ChemicalBook > CAS DataBase List > 2-Hydroxybenzyl alcohol

2-Hydroxybenzyl alcohol

Product Name
2-Hydroxybenzyl alcohol
CAS No.
90-01-7
Chemical Name
2-Hydroxybenzyl alcohol
Synonyms
SALICYL ALCOHOL;SALIGENIN;Salicylic alcohol;SALIGENOL;1‐(2‐Hydroxyphenyl)‐methanol;SALICAIN;Diathesin;SALIGENINE;α,2-toluenediol;α,2-Toluenediol
CBNumber
CB9303076
Molecular Formula
C7H8O2
Formula Weight
124.14
MOL File
90-01-7.mol
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2-Hydroxybenzyl alcohol Property

Melting point:
83-85 °C(lit.)
Boiling point:
190.92°C (rough estimate)
Density 
1,613 g/cm3
refractive index 
1.5035 (estimate)
storage temp. 
Store below +30°C.
solubility 
ethanol: soluble5%, clear to very slightly hazy, colorless to light yellow
pka
pK1:9.92 (25°C)
form 
Crystalline Flakes or Powder
color 
Light beige
Water Solubility 
67 g/L (22 ºC)
Merck 
14,8325
BRN 
1907195
Stability:
Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents.
LogP
0.730
CAS DataBase Reference
90-01-7(CAS DataBase Reference)
NIST Chemistry Reference
Salicyl alcohol(90-01-7)
EPA Substance Registry System
2-Hydroxybenzenemethanol (90-01-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
DO6430000
TSCA 
Yes
HS Code 
29072900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20662
Product name
2-Hydroxybenzyl alcohol
Purity
for synthesis
Packaging
50g
Price
$73.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20662
Product name
2-Hydroxybenzyl alcohol
Purity
for synthesis
Packaging
250g
Price
$324
Updated
2024/03/01
Sigma-Aldrich
Product number
166952
Product name
2-Hydroxybenzyl alcohol
Purity
99%
Packaging
25g
Price
$51.6
Updated
2024/03/01
Sigma-Aldrich
Product number
166952
Product name
2-Hydroxybenzyl alcohol
Purity
99%
Packaging
100g
Price
$129
Updated
2024/03/01
TCI Chemical
Product number
H0223
Product name
2-Hydroxybenzyl Alcohol
Purity
>98.0%(GC)
Packaging
25g
Price
$61
Updated
2024/03/01
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2-Hydroxybenzyl alcohol Chemical Properties,Usage,Production

Chemical Properties

light brown crystalline powder

Chemical Properties

Salicyl alcohol: (saligenin, o-hydroxy benzyl alcohol) crystallizes from water in the form of needles or white rhombic crystals. It occurs in nature as the bitter glycoside, salicin CAS: 138-52-3, which is isolated from the bark of Salix helix, S. pentandra, S. praecos, some other species of willow trees, and the bark of a number of species of poplar trees such as Polpulus balsamifera, P. candicans, and P. nigra.

Uses

anesthetic (local), antiinflammatory

Uses

2-Hydroxybenzyl Alcohol is a phenolic component of a part of a salix bark extract which maintains a minor anti-depressant effect. Phenolic analog with potential for anti-melanomic effect. Also It is an intermediate in the production of phenol formaldehyde res ins (may remain after condensation of the resin); sensitizer in phenol-formaldehyde resins; in loeal anesthetics.

Definition

ChEBI: A hydroxybenzyl alcohol that is phenol substituted by a hydroxymethyl group at C-2.

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 5314, 1995 DOI: 10.1021/jo00121a060
Tetrahedron Letters, 10, p. 1739, 1969

General Description

2-Hydroxybenzyl alcohol participates in the selective ring opening reaction of 4H-1,3,2-benzodioxasilines.

Contact allergens

Methylol phenols are sensitizers contained in resins based on phenol and formaldehyde of the resol type. Cross-reactivity is possible with other phenol derivative molecules.

Purification Methods

Crystallise saligenine from water or EtOH/*C6H6 (m 89o). [Beilstein 6 III 4537, 6 IV 5896.]

2-Hydroxybenzyl alcohol Preparation Products And Raw materials

Raw materials

Formaldehyde

Preparation Products

SALITHION Xanthene
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2-Hydroxybenzyl alcohol Suppliers

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View Lastest Price from 2-Hydroxybenzyl alcohol manufacturers

Capot Chemical Co.,Ltd.
Product
2-Hydroxybenzyl alcohol 90-01-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-01-03
Shanghai Standard Technology Co., Ltd.
Product
2-Hydroxybenzyl Alcohol 90-01-7
Price
US $0.00/mg
Min. Order
100mg
Purity
≥98%(HPLC)
Supply Ability
100 g
Release date
2020-05-27
Hong Kong Tiansheng New Material Trading Co., Ltd
Product
salicyl alcohol 90-01-7
Price
US $17.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2021-09-24

90-01-7, 2-Hydroxybenzyl alcoholRelated Search:

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