4-ACETAMIDO-TEMPO
- Product Name
- 4-ACETAMIDO-TEMPO
- CAS No.
- 14691-89-5
- Chemical Name
- 4-ACETAMIDO-TEMPO
- Synonyms
- 4-Acetamido-2,2,6,6-tetramethylpiperidinyloxy;tempace;ACETAMINO-TEMPO;4-ACETAMIDO-TEMPO;4-Acetamino-Tempo;4-ACETAMIDO-2,2,6,6-TEMPO;4-Acetylamino-2,2,6,6-tetramet;4-ACETAMIDO-TEMPO, FREE RADICAL;4-Acetamido-TEMPO, free radical 97%;Free Radical [Catalyst for Oxidation]
- CBNumber
- CB9319738
- Molecular Formula
- C11H21N2O2*
- Formula Weight
- 213.3
- MOL File
- 14691-89-5.mol
4-ACETAMIDO-TEMPO Property
- Melting point:
- 143-145 °C (lit.) 143-146 °C
- Boiling point:
- 353.29°C (rough estimate)
- Density
- 1.0451 (rough estimate)
- refractive index
- 1.4620 (estimate)
- storage temp.
- 2-8°C
- solubility
- Soluble in ethanol, acetone, acetonitrile, methylene chloride. Insoluble in hexane, ether.
- form
- powder to crystaline
- color
- Light yellow to Brown
- BRN
- 3546225
- InChI
- InChI=1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
- InChIKey
- UXBLSWOMIHTQPH-UHFFFAOYSA-N
- SMILES
- C1(NC(=O)C)CC(N([O])C(C)(C)C1)(C)C |^1:8|
- CAS DataBase Reference
- 14691-89-5(CAS DataBase Reference)
- EPA Substance Registry System
- 1-Piperidinyloxy, 4-(acetylamino)-2,2,6,6-tetramethyl- (14691-89-5)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-22-36/37
- Safety Statements
- 26-36-24/25-22
- WGK Germany
- 1
- F
- 9
- TSCA
- Yes
- HS Code
- 29339900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 00375
- Product name
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl
- Purity
- purum, ≥98.0% (HPLC)
- Packaging
- 1g
- Price
- $80.2
- Updated
- 2025/07/31
- Product number
- 00375
- Product name
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl
- Purity
- purum, ≥98.0% (HPLC)
- Packaging
- 5g
- Price
- $327
- Updated
- 2025/07/31
- Product number
- A1348
- Product name
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical[Catalyst for Oxidation]
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $49
- Updated
- 2025/07/31
- Product number
- A1348
- Product name
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical[Catalyst for Oxidation]
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $136
- Updated
- 2025/07/31
- Product number
- 390380
- Product name
- 4-Acetamido-TEMPO, free radical
- Purity
- 97%
- Packaging
- 25g
- Price
- $1036
- Updated
- 2025/07/31
4-ACETAMIDO-TEMPO Chemical Properties,Usage,Production
Chemical Properties
ORANGE-RED CRYSTALLINE POWDER
Uses
4-Acetamido-TEMPO, free radical oxidizes alcohols to carbonyl compounds in the presence of TsOH.
General Description
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
Purification Methods
Dissolve the 1-oxyl in CH2Cl2, wash it with saturated K2CO3, then saturated aqueous NaCl, dry (Na2SO4), filter and evaporate. The red solid is recrystallised from aqueous MeOH, m 147.5o. [Ma & Bobbitt J Org Chem 56 6110 1991, Rozantsev & Kokhanov Bull Acad Sci USSR, Div Chem Sci 15 1422 1966, Beilstein 22/8 V 174.]
4-ACETAMIDO-TEMPO Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-ACETAMIDO-TEMPO manufacturers
- Product
- 4-ACETAMIDO-TEMPO 14691-89-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-19
- Product
- 4-ACETAMIDO-TEMPO 14691-89-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-22
- Product
- 4-Acetamido-TEMPO, free radical 14691-89-5
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- >98%
- Supply Ability
- 20 tons
- Release date
- 2020-02-10