3-BENZYLOXYANILINE

Product Name: 3-BENZYLOXYANILINE
CAS No.: 1484-26-0
Chemical Name: 3-BENZYLOXYANILINE
Synonyms: AKOS BC-2549;AKOS BBB/398;3-BENZYLOXYANILINE;TIMTEC-BB SBB000388;M-(BENZYLOXY)ANILINE;3-Benzyloxyaniline 98%;3-Benzyloxyaniline,98%;3-Benzyloxyaniline >3-(Phenylmethoxy)aniline;3-(benzyloxy)phenylamine
CBNumber: CB9282029
Molecular Formula: C13H13NO
Formula Weight: 199.25
MOL File: 1484-26-0.mol

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3-BENZYLOXYANILINE Property

Melting point:: 63-67 °C (lit.)
Boiling point:: 170 °C(Press: 3 Torr)
Density: 1.129±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: soluble in Methanol
pka: 4.17±0.10(Predicted)
form: Solid
color: Pale brown
InChI: InChI=1S/C13H13NO/c14-12-7-4-8-13(9-12)15-10-11-5-2-1-3-6-11/h1-9H,10,14H2
InChIKey: IGPFOKFDBICQMC-UHFFFAOYSA-N
SMILES: C1(N)=CC=CC(OCC2=CC=CC=C2)=C1
CAS DataBase Reference: 1484-26-0(CAS DataBase Reference)
EPA Substance Registry System: 3-(Benzyloxy)aniline (1484-26-0)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: 2811
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29222990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 100803
Product name: 3-Benzyloxyaniline
Purity: 98%
Packaging: 10g
Price: $148.4
Updated: 2025/07/31

TCI Chemical

Product number: B4197
Product name: 3-Benzyloxyaniline
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $29
Updated: 2025/07/31

TCI Chemical

Product number: B4197
Product name: 3-Benzyloxyaniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $83
Updated: 2025/07/31

TRC

Product number: B288573
Product name: 3-Benzyloxyaniline
Packaging: 500mg
Price: $60
Updated: 2021/12/16

Matrix Scientific

Product number: 017113
Product name: 3-(Benzyloxy)aniline
Purity: 97%
Packaging: 5g
Price: $67
Updated: 2021/12/16

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3-BENZYLOXYANILINE Chemical Properties,Usage,Production

Chemical Properties

Beige to tan powder

Synthesis Reference(s)

Tetrahedron Letters, 23, p. 147, 1982 DOI: 10.1016/S0040-4039(00)86770-2

Synthesis

24318-00-1

1484-26-0

591-27-5

Using 1-(benzyloxy)-3-nitrobenzene as the starting material, the reaction was carried out using an experimental method similar to that of Example 59, in which ferrous acetate (II), nickel nitrate (II), or cobalt acetylacetonate (III) was chosen as the metal reducing agent. The experimental results are detailed in Table 11. The data of Examples 60 to 66 show that the reaction rate is significantly enhanced when metal compounds such as iron, nickel or cobalt salts and amine additives such as pyrrolidine are added to the catalytic reduction system of the present invention in the presence of a rhodium/carrier catalyst. Under this condition, functional groups such as benzyl ether, which are easy to reduce, are retained, and nitro is selectively reduced to amino, thereby increasing the yield of the target products 3-benzyloxyaniline and 3-aminophenol.

References

[1] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[2] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[3] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[4] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[5] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45

3-BENZYLOXYANILINE Preparation Products And Raw materials

Raw materials

Benzyl chloride Ferrous acetate Acetone Potassium carbonate Tetrahydrofuran Hydrogen 4-Nitrophenol Rhodium

Preparation Products

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3-BENZYLOXYANILINE Suppliers

Americas 1 China 139 Europe 1 Germany 2 India 4 Japan 2 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 6 United States 17 Global 175

AbaChemScene

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Alchem Pharmtech,Inc.

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Aladdin Scientific

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Combi-Blocks Inc.

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Frontier Scientific, Inc.

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Matrix Scientific

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HONEST JOY HOLDINGS LIMITED

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3B Scientific Corporation

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Cambridge Major Laboratories, Inc

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ASDI Incorporated

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Precursor Chemicals, Inc.

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TimTec Corporation

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View Lastest Price from 3-BENZYLOXYANILINE manufacturers

Career Henan Chemical Co

Product: 3-BENZYLOXYANILINE 1484-26-0
Price: US $0.01/KG
Min. Order: 1KG
Purity: 98%; 99%
Supply Ability: 1kg; 10kg; 25kg
Release date: 2020-01-07

Career Henan Chemical Co

Product: 3-BENZYLOXYANILINE 1484-26-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98
Supply Ability: 10t
Release date: 2019-12-18

1484-26-0, 3-BENZYLOXYANILINERelated Search:

1,4-DIBENZYLOXY-2-NITROBENZENE 3-BENZYLOXYANILINE Nequinate 1-(Benzyloxy)-2-methyl-3-nitrobenzene 3-BENZYLOXYPHENYL ISOTHIOCYANATE p-Benzyloxyaniline,4-BENZYLOXYANILINE 2-BENZYLOXYANILINE 4-BENZYLOXYANILINE HYDROCHLORIDE,P-BENZYLOXYANILINE HYDROCHLORIDE,4-BENZYLOXYANILINE HYDROCHLORIDE 98% 7-NITRO-3,4-BENZOCOUMARIN 5-(benzyloxy)-2-fluoroaniline 4-BENZYLOXY-2-NITROTOLUENE 4-BENZYLOXY-2-NITROANILINE 2-(BENZYLOXY)-4-NITROANILINE 2-BENZYLOXY-5-CHLORO-4-NITRO-PHENYLAMINE 4-BENZYLOXY-3-METHOXY-6-B-DINITROSTYRENE 2-(2,2-DIMETHYLPROPANOYL)-3-((3-(BENZYLOXY)PHENYL)AMINO)PROP-2-ENENITRILE 3-[4-(BENZYLOXY)-5-METHOXY-2-NITROPHENYL]ACRYLIC ACID 3,3-DIMETHYL-1-(3-[(4-NITROBENZYL)OXY]PHENYL)-2-AZETANONE

Benzenamine, 3-(phenylmethoxy)-

M-(BENZYLOXY)ANILINE

3-BENZYLOXYANILINE

AKOS BBB/398

AKOS BC-2549

TIMTEC-BB SBB000388

3-Aminophenyl benzyl ether

3-Benzyloxyaniline 98%

3-(benzyloxy)phenylamine

3-(Phenylmethoxy)aniline

3-Benzyloxyaniline,98%

3-Amino-alpha-phenylanisole

3-Benzyloxyaniline &gt

3-BENZYLOXYANILINE ISO 9001：2015 REACH

1484-26-0

Building Blocks

Amines

C11 to C37

Organic Building Blocks

Nitrogen Compounds

Anilines, Aromatic Amines and Nitro Compounds

Amines

C11 to C38

Nitrogen Compounds