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4-Methyl-3-(hydroxyMethyl)Morpholine

Product Name
4-Methyl-3-(hydroxyMethyl)Morpholine
CAS No.
1159598-86-3
Chemical Name
4-Methyl-3-(hydroxyMethyl)Morpholine
Synonyms
4-Methyl-3-morpholinemethanol;3-Morpholinemethanol, 4-methyl-;(4-Methylmorpholin-3-yl)methanol;4-Methyl-3-(hydroxyMethyl)Morpholine
CBNumber
CB92629985
Molecular Formula
C6H13NO2
Formula Weight
131.17
MOL File
1159598-86-3.mol
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4-Methyl-3-(hydroxyMethyl)Morpholine Property

Boiling point:
201.1±15.0 °C(Predicted)
Density 
1.031±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
14.85±0.10(Predicted)
Appearance
Colorless to light yellow Liquid
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B585958
Product name
4-Methyl-3-(hydroxymethyl)morpholine
Packaging
100mg
Price
$240
Updated
2021/12/16
ChemScene
Product number
CS-0061777
Product name
(4-Methylmorpholin-3-yl)methanol
Packaging
100mg
Price
$93
Updated
2021/12/16
ChemScene
Product number
CS-0061777
Product name
(4-Methylmorpholin-3-yl)methanol
Packaging
250mg
Price
$155
Updated
2021/12/16
ChemScene
Product number
CS-0061777
Product name
(4-Methylmorpholin-3-yl)methanol
Packaging
1g
Price
$309
Updated
2021/12/16
Apolloscientific
Product number
OR55495
Product name
4-Methyl-3-(hydroxymethyl)morpholine
Purity
95%
Packaging
1g
Price
$432
Updated
2021/12/16
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4-Methyl-3-(hydroxyMethyl)Morpholine Chemical Properties,Usage,Production

Synthesis

50-00-0

106910-83-2

1159598-86-3

Step 2: Preparation of (4-methylmorpholin-3-yl)methanol To a solution of morpholin-3-ylmethanol (0.540 g, 4.6 mmol) in methanol (20 mL) was added formaldehyde (1.86 g, 23 mmol, 37% aqueous solution) and palladium/carbon catalyst (0.200 g). The reaction mixture was stirred overnight at room temperature under hydrogen atmosphere (1.0 atm). Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent ratio: methanol:dichloromethane=1:15) to afford (4-methylmorpholin-3-yl)methanol (0.130 g, 22% yield) as a yellow oil.

References

[1] Patent: US2016/168090, 2016, A1. Location in patent: Paragraph 0927-0928

4-Methyl-3-(hydroxyMethyl)Morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Methyl-3-(hydroxyMethyl)Morpholine Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 4-Methyl-3-(hydroxyMethyl)Morpholine manufacturers

Nanjing jinheyou Trading Co., Ltd.
Product
4-Methyl-3-(hydroxyMethyl)Morpholine 1159598-86-3
Price
US $0.00/g
Min. Order
1g
Purity
95%min
Supply Ability
20kg/month
Release date
2019-11-19
Nanjing jinheyou Trading Co., Ltd.
Product
4-Methyl-3-(hydroxyMethyl)Morpholine 1159598-86-3
Price
US $0.00/g
Min. Order
1g
Purity
95%min
Supply Ability
20kg/month
Release date
2019-11-19