ChemicalBook > CAS DataBase List > 1,3-Diamino-2-propanol

1,3-Diamino-2-propanol

Product Name
1,3-Diamino-2-propanol
CAS No.
616-29-5
Chemical Name
1,3-Diamino-2-propanol
Synonyms
1,3-DIAMINOPROPAN-2-OL;1,3-DIAMINO-2-HYDROXYPROPANE;Glycerol-α,γ-diamine;1,3-diamino-2-propano;1,3-DIAMINO-2-PROPANOL;2-Propanol, 1,3-diamino-;2-Hydroxypropylenediamine;1,3-Diamino-2-propanol>1,3-DIAMINO-2-HYDROXYPROPAN;1,3-Diamino-2-propanol ,97%
CBNumber
CB9315639
Molecular Formula
C3H10N2O
Formula Weight
90.12
MOL File
616-29-5.mol
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1,3-Diamino-2-propanol Property

Melting point:
40-44 °C(lit.)
Boiling point:
235°C
Density 
1.0352 (rough estimate)
refractive index 
1.4610 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
water: soluble1g/10 mL
form 
Low Melting Solid
pka
9.69, 7.93(at 20℃)
color 
White to yellow
Water Solubility 
Very soluble in water.
BRN 
741859
InChI
InChI=1S/C3H10N2O/c4-1-3(6)2-5/h3,6H,1-2,4-5H2
InChIKey
UYBWIEGTWASWSR-UHFFFAOYSA-N
SMILES
C(N)C(O)CN
CAS DataBase Reference
616-29-5(CAS DataBase Reference)
EPA Substance Registry System
2-Propanol, 1,3-diamino- (616-29-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
3259
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29221990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
33262
Product name
1,3-Diamino-2-propanol
Purity
purum, ≥96.5% (GC)
Packaging
5G
Price
$60.6
Updated
2024/03/01
Sigma-Aldrich
Product number
33262
Product name
1,3-Diamino-2-propanol
Purity
purum, ≥96.5% (GC)
Packaging
25g
Price
$219
Updated
2024/03/01
TCI Chemical
Product number
H0497
Product name
1,3-Diamino-2-propanol
Purity
>97.0%(T)
Packaging
5g
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
H0497
Product name
1,3-Diamino-2-propanol
Purity
>97.0%(T)
Packaging
25g
Price
$109
Updated
2024/03/01
Alfa Aesar
Product number
A19618
Product name
1,3-Diamino-2-propanol, 97%
Packaging
10g
Price
$57.65
Updated
2024/03/01
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1,3-Diamino-2-propanol Chemical Properties,Usage,Production

Description

1,3-Diamino-2-propanol (DAP), also known as 2-hydroxy-1,3-diaminopropane, is a white to yellowish low melting solid. Keep in a cool, well-ventilated place. Avoid prolonged storage periods. Store under inert gas, in a tightly sealed container and at ambient temperatures. 1,3-Diamino-2-propanol is incompatible with acids and strong oxidizing agents and should not be stored or handled in their vicinity.

Chemical Properties

white to yellowish low melting solid

Uses

  • 1,3-Diamino-2-propanol is a versatile bidentate diamine ligand which is used in the synthesis of a variety of organometallic compounds.
  • It is a precursor to synthesize the fluorogenic dsDNA binder, N1,N3-bis(4-amidinophenyl)propane-1,3-diamine (BAPPA).
  • It can also be used as a branching unit in the synthesis of peptide dendrimers.

Application

1,3-diamino-2-propanol (DAPL), a close analog of 1,3-diaminopropane, is an indirect inhibitor of ornithine decarboxylase (ODC). It is administered orally and inhibits ODC activity in the livers of partially hepatectomized rats[1]. It contains amine and hydroxyl groups. Therefore, it can be crosslinked with the carboxyl group via covalent and hydrogen bonds and has been investigated as a diamine monomer in the aqueous phase to fabricate the high-performance RO membrane[2].

Preparation

1,3-Diamino-2-propanol is synthesized by reacting Epichlorohydrin with ammonia in alkaline environment by adding sodium hydroxide. Afterwards, the product undergoes a series of purification steps.

Hazard

1,3-Diamino-2-propanoli is a hazardous chemical.
H302 (66.17%): Harmful if swallowed [Warning Acute toxicity, oral]. H314 (66.92%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]. H315 (33.08%): Causes skin irritation [Warning Skin corrosion/irritation]. H317 (66.17%): May cause an allergic skin reaction [Warning Sensitization, Skin]. H318 (66.17%): Causes serious eye damage [Danger Serious eye damage/eye irritation]. H319 (33.08%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]. H335 (34.59%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation.

Purification Methods

Dissolve it in an equal amount of water, shake it with charcoal and distil it at 68o/0.1mm. The distillate solidifies. It is too viscous to be distilled through a packed column. [Beilstein 4 IV 1694.]

References

[1] Raunio H, et al. The inhibition of induction of microsomal monooxygenase activity by 1,3-diamino-2-propanol, an inhibitor of ornithine decarboxylase. Biochemical and Biophysical Research Communications, 1979; 9: 285–290.
[2] Su T, et al. A novel polyamide thin-film nanocomposite reverse osmosis membrane constructed by a 3D multi-layer graphene oxide assembled with 1,3-diamino-2-propanol. Journal of Membrane Science, 2023; 681: 121773.

1,3-Diamino-2-propanol Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-Diamino-2-propanol Suppliers

Saintchem Chemical Co., Ltd.
Tel
13968039099 +undefined-13968039099
Fax
+86-483-8188266
Email
cherry.zhang@saintchem.com
Country
China
ProdList
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60
ELSA BIOTECHNOLOGY CO.,LTD.
Tel
15261860116
Fax
86-025-84106591
Email
sales@elsa-biotech.com
Country
China
ProdList
99
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55
Taizhou Hoyoo Chemical Co.,Ltd
Tel
0576-0576-88666163 15057600339
Fax
0576-88666163
Email
hoyoochem@yahoo.com
Country
China
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
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Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
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60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
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66
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View Lastest Price from 1,3-Diamino-2-propanol manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
1,3-Diamino-2-propanol 616-29-5
Price
US $99.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-12-05
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Diamino-2-propanol 616-29-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Chuanghai Biotechnology Co,.LTD
Product
1, 3-Diamino-2-Hydroxypropane 616-29-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

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