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Butyl benzoate

Product Name
Butyl benzoate
CAS No.
136-60-7
Chemical Name
Butyl benzoate
Synonyms
TGI;n-Butyl;NSC 8474;FEMA 8752;AI3-00521;HSDB 2089;daicarixbn;BRN 1867073;anthrapoleaz;Butylbenzoat
CBNumber
CB9357923
Molecular Formula
C11H14O2
Formula Weight
178.23
MOL File
136-60-7.mol
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Butyl benzoate Property

Melting point:
-22 °C
Boiling point:
249 °C (lit.)
Density 
1.01 g/mL at 25 °C (lit.)
vapor pressure 
8.5Pa at 20℃
refractive index 
n20/D 1.498(lit.)
Flash point:
223 °F
storage temp. 
room temp
solubility 
0.06g/l
form 
Oily Liquid
color 
Clear yellow
Odor
at 100.00 %. mild amber balsam fruity
Odor Type
balsamic
Water Solubility 
34.1mg/L at 20℃
Merck 
14,1552
BRN 
1867073
LogP
3.3
CAS DataBase Reference
136-60-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, butyl ester(136-60-7)
EPA Substance Registry System
Butyl benzoate (136-60-7)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
DG4925000
TSCA 
Yes
HS Code 
29163100
Hazardous Substances Data
136-60-7(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 5.14 g/kg (Smyth)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
293296
Product name
Butyl benzoate
Purity
99%
Packaging
250g
Price
$28.4
Updated
2024/03/01
Sigma-Aldrich
Product number
293296
Product name
Butyl benzoate
Purity
99%
Packaging
1kg
Price
$29.1
Updated
2024/03/01
TCI Chemical
Product number
B0066
Product name
Butyl Benzoate
Purity
>99.0%(GC)
Packaging
25mL
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
B0066
Product name
Butyl Benzoate
Purity
>99.0%(GC)
Packaging
500mL
Price
$38
Updated
2024/03/01
Alfa Aesar
Product number
A17010
Product name
n-Butyl benzoate, 98%
Packaging
250g
Price
$25.65
Updated
2024/03/01
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Butyl benzoate Chemical Properties,Usage,Production

Chemical Properties

Butyl benzoate is a clear yellowish oily liquid or colorless viscous liquid. Insoluble in water,  poorly soluble in Propylene glycol, soluble in alcohol, 95% ethanol and oil, with sweet and soft with astringent floral and paste fragrance, very light ambergris scent, woody and spicy underlying fragrance. The aroma is weak and lingers long. B.P. 250℃. Sp.Gr. 1.01.

Application

Butyl benzoate has been used as:
preservative in commercial cosmetic lotions
as involatile solvent, for sampling of isocyanates with silica gel solid phase extraction

Uses

Butyl benzoate is used as a solvent for cellulose ether, a dye carrier for textiles, and a perfume ingredient . It occurs naturally as a volatile component of various fruits and vegetables. It has been approved by the FDA as an indirect food additive for use as a component of adhesives.

Production Methods

Butyl benzoate is formed by the direct esterification of n-butyl alcohol with benzoic acid under azeotropic conditions .

Definition

ChEBI: Butyl benzoate is a benzoate ester obtained by condensation of benzoic acid and butanol. It is used as a perfume ingredient and as a solvent for cellulose ether, a dye carrier for textiles. It has a role as an antimicrobial food preservative, a fragrance and a plant metabolite.

Synthesis Reference(s)

Journal of the American Chemical Society, 111, p. 8742, 1989 DOI: 10.1021/ja00205a039
Synthetic Communications, 14, p. 857, 1984 DOI: 10.1080/00397918408075729
The Journal of Organic Chemistry, 39, p. 3318, 1974 DOI: 10.1021/jo00937a003

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by skin contact. Mildly toxic by ingestion. Severe skin irritant and moderate eye irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use Co2, dry chemical, water mist, fog, spray. When heated to decomposition it emits acrid and irritating fumes. See also ESTERS.

Butyl benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Butyl benzoate Suppliers

Radermecker Chimie BVBA
Tel
--
Fax
--
Email
info@radermecker-chimie.be
Country
Belgium
ProdList
131
Advantage
58
Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
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View Lastest Price from Butyl benzoate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Butyl benzoate 136-60-7
Price
US $70.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-06-03
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
2-butylbenzoate 136-60-7
Price
US $70.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-06-03
Hebei Weibang Biotechnology Co., Ltd
Product
Butyl benzoate 136-60-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21

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