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tert-butyl 2-(3-broMophenyl)acetate

Product Name
tert-butyl 2-(3-broMophenyl)acetate
CAS No.
197792-52-2
Chemical Name
tert-butyl 2-(3-broMophenyl)acetate
Synonyms
tert-butyl 2-(3-broMophenyl)acetate;Benzeneacetic acid, 3-bromo-, 1,1-dimethylethyl ester
CBNumber
CB92706129
Molecular Formula
C12H15BrO2
Formula Weight
271.15
MOL File
197792-52-2.mol
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tert-butyl 2-(3-broMophenyl)acetate Property

storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
InChI
InChI=1S/C12H15BrO2/c1-12(2,3)15-11(14)8-9-5-4-6-10(13)7-9/h4-7H,8H2,1-3H3
InChIKey
IUQYZZLJRJUKIH-UHFFFAOYSA-N
SMILES
C1(CC(OC(C)(C)C)=O)=CC=CC(Br)=C1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
6003DL
Product name
Tert-butyl2-(3-bromophenyl)acetate
Packaging
2.5g
Price
$266
Updated
2021/12/16
AK Scientific
Product number
6003DL
Product name
Tert-butyl2-(3-bromophenyl)acetate
Packaging
10g
Price
$680
Updated
2021/12/16
Ambeed
Product number
A213991
Product name
tert-Butyl2-(3-bromophenyl)acetate
Purity
95%
Packaging
100mg
Price
$22
Updated
2021/12/16
Ambeed
Product number
A213991
Product name
tert-Butyl2-(3-bromophenyl)acetate
Purity
95%
Packaging
250mg
Price
$33
Updated
2021/12/16
Ambeed
Product number
A213991
Product name
tert-Butyl2-(3-bromophenyl)acetate
Purity
95%
Packaging
1g
Price
$79
Updated
2021/12/16
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tert-butyl 2-(3-broMophenyl)acetate Chemical Properties,Usage,Production

Synthesis

1694-31-1

591-18-4

197792-52-2

General procedure for the synthesis of tert-butyl 2-(3-bromophenyl)acetate: 1-bromo-3-iodobenzene (1.0 mmol), CuI (9.5 mg, 0.05 mmol), 2-pyridinecarboxylic acid (12 mg, 0.10 mmol), and cesium carbonate (978 mg, 3.0 mmol) were added to a Schlenk tube. The reaction tube was evacuated and displaced three times with argon, followed by the addition of tert-butyl acetoacetate (2.0 mmol) and 1,4-dioxane (2 mL). The reaction tube was placed in an oil bath and the reaction mixture was stirred at the indicated temperature for 33-48 hours. After completion of the reaction, the mixture was cooled and partitioned with ethyl acetate and saturated NH4Cl solution. The organic layer was separated, washed with brine, dried over anhydrous Na2SO4 and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography with the eluent petroleum ether/ethyl acetate (20:1 to 3:1) to afford the target product tert-butyl 2-(3-bromophenyl)acetate.

References

[1] Tetrahedron, 2014, vol. 70, # 20, p. 3327 - 3332

tert-butyl 2-(3-broMophenyl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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197792-52-2, tert-butyl 2-(3-broMophenyl)acetateRelated Search:

Tetrabutyl titanate

  • tert-butyl 2-(3-broMophenyl)acetate
  • Benzeneacetic acid, 3-bromo-, 1,1-dimethylethyl ester
  • 197792-52-2