Pyridine sulfur trioxide
- Product Name
- Pyridine sulfur trioxide
- CAS No.
- 26412-87-3
- Chemical Name
- Pyridine sulfur trioxide
- Synonyms
- SULFUR TRIOXIDE PYRIDINE COMPLEX;sulfur trioxide pyridine;PYRIDINE SULFUR TRIOXIDE COMPLEX;NSC 75831;PyridineSO3;fur trioxide;Pyridine suL;Sulfur trioxide pyri;sulfonylideneoxidane;Pyridine sulfur trio
- CBNumber
- CB9284694
- Molecular Formula
- C5H5NO3S
- Formula Weight
- 159.16
- MOL File
- 26412-87-3.mol
Pyridine sulfur trioxide Property
- Melting point:
- ~160 °C
- storage temp.
- Store below +30°C.
- solubility
- Soluble in polar organic solvents.
- form
- Powder
- color
- White to beige
- Water Solubility
- reacts
- Sensitive
- Moisture Sensitive
- BRN
- 3704116
- InChI
- InChI=1S/C5H5N.O3S/c1-2-4-6-5-3-1;1-4(2)3/h1-5H;
- InChIKey
- UDYFLDICVHJSOY-UHFFFAOYSA-N
- SMILES
- C1=CC=NC=C1.S(=O)(=O)=O
- CAS DataBase Reference
- 26412-87-3(CAS DataBase Reference)
- EPA Substance Registry System
- Pyridine sulfur trioxide (26412-87-3)
Safety
- Hazard Codes
- C
- Risk Statements
- 22-34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 3-10-21
- Autoignition Temperature
- >350 °C
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29420000
- Toxicity
- LD50 orally in Rabbit: 500 - 2000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 84737
- Product name
- Sulfur trioxide pyridine complex
- Purity
- technical, ≥45% SO
- Packaging
- 100g
- Price
- $91.6
- Updated
- 2024/03/01
- Product number
- 8.18112
- Product name
- Sulfur trioxide pyridine complex
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $77.8
- Updated
- 2024/03/01
- Product number
- 84737
- Product name
- Sulfur trioxide pyridine complex
- Purity
- technical, ≥45% SO
- Packaging
- 10g
- Price
- $21.5
- Updated
- 2022/05/15
- Product number
- P0998
- Product name
- Pyridine - Sulfur Trioxide Complex
- Purity
- >95.0%(T)
- Packaging
- 25g
- Price
- $73
- Updated
- 2024/03/01
- Product number
- P0998
- Product name
- Pyridine - Sulfur Trioxide Complex
- Purity
- >95.0%(T)
- Packaging
- 100g
- Price
- $163
- Updated
- 2024/03/01
Pyridine sulfur trioxide Chemical Properties,Usage,Production
Chemical Properties
white solid
Uses
Sulfur trioxide-pyridine complex is used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with dimethyl sulfoxide. It is also used as a source of sulfur trioxide especially in the preparation of sulfate esters. Further, it is used as an activating electrophile in a Parikh-Doering oxidation. In addition to this, it is also used in the preparation and anticoagulation test of sulfated silk fibroin.
Uses
Pyridine-Sulfur Trioxide Complex is used in the sulfation of squid ink polysaccharides (SIPs) as a potential candidate compound for the prevention of tumor metastasis. Pyridine-Sulfur Trioxide Complex is also used in the preparation and anticoagulation test of sulfated silk fibroin.
Uses
Usually used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with DMSO.
Purification Methods
Wash the solid with a little CCl4, then H2O to remove traces of pyridine sulfate, and dry it over P2O5. [Baumgarten Chem Ber 59 1166 1926, Olah et al. Synthesis 59 1979, Beilstein 20/5 V 184].
Pyridine sulfur trioxide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Pyridine sulfur trioxide manufacturers
- Product
- Pyridine sulfur trioxide 26412-87-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2024-09-10
- Product
- Pyridine sulfur trioxide 26412-87-3
- Price
- US $10.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-06-29
- Product
- Sulfur Trioxide Pyridine Complex 26412-87-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-04-15