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Nadic anhydride

Product Name
Nadic anhydride
CAS No.
826-62-0
Chemical Name
Nadic anhydride
Synonyms
NADIC ANHYDRIDE;NADIC ANHYDRIDE;5-NORBORNENE-2,3-DICARBOXYLIC ANHYDRIDE;NADIC ANHYDRIDE 98%;3A,4,7,7A-TETRAHYDRO-4,7-METHANOISOBENZOFURAN-1,3-DIONE;(3aR,4S,7R,7aS)-3a,4,7,7a-Tetrahydro-4,7-Methanoisobenzofuran-1,3-dione;NA-anhydride;Nadic anhydrous;EBDIC ANHYDRIDE;HIMIC ANHYDRIDE
CBNumber
CB9274095
Molecular Formula
C9H8O3
Formula Weight
164.16
MOL File
826-62-0.mol
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Nadic anhydride Property

Melting point:
165-167 °C(lit.)
Boiling point:
251.61°C (rough estimate)
Density 
1.2132 (rough estimate)
refractive index 
1.5260 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
diethyl ether: soluble0.1g/10 mL, clear, colorless
form 
powder to crystal
Specific Gravity
1.250 (20/4℃)
color 
White to Almost white
Merck 
14,1796
BRN 
150228
InChI
InChI=1S/C9H8O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h1-2,4-7H,3H2
InChIKey
KNDQHSIWLOJIGP-UHFFFAOYSA-N
SMILES
C1(=O)C2C(C3CC2C=C3)C(=O)O1
LogP
-0.040 (est)
CAS DataBase Reference
826-62-0(CAS DataBase Reference)
EPA Substance Registry System
4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydro- (826-62-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
41-42/43
Safety Statements 
22-24-26-37/39
RIDADR 
UN 1325
WGK Germany 
3
RTECS 
DT5600000
21
HS Code 
38220090
Toxicity
skn-rbt 500 mg/24H MLD 28ZPAK -,140,72
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
14353
Product name
Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride
Purity
≥95.0%
Packaging
250g
Price
$164
Updated
2024/03/01
TCI Chemical
Product number
N0331
Product name
5-Norbornene-2,3-dicarboxylic Anhydride
Purity
>97.0%(T)
Packaging
25g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
N0331
Product name
5-Norbornene-2,3-dicarboxylic Anhydride
Purity
>97.0%(T)
Packaging
500g
Price
$85
Updated
2024/03/01
Matrix Scientific
Product number
172490
Product name
Bicyclo[2.2.1]-5-heptene-2,3-dicarboxylic anhydride
Packaging
100g
Price
$108
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK325920
Product name
5-Norbornene-2,3-dicarboxylic Anhydride
Purity
95%
Packaging
100g
Price
$53
Updated
2021/12/16
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Nadic anhydride Chemical Properties,Usage,Production

Description

The substance 5-norbornene-2,3-dicarboxylic anhydride has a purity of approximately 99.5 % and consists of two isomers, cis-5-norbrene-endo-2,3-dicarboxylic anhydride (99.2 %) and cis-5-norbreneexo-2,3-dicarboxylic anhydride (0.3 %). It has an estimated log Po/w = 2.3. Due to its chemical nature as an anhydride it readily hydrolyses into the free diacid, norbornene-2,3-dicarboxylic acid. Therefore, migration into aqueous foodstuffs will also lead to the presence of the two isomeric diacids. Melting point of the substance is 163-165 °C.

Chemical Properties

white solid

Uses

5-Norbornene-2,3-dicarboxylic anhydride, as a copolymer monomer in polyester can coatings up to 18.3 % w/w in the final dry coating, does not pose a safety concern to the consumer under sterilised conditions and prolonged contact with all foodstuffs (except beverages).

Application

Nadic anhydride, also known as 5-Norbornene-2,3-dicarboxylic anhydride, is an organic anhydride derivative of norbornene. Besides its use as a component of polyester can coatings in foodstuffs, it is also used as an organic synthesis intermediate. 5-Norbornene-2,3-dicarboxylic anhydride (NA) can lower the cPC content of a polymerization reaction under zinc glutarate catalysis (3 MPa CO2, 60 °C, 0.8 wt% catalyst in neat PO) from 4.5% to about 1%, even if the anhydride concentration is as low as 0.3 mol%.

Reactions

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride reacts with methyl aminomethyllambertianate to give amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent.

Safety Profile

Mild skin and severe eye irritant.When heated to decomposition it emits acrid smoke andirritating fumes.

Toxicity evaluation

In a cytogenetic test in vitro, 5-norbornene-2,3-dicarboxylic anhydride was clastogenic both in presence and absence of an exogenous metabolic activation system. Gene mutation assays in bacteria and cultured mammalian cells provided negative results. When administered to rats by the oral route at the maximum tolerated dose, 5-norbornene-2,3-dicarboxylic anhydride was not clastogenic/aneugenic in bone marrow, and did not induce DNA damage in liver and at the site of first contact (stomach) in a combined micronucleus and comet assay. It is concluded that the clastogenic activity of 5-norbornene2,3-dicarboxylic anhydride observed in vitro is not expressed in vivo, and that 5-norbornene-2,3- dicarboxylic anhydride does not raise concern for genotoxicity.

Nadic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Nadic anhydride Suppliers

Shanghai LanRun Chemical Co., Ltd.
Tel
021-69515658 ; 69515628 13701998368
Fax
021-69515998
Email
longrunchem@163.com
Country
China
ProdList
3912
Advantage
50
Henan Research New Material Co., Ltd.
Tel
1890-3931531 18903931628
Email
sales036@researchvip.com
Country
China
ProdList
182
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
Advantage
62
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-0393-8910800 15036113989
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
557
Advantage
64
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View Lastest Price from Nadic anhydride manufacturers

Shanghai UCHEM Inc.
Product
Himic anhydride 826-62-0
Price
US $28.00/kg
Min. Order
1kg
Purity
0.98
Supply Ability
100kg
Release date
2023-10-26
Henan Research New Materials Co., Ltd.
Product
Nadic Anhydride (NA) 826-62-0
Price
US $0.00/KG
Min. Order
1KG
Purity
≥98.0
Supply Ability
1000KG
Release date
2021-07-05
Hebei Chuanghai Biotechnology Co,.LTD
Product
Himic Anhydride 826-62-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

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