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Pyridine sulfur trioxide

Product Name
Pyridine sulfur trioxide
CAS No.
26412-87-3
Chemical Name
Pyridine sulfur trioxide
Synonyms
SULFUR TRIOXIDE PYRIDINE COMPLEX;sulfur trioxide pyridine;PYRIDINE SULFUR TRIOXIDE COMPLEX;NSC 75831;PyridineSO3;fur trioxide;Pyridine suL;Sulfur trioxide pyri;sulfonylideneoxidane;Pyridine sulfur trio
CBNumber
CB9284694
Molecular Formula
C5H5NO3S
Formula Weight
159.16
MOL File
26412-87-3.mol
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Pyridine sulfur trioxide Property

Melting point:
~160 °C
storage temp. 
Store below +30°C.
solubility 
Soluble in polar organic solvents.
form 
Powder
color 
White to beige
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
BRN 
3704116
InChI
InChI=1S/C5H5N.O3S/c1-2-4-6-5-3-1;1-4(2)3/h1-5H;
InChIKey
UDYFLDICVHJSOY-UHFFFAOYSA-N
SMILES
C1=CC=NC=C1.S(=O)(=O)=O
CAS DataBase Reference
26412-87-3(CAS DataBase Reference)
EPA Substance Registry System
Pyridine sulfur trioxide (26412-87-3)
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Safety

Hazard Codes 
C
Risk Statements 
22-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
3-10-21
Autoignition Temperature
>350 °C
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29420000
Toxicity
LD50 orally in Rabbit: 500 - 2000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
84737
Product name
Sulfur trioxide pyridine complex
Purity
technical, ≥45% SO
Packaging
100g
Price
$91.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18112
Product name
Sulfur trioxide pyridine complex
Purity
for synthesis
Packaging
100g
Price
$77.8
Updated
2024/03/01
Sigma-Aldrich
Product number
84737
Product name
Sulfur trioxide pyridine complex
Purity
technical, ≥45% SO
Packaging
10g
Price
$21.5
Updated
2022/05/15
TCI Chemical
Product number
P0998
Product name
Pyridine - Sulfur Trioxide Complex
Purity
>95.0%(T)
Packaging
25g
Price
$73
Updated
2024/03/01
TCI Chemical
Product number
P0998
Product name
Pyridine - Sulfur Trioxide Complex
Purity
>95.0%(T)
Packaging
100g
Price
$163
Updated
2024/03/01
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Pyridine sulfur trioxide Chemical Properties,Usage,Production

Chemical Properties

white solid

Uses

Sulfur trioxide-pyridine complex is used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with dimethyl sulfoxide. It is also used as a source of sulfur trioxide especially in the preparation of sulfate esters. Further, it is used as an activating electrophile in a Parikh-Doering oxidation. In addition to this, it is also used in the preparation and anticoagulation test of sulfated silk fibroin.

Uses

Pyridine-Sulfur Trioxide Complex is used in the sulfation of squid ink polysaccharides (SIPs) as a potential candidate compound for the prevention of tumor metastasis. Pyridine-Sulfur Trioxide Complex is also used in the preparation and anticoagulation test of sulfated silk fibroin.

Uses

Usually used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with DMSO.

Purification Methods

Wash the solid with a little CCl4, then H2O to remove traces of pyridine sulfate, and dry it over P2O5. [Baumgarten Chem Ber 59 1166 1926, Olah et al. Synthesis 59 1979, Beilstein 20/5 V 184].

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Pyridine sulfur trioxide Suppliers

NANJING SHUNXIANG PHARMACEUTICAL TECHNOLOGY CO.,LTD.
Tel
13951004015 13913839793
Fax
025-86819859
Email
nancyzong@jinchemical.com
Country
China
ProdList
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58
Shandong Xibang Biological Technology Development Co. LTD
Tel
0536-3611186 15063661551
Fax
0536-3611186
Email
196056703@qq.com
Country
China
ProdList
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58
Shanghai Worldyang Chemical Co.,Ltd.
Tel
021-021-56795766
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9346
Advantage
58
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.
Tel
133-96369453 18678026865
Fax
0536-2101172
Email
sdfantai@163.com
Country
China
ProdList
854
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Shandong Chenyi Environmental Protection Technology Co., Ltd
Tel
0531-83179999 13395316108
Email
cyhbkjyxgs@163.com
Country
China
ProdList
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XI'AN VEDA CHEMICAL CO.,LTD
Tel
+86-29-88665278 13379235092
Email
sales@vedachem.com
Country
China
ProdList
47
Advantage
58
Tongling LishidaChem Technology Co., Ltd
Tel
0186-06623089 18606623089
Email
350737036@qq.com
Country
China
ProdList
124
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Shanghai xinchenfa Chemical Technology Co.,Ltd
Tel
021-13564487020 13564487020
Email
3546809660@qq.com
Country
China
ProdList
510
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
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View Lastest Price from Pyridine sulfur trioxide manufacturers

Hebei Mojin Biotechnology Co.,Ltd
Product
Pyridine sulfur trioxide 26412-87-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-09-10
Hebei Weibang Biotechnology Co., Ltd
Product
Pyridine sulfur trioxide 26412-87-3
Price
US $10.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-06-29
Shaanxi TNJONE Pharmaceutical Co., Ltd
Product
Sulfur Trioxide Pyridine Complex 26412-87-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000kg
Release date
2024-04-15

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