1-CHLORO-2,4-DIFLUOROBENZENE

Product Name: 1-CHLORO-2,4-DIFLUOROBENZENE
CAS No.: 1435-44-5
Chemical Name: 1-CHLORO-2,4-DIFLUOROBENZENE
Synonyms: 2,4-Difluorchlorbenzol;2,4-Diflurochlorobenzene;2,4-DIFLUOROCHLOROBENZENE;2,4-Difluorophenyl chloride;2,4-difluoro-dichlorobenzene;1-CHLORO-2,4-DIFLUOROBENZENE;Benzene,1-chloro-2,4-difluoro-;1-Chloro-2,4-difluorobenzene98%;1-Chloro-2,4-difluorobenzene >1-Chloro-2,4-difluorobenzene 98%
CBNumber: CB9310063
Molecular Formula: C6H3ClF2
Formula Weight: 148.54
MOL File: 1435-44-5.mol

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1-CHLORO-2,4-DIFLUOROBENZENE Property

Melting point:: -26 °C
Boiling point:: 127 °C (lit.)
Density: 1.353 g/mL at 25 °C (lit.)
refractive index: n20/D 1.475(lit.)
Flash point:: 91 °F
storage temp.: Sealed in dry,Room Temperature
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 1.353
BRN: 2081077
InChI: InChI=1S/C6H3ClF2/c7-5-2-1-4(8)3-6(5)9/h1-3H
InChIKey: AJCSNHQKXUSMMY-UHFFFAOYSA-N
SMILES: C1(Cl)=CC=C(F)C=C1F
CAS DataBase Reference: 1435-44-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,F
Risk Statements: 10-36/37/38
Safety Statements: 16-26-36/37/39
RIDADR: UN 1993 3/PG 3
WGK Germany: 2
Hazard Note: Flammable
HazardClass: 3
PackingGroup: III
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 335789
Product name: 1-Chloro-2,4-difluorobenzene
Purity: 98%
Packaging: 25g
Price: $152
Updated: 2025/07/31

Sigma-Aldrich

Product number: 335789
Product name: 1-Chloro-2,4-difluorobenzene
Purity: 98%
Packaging: 100g
Price: $412
Updated: 2023/01/07

TCI Chemical

Product number: C1830
Product name: 1-Chloro-2,4-difluorobenzene
Purity: >98.0%(GC)
Packaging: 25g
Price: $118
Updated: 2025/07/31

TRC

Product number: C377733
Product name: 1-Chloro-2,4-difluorobenzene
Packaging: 500mg
Price: $45
Updated: 2021/12/16

Ark Pharm

Product number: AK-87145
Product name: 1-Chloro-2,4-difluorobenzene
Purity: 98%
Packaging: 5g
Price: $7
Updated: 2021/12/16

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1-CHLORO-2,4-DIFLUOROBENZENE Chemical Properties,Usage,Production

Chemical Properties

Clear colourless to light yellow liquid

Uses

1-Chloro-2,4-difluorobenzene was used in the preparation of series of benzonorbornadienes. It was also used in the preparation of difluoroarenes.

Synthesis

108-90-7

348-51-6

352-33-0

625-98-9

1435-44-5

696-02-6

2367-91-1

GENERAL STEPS: In a FEP or PFA reactor equipped with a PTFE-lined magnetic stir bar and connected to a gas scrubber bottle, substituted benzene (0.95-1.10 mmol), 1,1,1,3,3-pentafluorobutane (2 mL per mL of C6H5R), and BF3-Et2O (1.3-1.5 mmol/mmol C6H5R) were added. The reaction mixture was stirred at 0-5 °C (ice bath) for 10-15 min, followed by batchwise addition of XeF2 (1.2-1.3 mmol/mmol C6H5R). After each addition, the mixture was stirred for 3-5 min at 22-25 °C and re-cooled to 0-5 °C. After complete addition of XeF2, the dark-colored reaction solution was continued to be stirred at 22-25 °C for 15-30 min. Upon completion of the reaction, the reaction was quenched by the addition of 10% aqueous KHCO3, the organic layer was separated and filtered through a short column packed with silica gel (40-60 μm). The organic phase was dried with magnesium sulfate and analyzed by 19F NMR and GC/MS. The major products are listed in the table, and the other products are as follows (with GC/MS data).

