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Acetyl tributyl citrate

Product Name
Acetyl tributyl citrate
CAS No.
77-90-7
Chemical Name
Acetyl tributyl citrate
Synonyms
ATBC;TRIBUTYL ACETYLCITRATE;Acetyltributylcitrat;TRIBUTYL O-ACETYLCITRATE;Tributyl citrate acetate;citroflexa4;Acetyl butyl citrate;tributylcitrateacetate;ACETYL TRI-N-BUTYL CITRATE;tributyl 2-acetoxypropane-1,2,3-tricarboxylate
CBNumber
CB0408022
Molecular Formula
C20H34O8
Formula Weight
402.48
MOL File
77-90-7.mol
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Acetyl tributyl citrate Property

Melting point:
-59 °C
Boiling point:
327 °C
Density 
1.05 g/mL at 25 °C (lit.)
Pour Point 
-43
vapor pressure 
0.26 psi ( 20 °C)
refractive index 
n20/D 1.443(lit.)
FEMA 
3080 | TRIBUTYL ACETYLCITRATE
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
Not miscible with water, miscible with ethanol (96 per cent) and with methylene chloride.
form 
Liquid
color 
Clear Colourless
Odor
at 100.00 %. very faint herbal wine sweet
Odor Type
herbal
Water Solubility 
<0.1 g/100 mL
FreezingPoint 
-80℃
JECFA Number
630
BRN 
2303316
InChIKey
QZCLKYGREBVARF-UHFFFAOYSA-N
LogP
5.227 (est)
CAS DataBase Reference
77-90-7(CAS DataBase Reference)
NIST Chemistry Reference
1,2,3-Propanetricarboxylic acid, 2-(acetyloxy)-, tributyl ester(77-90-7)
EPA Substance Registry System
Acetyl tributyl citrate (77-90-7)
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Safety

Safety Statements 
24/25
WGK Germany 
3
RTECS 
TZ8330000
TSCA 
TSCA listed
HS Code 
29181500
Hazardous Substances Data
77-90-7(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
1009901
Product name
Acetyltributyl citrate
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
500mg
Price
$450
Updated
2022/05/15
TCI Chemical
Product number
A0822
Product name
Tributyl O-Acetylcitrate
Purity
>97.0%(GC)
Packaging
25mL
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
A0822
Product name
Tributyl O-Acetylcitrate
Purity
>97.0%(GC)
Packaging
500mL
Price
$54
Updated
2024/03/01
scipoly
Product number
P-107
Product name
Acetyl tri-n-butyl citrate
Packaging
100g
Price
$14
Updated
2024/07/03
scipoly
Product number
P-107
Product name
Acetyl tri-n-butyl citrate
Packaging
250g
Price
$28
Updated
2024/07/03
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Acetyl tributyl citrate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Chemical Properties

Acetyltributyl citrate is a clear, odorless, practically colorless, oily liquid.

Chemical Properties

Tributyl acetylcitrate has a very faint, sweet, herbaceous odor. At high levels (e.g., 1000 ppm emulsion in water), it has a mild, fruity, nondescript flavor.

Chemical Properties

Acetyl tributyl citrate (ATBC) is a colorless, odorless liquid. Its water solubility is less than 0.002 g/100 mL, but it is soluble in organic solvents.

Uses

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.

Uses

Labelled Tributyl O-Acetylcitrate (T772950). Topical pharmaceutical formulation anesthetic surfactant ester.

Uses

plasticizer flavoring agent

Preparation

From citric acid via the tributyl ester followed by acetylation.

Production Methods

Acetyltributyl citrate is prepared by the esterification of citric acid with butanol followed by acylation with acetic anhydride.

Definition

Aqueous-based pharmaceutical coat- ings.

Taste threshold values

An emulsion of the title material in water at 1000 ppm has only a very faint, mildly fruity-winey, berry-like odor and a mild, nondescript taste.

General Description

Tributyl 2-acetylcitrate is a hydrophobic biodegradable plasticizer, that is usually synthesized by esterification of citric acid. Pharmaceutically, it is used as an excipient, which is generally applied as a thin film over the tablets or capsules.
Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards.

Pharmaceutical Applications

Acetyltributyl citrate is used to plasticize polymers in formulated pharmaceutical coatings, including capsules, tablets, beads, and granules for taste masking, immediate release, sustained-release and enteric formulations.

Safety Profile

When heated to decomposition it emits acrid smoke and irritating fumes. ADD750

Safety

and films intended for direct food contact. It is also used in selfadhesive thin films used for topical delivery systems. It is generally regarded as a relatively nontoxic and nonirritating material. However, ingestion of large quantities may be harmful.
LD50 (cat, oral): >50 mL/kg
LD50 (mouse, IP): >4 g/kg
LD50 (rat, oral): >31.5 g/kg

Carcinogenicity

The chronic toxicity of ATBC was evaluated in rats fed diets containing 200, 2000, or 20,000 ppm of ATBC for 2 years. There were no treatment- related lesions in any organs examined.

Solubility in organics

Miscible with alcohol and oils.

storage

Acetyltributyl citrate should be stored in a well-closed container in a cool, dry location at temperatures not exceeding 38℃. When stored in accordance with these conditions, acetyltributyl citrate is a stable product.

Incompatibilities

Acetyltributyl citrate is incompatible with strong alkalis and oxidizing materials.

Regulatory Status

Included in FDA Inactive Ingredients Database (oral capsules and tablets). Included in nonparenteral medicines licensed in the UK. Approved in the USA for direct food contact in food films.

Acetyl tributyl citrate Preparation Products And Raw materials

Raw materials

Preparation Products

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Acetyl tributyl citrate Suppliers

Jinan Jinbang Chemical Co., Ltd
Tel
13127153349
Email
1693669779@qq.com
Country
China
ProdList
294
Advantage
58
Jobachem Suzhou Co., Ltd
Tel
0512-62927368; 18136961057
Email
min.li@jobachem.com
Country
China
ProdList
51
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from Acetyl tributyl citrate manufacturers

Anhui Royal Chemical Co., Ltd.
Product
ACETYL TRIBUTYL CITRATE 77-90-7
Price
US $770.00/kg
Min. Order
1000kg
Purity
99%
Supply Ability
20 tons
Release date
2024-05-21
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Acetyl tributyl citrate 77-90-7
Price
US $100.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-04-28
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
butyl acetylcitrate 77-90-7
Price
US $60.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-17

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