(R)-(-)-Benzyl glycidyl ether
- Product Name
- (R)-(-)-Benzyl glycidyl ether
- CAS No.
- 14618-80-5
- Chemical Name
- (R)-(-)-Benzyl glycidyl ether
- Synonyms
- tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na
- CBNumber
- CB9320637
- Molecular Formula
- C10H12O2
- Formula Weight
- 164.2
- MOL File
- 14618-80-5.mol
(R)-(-)-Benzyl glycidyl ether Property
- Melting point:
- 88-93°C
- Boiling point:
- 130 °C (0.1 mmHg)
- alpha
- -5.4 º (c=5 in toluene)
- Density
- 1.077 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.517(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- form
- paste (yellow)
- Specific Gravity
- 1.077
- color
- Colorless to Almost colorless
- optical activity
- [α]20/D 5.4°, c = 5 in toluene
- Water Solubility
- Soluble in water.
- BRN
- 3588399
- CAS DataBase Reference
- 14618-80-5(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- RIDADR
- NA 1993 / PGIII
- WGK Germany
- 3
- RTECS
- TX2860020
- HS Code
- 29109000
- Toxicity
- mic-sat 660 nmol/plate MUREAV 298,197,1993
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 791547
- Product name
- Titania paste, transparent
- Packaging
- 10G
- Price
- $225
- Updated
- 2024/03/01
- Product number
- 791547
- Product name
- Titania paste, transparent
- Packaging
- 20G
- Price
- $326
- Updated
- 2024/03/01
- Product number
- 720429
- Product name
- 1H-Pyrazol-3-ylboronic acid hydrate
- Packaging
- 1g
- Price
- $251
- Updated
- 2023/06/20
- Product number
- 363529
- Product name
- (R)-(?)-Glycidyl benzyl ether
- Purity
- 99%
- Packaging
- 1g
- Price
- $42.4
- Updated
- 2023/06/20
- Product number
- B2238
- Product name
- Benzyl (R)-(-)-Glycidyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $19
- Updated
- 2024/03/01
(R)-(-)-Benzyl glycidyl ether Chemical Properties,Usage,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.
Synthesis Reference(s)
Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6
General Description
1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.
Safety Profile
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
(R)-(-)-Benzyl glycidyl ether Suppliers
- Tel
- 0519-88103998 13646148298
- Fax
- 0519-88104456
- amy.zhou@huarenchem.com
- Country
- China
- ProdList
- 56
- Advantage
- 63
- Tel
- 021-60455363 18019463053
- Fax
- 50966098
- sales@coolpharm.com
- Country
- China
- ProdList
- 12346
- Advantage
- 58
- Tel
- 13816253073
- lige@kelybiopharm.com
- Country
- China
- ProdList
- 105
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 94657
- Advantage
- 76
- Tel
- 021-61259108 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- +49 3493/605464
- Fax
- +49 3493/605470
- sales@intatrade.de
- Country
- Germany
- ProdList
- 3572
- Advantage
- 66
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44689
- Advantage
- 61
View Lastest Price from (R)-(-)-Benzyl glycidyl ether manufacturers
- Product
- (R)-()-Glycidyl benzyl ether 14618-80-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- (R)-(-)-Benzyl glycidyl ether 14618-80-5
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-12
- Product
- (R)-(-)-Benzyl glycidyl ether 14618-80-5
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%MIN
- Supply Ability
- ASK
- Release date
- 2020-01-07