLORIDE DIMER Allylpalladium(II) Chloride Dimer Benzeneruthenium(II) chloride dimer Palladium chloride Choline chloride CERIUM(III) CHLORIDE HEPTAHYDRATE Zinc chloride Lithium chloride monohydrate Sodium chloride Calcium chloride Lanthanum(III) chloride Bismuth trichloride METHOXYCARBONYLSULFENYL CHLORIDE Nickel chloride (T-4)-Dichloro[(oxydi-2,1-phenylene)bis[diphenylphosphine]]nickel DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) HYDROXY(1,5-CYCLOOCTADIENE)RHODIUM(I)DIMER

Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98%

Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladiuM(II),98%

Cinnamylpalladium chloride dimer

PalladiuM(II)(pi-cinnaMyl) Chloride DiMer

PalladiuM(II)(π-cinnaMyl) Chloride DiMer

PalladiuM(pi-cinnaMyl) chloride diMer 97%

Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(Ⅱ)

Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium

BIS[CINNAMYL PALLADIUM(II) CHLORIDE]

)-1-phenyl-2-propenyl]dipalladium(II), 98%

Di-mu-chlorobis[(1,2,3-η

Palladium(II)(pi-cinnamyl)ChlorideDimer&gt

adium(π-cinnamyL

Palladium(pi-cinnamyl) chloride dimer

Di( μ -chloro)bis(η 3- cinnamyl)dipalladium(II)

Palladium(II)(2-cinnamyl) Chloride Dimer

Palladium(π-cinnamyl

Di-mu-chlorobis[(1,2,3-eta)-1-phenyl-2-propen-1-yl]dipalladium

12131-44-1

C18H18Cl2Pd2

C9H9ClPd2

Pd