2,4-Dichlorobenzoic acid

ChemicalBook > CAS DataBase List > 2,4-Dichlorobenzoic acid

2,4-Dichlorobenzoic acid

Product Name: 2,4-Dichlorobenzoic acid
CAS No.: 50-84-0
Chemical Name: 2,4-Dichlorobenzoic acid
Synonyms: 2,4-DCBA;2,4-Dichlorobenzoic;2,4-Dichlolrobenzoic Acid;Benzoic acid, 2,4-dichloro-;'LGC' (1305);2.4-Dichlorobe;orbenzoic acid;AKOS BBS-00003747;Dichlorbenzoic aci;RARECHEM AL BO 0324
CBNumber: CB9255955
Molecular Formula: C7H4Cl2O2
Formula Weight: 191.01
MOL File: 50-84-0.mol

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2,4-Dichlorobenzoic acid Property

Melting point:: 157-160 °C (lit.)
Boiling point:: 200 °C
Density: 1.4410 (rough estimate)
refractive index: 1.4590 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: ethanol: soluble1g/10 mL, clear, colorless
form: Powder
pka: 2.68±0.25(Predicted)
color: White to almost white
PH: 2.8 (0.36g/l, H2O, 15℃)
Water Solubility: 0.36 g/L (15 ºC)
BRN: 1868192
Stability:: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference: 50-84-0(CAS DataBase Reference)
NIST Chemistry Reference: 2,4-Dichlorobenzoic acid(50-84-0)
EPA Substance Registry System: Benzoic acid, 2,4-dichloro- (50-84-0)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36-37/39-22
WGK Germany: 3
RTECS: DG6650000
Hazard Note: Irritant
TSCA: Yes
HS Code: 29163900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 139572
Product name: 2,4-Dichlorobenzoic acid
Purity: 98%
Packaging: 5g
Price: $36.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 139572
Product name: 2,4-Dichlorobenzoic acid
Purity: 98%
Packaging: 100g
Price: $40.1
Updated: 2024/03/01

TCI Chemical

Product number: D0337
Product name: 2,4-Dichlorobenzoic Acid
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: D0337
Product name: 2,4-Dichlorobenzoic Acid
Purity: >97.0%(GC)(T)
Packaging: 500g
Price: $73
Updated: 2024/03/01

Alfa Aesar

Product number: A12372
Product name: 2,4-Dichlorobenzoic acid, 98%
Packaging: 250g
Price: $37.65
Updated: 2024/03/01

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2,4-Dichlorobenzoic acid Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

2,4-Dichlorobenzoic Acid is a di-halogenated benzoic acid derivative and an intermediate in the synthesis of spirodiclofen (S682990), a tetronic acid acaricide fungicide used in controlling red mites.

Uses

2,4-Dichlorobenzoic acid is used as reagent during the synthesis of pyrimido[2?,1?:2,3]thiazolo[4,5-b]quinoxaline derivatives. It is also used as starting reagent during the synthesis of 1-(substituted)-1,4-dihydro-6-nitro-4-oxo-7-(sub-secondary amino)-quinoline-3-carboxylic acids.

Definition

ChEBI: A chlorobenzoic acid that is benzoic acid in which the ring hydrogens at positions 2 and 4 are substituted by chloro groups.

General Description

White to slightly yellowish powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2,4-Dichlorobenzoic acid is a halogenated carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in 2,4-Dichlorobenzoic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Fire Hazard

Flash point data for 2,4-Dichlorobenzoic acid are not available; however, 2,4-Dichlorobenzoic acid is probably combustible.

Purification Methods

Crystallise the acid from aqueous EtOH (charcoal), then *benzene (charcoal). It can also be recrystallised from water. [Beilstein 9 IV 998.] It can be freed from isomeric acids (to <0.05%) via the (±)--methylbenzylamine salt as follows: dissolve the dichloro-acid (10g, 50.2mmol) in isopropanol (200mL), heat to 60o and add the (±)-benzylamine (5.49g, 45.3mmol), then stir it at 60o for 1hour. Cool the mixture to room temperature, filter the slurry, wash it with isopropanol (25mL) and dry it in vacuo at 40o overnight to give 79% of the salt with m 185.2o. Dissolve the salt (5g) in H2O (50mL) and MeOH (20mL), then heat to 60o and add concentrated HCl to pH <2.0. Cool the solution to room temperature add H2O (12mL), filter it, wash it with H2O (30mL) and dry it in vacuo at 40o overnight to give 94% of the acid with m 162.0o. [Ley & Yates Organic Process Research & Development 12 120 2008.]

2,4-Dichlorobenzoic acid Preparation Products And Raw materials

Raw materials

2,4-Dichlorotoluene 2,3,4,5,6-PENTACHLOROTOLUENE 2,4-Diaminotoluene PHOSGENE Copper(I) chloride Potassium formate Potassium permanganate 2,4-Dichlorobenzoyl chloride

Preparation Products

Lobenzarit ETHYL 2,4-DICHLOROBENZOATE Furosemide 2,4-Dichlorobenzonitrile 2,4-Dichloro-5-sulfamoylbenzoic acid 7-CHLORO-10-(4-HYDROXYANILINO)-2-METHOXY BENZO(B)-1,5-NAPHTHY RIDINE 2,4-DICHLORO-3,5-DINITROBENZOIC ACID 6-chloro-1H-indazol-3-amine 4-CHLORO-2-(4-METHOXY-PHENYLAMINO)-BENZOIC ACID 2,4-Dichlorobenzoyl chloride

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View Lastest Price from 2,4-Dichlorobenzoic acid manufacturers

Speranza Chemical Co., Ltd.

Product: 2,4-Dichlorobenzoic acid 50-84-0
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 300MT/year
Release date: 2019-12-24

Hebei Weibang Biotechnology Co., Ltd

Product: 2,4-Dichlorobenzoic acid 50-84-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-20

Hebei Chuanghai Biotechnology Co,.LTD

Product: 2,4-Dichlorobenzoic acid 50-84-0
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99.9
Supply Ability: 1 ton
Release date: 2024-08-21

50-84-0, 2,4-Dichlorobenzoic acidRelated Search:

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2,4-Dichlorobenzoic acid, 98% 100GR

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2,4-Dichlorobenzoic Acid 98% For Synthesis

50-84-0

50-48-0

Carbonyl Compounds

Carboxylic Acids

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