ChemicalBook > CAS DataBase List > Triethyl acetyl citrate

Triethyl acetyl citrate

Product Name
Triethyl acetyl citrate
CAS No.
77-89-4
Chemical Name
Triethyl acetyl citrate
Synonyms
ACETYL TRIETHYL CITRATE;ATEC;O-AcetyL;triethyl 2-acetoxypropane-1,2,3-tricarboxylate;Uniplex 82;Triethyl O;citroflexa2;Citroflex A 2;Trithylcitratc;ethyl acetylcitrate
CBNumber
CB5483819
Molecular Formula
C14H22O8
Formula Weight
318.32
MOL File
77-89-4.mol
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Triethyl acetyl citrate Property

Melting point:
-42°C
Boiling point:
228-229 °C/100 mmHg (lit.)
Density 
1.136 g/mL at 25 °C (lit.)
Pour Point 
-42
refractive index 
n20/D 1.439(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble 1 in 140 of water; miscible with acetone, ethanol, and propan-2-ol.
form 
Liquid
color 
Colourless
Odor
odorless
BRN 
1804947
LogP
2.170 (est)
CAS DataBase Reference
77-89-4(CAS DataBase Reference)
NIST Chemistry Reference
1,2,3-Propanetricarboxylic acid, 2-acetoxy-, triethyl ester(77-89-4)
EPA Substance Registry System
1,2,3-Propanetricarboxylic acid, 2-(acetyloxy)-, triethyl ester (77-89-4)
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Safety

Safety Statements 
23-24/25
WGK Germany 
1
RTECS 
GE8225000
TSCA 
TSCA listed
HS Code 
2918150000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
388351
Product name
Triethyl 2-acetylcitrate
Purity
99%
Packaging
500ml
Price
$61.8
Updated
2024/03/01
Sigma-Aldrich
Product number
1009923
Product name
Acetyltriethyl citrate
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
500mg
Price
$450
Updated
2022/05/15
TCI Chemical
Product number
A0086
Product name
Triethyl O-Acetylcitrate
Purity
>97.0%(GC)
Packaging
25g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
A0086
Product name
Triethyl O-Acetylcitrate
Purity
>97.0%(GC)
Packaging
500g
Price
$68
Updated
2024/03/01
scipoly
Product number
P-108
Product name
Acetyl triethyl citrate
Packaging
100g
Price
$14
Updated
2024/07/03
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Triethyl acetyl citrate Chemical Properties,Usage,Production

Chemical Properties

Acetyltriethyl citrate occurs as a clear, odorless, practically colorless oily liquid.

Uses

ATEC is produced by the reaction of citric acid triethyl ester with acetic acid anhydride. It is used as a solvent plasticizer for cellulose nitrate and cellulose acetate.

Uses

Triethyl O-Acetylcitrate is used in the preparation of poly(lactic) acid biodegradable and flexible films, acting as a plasticizer. Also used in the synthesis of control-release capsules containing polymeric coatings.

Definition

Aqueous-based pharmaceutical coat- ings.

Production Methods

Acetyltriethyl citrate is prepared by the esterification of citric acid with ethanol followed by acylation with acetic anhydride.

General Description

Certified pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards. Triethyl 2-acetylcitrate is widely used in hydrophilic adhesives for medications and in biodegradable composition for papermaking and nonwoven production.

Pharmaceutical Applications

Acetyltriethyl citrate is used to plasticize polymers in formulated pharmaceutical coatings. The coating applications include capsules, tablets, beads and granules for taste masking, immediate release, sustained-release and enteric formulations. It is also used in diffusion-controlled release drug delivery systems.

Safety

Acetyltriethyl citrate is used in oral pharmaceutical formulations and is generally regarded as a nontoxic and nonirritating material. However, ingestion of large quantities may be harmful.
LD50 (cat, oral): 8.5 g/kg
LD50 (mouse, IP): 1.15 g/kg
LD50 (rat, oral): 7 g/kg

storage

Acetyltriethyl citrate should be stored in dry, closed containers at temperatures not exceeding 388℃. When stored in accordance with these conditions, acetyltriethyl citrate is a stable product.

Incompatibilities

Acetyltriethyl citrate is incompatible with strong alkalis and oxidizing materials.

Regulatory Status

Approved in the USA for direct food contact in food films.

Triethyl acetyl citrate Preparation Products And Raw materials

Raw materials

Preparation Products

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Triethyl acetyl citrate Suppliers

Hubei Chusheng Chemical Co., Ltd.
Tel
027-87891008 18971624303
Fax
027-87892127
Email
1569406342@qq.com
Country
China
ProdList
267
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
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61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
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Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
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50
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
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57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
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57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
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57
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View Lastest Price from Triethyl acetyl citrate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Triethyl acetyl citrate 77-89-4
Price
US $100.00/kg
Min. Order
1kg
Purity
98
Supply Ability
4000
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Acetyl Triethyl Citrate 77-89-4
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25
Hebei Weibang Biotechnology Co., Ltd
Product
Triethyl acetyl citrate 77-89-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30

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