References

[1] Russian Journal of Organic Chemistry, 2016, vol. 52, # 10, p. 1400 - 1407
[2] Zh. Org. Khim., 2016, vol. 52, # 10, p. 1412 - 1419,8

1-CHLORO-2,4-DIFLUOROBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-CHLORO-2,4-DIFLUOROBENZENE Suppliers

Americas 1 Belgium 1 China 144 Europe 3 France 1 Germany 2 India 10 Italy 1 Japan 4 Slovakia 1 Switzerland 2 The Netherlands 1 United Kingdom 16 United States 28 Global 215

J & K SCIENTIFIC LTD.

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Alfa Aesar

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Energy Chemical

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Beijing Ouhe Technology Co., Ltd

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JinYan Chemicals(ShangHai) Co.,Ltd.

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View Lastest Price from 1-CHLORO-2,4-DIFLUOROBENZENE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 1-CHLORO-2,4-DIFLUOROBENZENE 1435-44-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-06

Henan Fengda Chemical Co., Ltd

Product: 1-CHLORO-2,4-DIFLUOROBENZENE 1435-44-5
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Honest Joy Holdings Limited

Product: 1-Chloro-2,4-difluorobenzene 1435-44-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.7%
Supply Ability: 100 tons
Release date: 2022-01-26

1435-44-5, 1-CHLORO-2,4-DIFLUOROBENZENERelated Search:

1,3-DICHLORO-2,4-DIFLUOROBENZENE 1,3-DICHLORO-2,4,6-TRIFLUOROBENZENE Teflubenzuron 2,4,6-Trifluorochlorobenzene Chloropentafluorobenzene 1,3,5-Trichloro-2,4,6-trifluorobenzene 2,4-Difluoro-3,5-dichloroaniline 1-CHLORO-2,4-DIFLUOROBENZENE 1,3-DICHLOROTETRAFLUOROBENZENE 3-CHLORO-2,6-DIFLUOROBENZALDEHYDE 2-CHLORO-3,5-DIFLUOROANISOLE 2,3,4-Trifluorochlorobenzene 3-CHLORO-2,6-DIFLUOROBENZOIC ACID 2-CHLORO-4 5-DIFLUOROBENZENE ACID 98% CHLORO-2,6-DIFLUOROBENZENE,1-CHLORO-2,6-DIFLUOROBENZENE,2-CHLORO-1,3-DIFLUOROBENZENE,1-CHLORO-2,6-DIFLUOROBENZENE / 2,6-DIFLUOROCHLOROBENZENE 2,3-DIFLUOROCHLOROBENZENE 1-Chloro-2,5-difluorobenzene 6-BROMO-2-CHLORO-1,3-DIFLUOROBENZENE

1-Chloro-2,4-difluorobenzene 98%

1-Chloro-2,4-difluorobenzene98%

2,4-Diflurochlorobenzene

2,4-Difluorchlorbenzol

1-CHLORO-2,4-DIFLUOROBENZENE / 2,4-DIFLUOROCHLOROBENZENE

1-CHLORO-2,4-DIFLUOROBENZENE

2,4-DIFLUOROCHLOROBENZENE

2,4-Difluorophenyl chloride

2,4-difluoro-dichlorobenzene

Benzene,1-chloro-2,4-difluoro-

1-Chloro-2,4-difluorobenzene &gt

1-CHLORO-2,4-DIFLUOROBENZENE ISO 9001：2015 REACH

2,4-Di Fluoro Chloro Benzene (2,4 DFCB)

1435-44-5

ClC6H3F2

Building Blocks

Halogenated Hydrocarbons

Organic Building Blocks

Aryl

C6

Fluorine series

Aryl Fluorinated Building Blocks

Building Blocks

Chemical Synthesis

Fluorinated Building Blocks

Halogenated Hydrocarbons

Organic Building Blocks

Organic Fluorinated Building Blocks

Other Fluorinated Organic Building Blocks

Aryl

Halogenated Hydrocarbons

Aromatic Hydrocarbons (substituted) & Derivatives

Chlorine Compounds

Fluorine Compounds

C6