TRIMETHYL CITRATE

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Description Reference

Product Name: TRIMETHYL CITRATE
CAS No.: 1587-20-8
Chemical Name: TRIMETHYL CITRATE
Synonyms: METHYL CITRATE;2,3-propanetricarboxylicacid,2-hydroxy-trimethylester;NSC 75824;TRIMETHYL CITRATE;Citric acid trimethyl;Trimethyl Citrate >Maropitant Citrate/Bas;Trimethyl citrate >=98.0%;CITRIC ACID TRIMETHYL ESTER;Trimethyl 2-hydroxy-1,2,3-propanetricarboxylate
CBNumber: CB9336607
Molecular Formula: C9H14O7
Formula Weight: 234.2
MOL File: 1587-20-8.mol

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TRIMETHYL CITRATE Property

Melting point:: 75-78 °C
Boiling point:: 176 16mm
Density: 1.3363 (rough estimate)
vapor pressure: 1.3hPa at 20℃
refractive index: 1.4455 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: Solid
pka: 10.43±0.29(Predicted)
color: White to Off-White
Odor: at 100.00 %. ethereal fruity
Odor Type: ethereal
Water Solubility: 53.2g/L at 20℃
BRN: 1796169
LogP: 0.7 at 20℃
CAS DataBase Reference: 1587-20-8(CAS DataBase Reference)
EPA Substance Registry System: 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, trimethyl ester (1587-20-8)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29181500

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P363Wash contaminated clothing before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S377910
Product name: TRIMETHYL CITRATE
Purity: AldrichCPR
Packaging: 250mg
Price: $179
Updated: 2024/03/01

Sigma-Aldrich

Product number: 27502
Product name: Trimethyl citrate
Purity: ≥98.0%
Packaging: 5G
Price: $121
Updated: 2024/03/01

TCI Chemical

Product number: C0368
Product name: Trimethyl Citrate
Purity: >98.0%(GC)
Packaging: 5g
Price: $38
Updated: 2024/03/01

TCI Chemical

Product number: C0368
Product name: Trimethyl Citrate
Purity: >98.0%(GC)
Packaging: 25g
Price: $110
Updated: 2024/03/01

TRC

Product number: T796170
Product name: Trimethyl Citrate
Packaging: 50g
Price: $120
Updated: 2021/12/16

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TRIMETHYL CITRATE Chemical Properties,Usage,Production

Description

Trimethyl citrate is an ester of citric acid. It is a kind of non-toxic plasticizer¹. Trimethyl citrate is one of the constituents of Dioscorea opposita². The IC50 value for monoamine oxidase-B of trimethyl citrate was studied. It has various applications³: it can do the main flame retardant candle flame color, its melting point and can fully meet the flammability requirements of candle products. It can be used for the synthesis of pharmaceutical and pesticide. It can act as the main raw material for the production of citric acid hydrochloride, citric acid hydrochloride as well as the synthetic hot melt adhesive. It can also be used as the methyl methacrylate polymer a blowing agent, a stabilizer acrylamide, polyamide adhesive initiators, PVC plasticizers. It can also be used as solvent for household and II cleaner, film-former⁴.

Reference

Huang, Li, L. I. Chun-Lian, and H. U. Qing-Guo. "Study on Catalytic Synthesis of Trimethyl Citrate by Solid Acid." Liaoning Chemical Industry (2012).
https://www.sigmaaldrich.com/catalog/product/aldrich/27502?lang=en&region=US
www.zhonglanindustry.com/product/trimethyl-citrate
https://www.lookchem.com/Trimethyl-citrate/

Chemical Properties

Colorless crystals. M.P. 79℃. B.P. 287℃. (decomposes). Slightly soluble in water, soluble in alcohol and oils.

Uses

Trimethyl Citrate is a reagent used in the preparation of citrate-ciprofloxacin conjugates which has antibacterial activity.

Preparation

Trimethyl citrate is produced by direct esterification of Citric acid with Methanol using the old-fashioned method with 3% sulfuric acid and reflux to complete the esterification.

General Description

Trimethyl citrate is one of the constituents of Dioscorea opposita. The IC₅₀ value for monoamine oxidase-B of trimethyl citrate was studied.

Flammability and Explosibility

Not classified

TRIMETHYL CITRATE Preparation Products And Raw materials

Raw materials

Preparation Products

Citrazinic acid

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View Lastest Price from TRIMETHYL CITRATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: TRIMETHYL CITRATE 1587-20-8
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-11

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: TRIMETHYL CITRATE 1587-20-8
Price: US $100.00-75.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-14

airuikechemical co., ltd.

Product: Trimethyl citrate 1587-20-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99.9%
Supply Ability: 20 tons
Release date: 2024-04-07

1587-20-8, TRIMETHYL CITRATERelated Search:

Triethyl citrate TRIMETHYL CITRATE tris(2-ethylhexyl) 2-(acetyloxy)propane-1,2,3-tricarboxylate STEARYL CITRATE n-Butyryl tri-n-hexyl citrate Tributyl citrate CITRIC ACID TRIALLYL ESTER CITRIC ACID TRI-N-PROPYL ESTER TRIS(2-ETHYLHEXYL)CITRATE Triethyl acetyl citrate Acetyl tributyl citrate Trihexyl O-acetylcitrate Citric acid TRI-N-AMYL CITRATE TRIISOOCTYL CITRATE COSTAUSOL(TM) SALOR-INT L160326-1EA TRI(N-OCTYLDECYL)ACETYL CITRATE

2,3-propanetricarboxylicacid,2-hydroxy-trimethylester

3-Hydroxy-3-methoxycarbonylpentanedioic acid, dimethyl ester

Trimethyl 2-hydroxy-1,2,3-propanetricarboxylate

METHYL CITRATE

CITRIC ACID TRIMETHYL ESTER

1,2,3-Propanetricarboxylic acid, 2-hydroxy-, trimethyl ester

TRIMETHYL CITRATE

2-Hydroxy-1,2,3-propanetricarboxylic acid trimethyl ester

Citric acid trimethyl

2-hydroxypropane-1,2,3-tricarboxylic acid trimethyl ester

trimethyl 2-hydroxypropane-1,2,3-tricarboxylate

NSC 75824

1,2,3-Propanetricarboxylicacid, 2-hydroxy-, 1,2,3-triMethyl ester

Trimethyl citrate >=98.0%

Trimethyl Citrate &gt

1,2,3-trimethyl 2-hydroxypropane-1,2,3-tricarboxylate

2,3-propanetricarboxylicacid,2-hydroxy-trimethyleste

Maropitant Citrate/Bas

1587-20-8

C3H4OHCOOCH33

CH33C6H5O7

Hydroxycarboxylic Acid Esters (Plasticizer)

Plasticizer

Building Blocks

Carbonyl Compounds

C8 to C9

Esters

Organic Building Blocks

Miscellaneous

Functional Materials

Hydroxycarboxylic Acid Esters (Plasticizer)

Plasticizer

C8 to C9

Carbonyl Compounds

Esters