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Sodium acrylate

Product Name
Sodium acrylate
CAS No.
7446-81-3
Chemical Name
Sodium acrylate
Synonyms
ACRYLIC ACID, SODIUM SALT;DK884;Sodium acryL;SODIUM ACRYLATE;Sodium propenoate;Sodium 2-propenoate;SodiuM acrylate 97%;Sodium acrylate(~white);Sodium acrylate(~yellow);SODIUM ACRYLATE ANHYDROUS
CBNumber
CB9343487
Molecular Formula
C3H3NaO2
Formula Weight
94.04
MOL File
7446-81-3.mol
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Sodium acrylate Property

Melting point:
>300 °C (lit.)
Density 
1.528[at 20℃]
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Aqueous Acid (Slightly), Methanol (Slightly), Water (Slightly)
form 
Solid
color 
White to Off-White
Water Solubility 
479g/L at 20℃
Hydrolytic Sensitivity
0: forms stable aqueous solutions
Stability:
May be unstable; may spontaneously polymerize. Incompatible with strong oxidizing agents.
InChI
InChI=1S/C3H4O2.Na/c1-2-3(4)5;/h2H,1H2,(H,4,5);/q;+1/p-1
InChIKey
NNMHYFLPFNGQFZ-UHFFFAOYSA-M
SMILES
C([O-])(=O)C=C.[Na+]
LogP
0.46 at 25℃
CAS DataBase Reference
7446-81-3(CAS DataBase Reference)
EPA Substance Registry System
Sodium acrylate (7446-81-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
TSCA 
Yes
HS Code 
29161100
Hazardous Substances Data
7446-81-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
408220
Product name
Sodium acrylate
Purity
97%
Packaging
25g
Price
$89
Updated
2024/03/01
Sigma-Aldrich
Product number
408220
Product name
Sodium acrylate
Purity
97%
Packaging
100g
Price
$261
Updated
2024/03/01
scipoly
Product number
M-235
Product name
Acrylic acid, sodium salt
Packaging
25g
Price
$31
Updated
2024/07/03
scipoly
Product number
M-235
Product name
Acrylic acid, sodium salt
Packaging
50g
Price
$50
Updated
2024/07/03
TRC
Product number
S960060
Product name
Sodium acrylate
Packaging
5g
Price
$50
Updated
2021/12/16
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Sodium acrylate Chemical Properties,Usage,Production

Chemical Properties

Colorless or light yellow viscous liquid, non-toxic, weakly alkaline, insoluble in organic solvents such as ethanol, acetone, etc., easily soluble in water and aqueous sodium hydroxide, but in aqueous solutions such as calcium hydroxide, magnesium hydroxide, etc., with the increase in the number of alkaline-earth metal ions, the first to dissolve and then precipitate.

Uses

Sodium Acrylate (SA) is a sodium salt of acrylic acid with antibacterial properties. Sodium polyacrylate is a sodium salt of a polymer consisting of acrylic acid, methacrylic acid or one of their simple esters. SA can be used in tuning the grain size of iron oxide microparticles for potential applications in biological assaying and in chemical sensors. Additionally, it acts as a reducing and capping agent for gold nanoparticles, beneficial for various biological applications.

benefits

Sodium acrylate is the sodium salt of acrylic acid. In Skincare or personal care products, sodium acrylate is often used as an ingredient with specific properties, such as its ability to act as a thickening agent or stabilizer in formulations, contributing to the overall texture and stability of the product.
Thickening Agent:Sodium acrylate is commonly used as a thickening agent in cosmetic formulations. It helps improve the viscosity and texture of the product, giving it a smooth and luxurious feel. This is particularly important for products like creams, lotions, and gels.
Stabilizer:Sodium acrylate can contribute to the stability of formulations. It helps prevent the separation of ingredients and enhances the overall shelf life of the product. This is important for maintaining the efficacy and quality of skincare products over time.
Enhanced Spreadability:The inclusion of sodium acrylate in formulations can improve the spreadability of skincare products on the skin. This ensures even application and distribution of the product, enhancing the user experience.
Film-Forming Properties:In some formulations, sodium acrylate may have film-forming properties. This can create a thin film on the skin, providing a protective barrier and potentially helping to lock in moisture.

General Description

Sodium acrylate (SA) is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid. It can be used in the preparation of poly(sodium acrylate) using bulk, solution, emulsion, and suspension polymerization techniques. It results in the formation of a water soluble polymer that can be used in a variety of industries and personal care applications.

Flammability and Explosibility

Non flammable

Synthesis

An aqueous solution of sodium acrylate is prepared from 216.2 g of acrylic acid (100%=3 mol), 262.8 g of NaOH (50%) and 497 g of water. 3.7 g of N-nitrosodiphenylamine and 3.7 g of 4-methoxyphenol are added to stabilize the solution. 12 g of the quaternary ammonium salt used in Example 1 are also added. 1,125 g (9 mol) of 1,4-dichlorobutene are run in at 90° C. 15.9 g of Na2CO3 are added after 1 hour and the mixture is left to react for a further 2 hours at 90° C. After phase separation, the organic layer is distilled under vacuum. 286.0 g (1.78 mol) of 4-chloro-2-butenyl acrylate (59.4% of the theoretical yield) are obtained. 641 g (5.13 mol) of dichlorobutene are recovered.

References

[1] SIMONE MANZINI . Palladium- and Nickel-Catalyzed Synthesis of Sodium Acrylate from Ethylene, CO2, and Phenolate Bases: Optimization of the Catalytic System for a Potential Process[J]. European Journal of Organic Chemistry, 2015, 2015 32: Pages 7122-7130. DOI:10.1002/ejoc.201501113.
[2] KALRA B, GROSS R A. HRP-mediated polymerizations of acrylamide and sodium acrylate[J]. Green Chemistry, 2002, 2: 174-178. DOI:10.1039/B106735B.
[3] https://www.ewg.org/skindeep/ingredients/705976-SODIUM_ACRYLATES_COPOLYMER/

Sodium acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Sodium acrylate Suppliers

BOC Sciences
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View Lastest Price from Sodium acrylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Sodium acrylate 7446-81-3
Price
US $79.00-38.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-28
Hebei Yanxi Chemical Co., Ltd.
Product
Sodium acrylate 7446-81-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100tons
Release date
2023-09-27
Hebei Weibang Biotechnology Co., Ltd
Product
Sodium acrylate 7446-81-3
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-25

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