3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

Product Name: 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
CAS No.: 63160-13-4
Chemical Name: 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
Synonyms: Davis Oxaziridine;2-(benzenesulfonyl)-3-phenyloxaziridine;2-OXAZIRIDINE;3-PHENYL-2-(PHENYLSULFONYL)-1;N-(Phenylsulfonyl)phenyloxaziridine;3-Phenyl-N-phenylsulfonyloxaziridine;Oxaziridine, 3-phenyl-2-(phenylsulfonyl;3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE;trans-2-(Phenylsulfonyl)-3-phenyloxyaziridine;TRANS-2-(PHENYL SULFONYL)-3-PHENYL OXAZIRIDINE
CBNumber: CB9287428
Molecular Formula: C13H11NO3S
Formula Weight: 261.3
MOL File: 63160-13-4.mol

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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Property

Melting point:: 96-97 °C
Boiling point:: 394.4±45.0 °C(Predicted)
Density: 1.398±0.06 g/cm3(Predicted)
storage temp.: -20°C Freezer
solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly, Sonicated)
form: Solid
pka: -13.47±0.40(Predicted)
color: White to Off-White

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Safety

HS Code: 2935909099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: D194900
Product name: DavisOxaziridine
Packaging: 1g
Price: $180
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8663-1-23
Product name: 3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity: 96%
Packaging: 250mg
Price: $195
Updated: 2021/12/16

Synthonix

Product number: P5853
Product name: 3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity: 95%
Packaging: 25g
Price: $280
Updated: 2021/12/16

Synthonix

Product number: P5853
Product name: 3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity: 95%
Packaging: 250mg
Price: $20
Updated: 2021/12/16

Synthonix

Product number: P5853
Product name: 3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity: 95%
Packaging: 1g
Price: $40
Updated: 2021/12/16

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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Chemical Properties,Usage,Production

Uses

Davis Oxaziridine is an oxidizing agent used in the preparation of wide variety of pharmaceutical compounds.

Uses

3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine, is an oxidizing agent used in the preparation of wide variety of pharmaceutical compounds.

Preparation

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE can be readily prepared on a 100 g scale in 88% yield via oxidation of N-benzylidenebenzenesulfonamide with buffered m-Chloroperbenzoic Acid or more conveniently with Potassium Monoperoxysulfate (Oxone). This Baeyer-Villiger type of oxidation of sulfonimine affords only the trans-oxaziridine. A number of other (±)-trans-2-(arylsulfonyl)-3- aryloxaziridines (2) can also be prepared by these methods.

General Description

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE is a neutral, aprotic, electrophilic oxidizing agent for the chemoselective oxidation of many nucleophilic substrates^[1].

storage

3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine can be stored in a brown bottle in the refrigerator for years without noticeable decomposition. Storage at rt for long periods of time, however, is potentially hazardous.^[2] The nitro-substituted oxaziridines (2) are more thermally stable and are recommended for reactions at elevated temperatures.

References

1. (a) Davis, F. A.; Sherppard, A. C. T 1989, 45, 5703. (b) Davis, F. A.; Chen, B.-C. CRV 1992, 92, 912.
2. Vishwakarma, L. C.; Stringer, O. D.; Davis, F. A. OS 1988, 66, 203.

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Suppliers

Canada 1 China 126 Germany 1 India 2 Spain 1 United States 12 Global 143

Accela ChemBio Inc.

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Aceschem Inc.

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Davos Chemical Corporation

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View Lastest Price from 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE 63160-13-4
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98.00%
Supply Ability: 20tons
Release date: 2023-09-07

Career Henan Chemical Co

Product: 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE 63160-13-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-07

63160-13-4, 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINERelated Search:

BENZENESULFOHYDROXAMIC ACID 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

TRANS-2-(PHENYL SULFONYL)-3-PHENYL OXAZIRIDINE

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

Oxaziridine, 3-phenyl-2-(phenylsulfonyl

2-(benzenesulfonyl)-3-phenyloxaziridine

trans-2-(Phenylsulfonyl)-3-phenyloxyaziridine

3-Phenyl-N-phenylsulfonyloxaziridine

Davis Oxaziridine

N-(Phenylsulfonyl)phenyloxaziridine

2-OXAZIRIDINE

3-PHENYL-2-(PHENYLSULFONYL)-1

TIANFU-CHEM 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

63160-13-4

Aromatics

Heterocycles

Intermediates

Sulfur & Selenium Compounds