ChemicalBook > CAS DataBase List > 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE

6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE

Product Name: 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE
CAS No.: 676371-00-9
Chemical Name: 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE
Synonyms: 6-broMoiMidazo[1;2-a] pyridin-8-aMine;8-Amino-6-bromoimidazo[1,2-a]pyridine;6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE;6-Bromoimidazo[1,2-a]pyridin-8-ylamine;Imidazo[1,2-a]pyridin-8-amine, 6-bromo-;6-Bromo-1H-imidazo[1,2-a]pyridin-8-amine;6-bromo-1H-imidazo [1,2-a]pyridine-8-amine;6-Bromo-1,5-dihydroimidazo[1,2-a]pyridin-8-amine;6-bromoH-imidazo[1,2-a]pyridine-8-carboxylic acid
CBNumber: CB9371624
Molecular Formula: C7H6BrN3
Formula Weight: 212.05
MOL File: 676371-00-9.mol

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6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE Property

Density: 1.87±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 6.31±0.50(Predicted)
Appearance: Light brown to gray Solid
InChI: InChI=1S/C7H6BrN3/c8-5-3-6(9)7-10-1-2-11(7)4-5/h1-4H,9H2
InChIKey: NBHRWSCVWCCKDN-UHFFFAOYSA-N
SMILES: C12=NC=CN1C=C(Br)C=C2N

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Safety

Hazard Codes: Xn
Risk Statements: 22-43
Safety Statements: 36/37
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: B678825
Product name: 6-Bromo-1,5-dihydroimidazo[1,2-A]pyridin-8-amine
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 070223
Product name: 6-Bromo-1H-imidazo[1,2-a]pyridin-8-amine
Purity: 95%
Packaging: 1g
Price: $95
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H30-9-43
Product name: 8-Amino-6-bromoimidazo[1,2-a]pyridine
Packaging: 250mg
Price: $100
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB54436
Product name: 6-Bromoimidazo[1,2-a]pyridin-8-amine
Packaging: 250mg
Price: $130
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB54436
Product name: 6-Bromoimidazo[1,2-a]pyridin-8-amine
Packaging: 500mg
Price: $190
Updated: 2021/12/16

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6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE Chemical Properties,Usage,Production

Synthesis

38875-53-5

2032-35-1

676371-00-9

General procedure for the synthesis of 6-bromoimidazo[1,2-A]pyridin-8-amine from 2,3-diamino-5-bromopyridine and bromoacetaldehyde diethyl acetal: Concentrated hydrochloric acid (0.3 mL) was added to a solution of bromoacetaldehyde diethyl acetal (2.37 mL, 15.4 mmol) in dioxane/water (2:1, 15 mL) at room temperature and the mixture was refluxed for 30 min. After cooling the mixture to room temperature, sodium bicarbonate (2.6 g, 30.8 mmol) was carefully added, followed by dropwise addition of 2,3-diamino-5-bromopyridine (1.5 g, 7.7 mmol) in dioxane/water (2:1, 15 mL). The resulting mixture was stirred under reflux conditions for 14 hours and then cooled to room temperature. The mixture was diluted with 1 M sodium hydroxide solution (30 mL) and extracted with dichloromethane (3 x 35 mL). The organic layers were combined, washed with brine (20 mL), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford 1.5 g (92% yield) of the target product, 6-bromoimidazo[1,2-A]pyridin-8-amine, with mass spectrometry analysis revealing [M+H]+=214.0.

References

[1] Patent: WO2004/26867, 2004, A2. Location in patent: Page 32-33

6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE manufacturers

Career Henan Chemical Co

Product: 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE 676371-00-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KGS
Release date: 2019-12-30

676371-00-9, 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINERelated Search:

IMIDAZO[1,2-A]PYRIDINE-8-CARBOXYLIC ACID [4-(6-BROMO-2-METHYL-8-NITRO-IMIDAZO[1,2-A ]PYRIDIN-3-YL)-THIAZOL-2-YL]-HYDRAZINE Imidazo[1,2-a]pyridine-8-carboxaldehyde (9CI) (1-METHYL-1H-IMIDAZOL-2-YL)-ACETIC ACID 6-Bromo-8-nitroimidazo[1,2-a]pyridine 6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE

6-bromo-1H-imidazo [1,2-a]pyridine-8-amine

8-Amino-6-bromoimidazo[1,2-a]pyridine

6-Bromo-1H-imidazo[1,2-a]pyridin-8-amine

2-a] pyridin-8-aMine

6-broMoiMidazo[1

6-bromo-1,5-dihydroimidazo[1,2-a]pyridine-8-carboxylic acid

6-Bromo-1,5-dihydroimidazo[1,2-a]pyridin-8-amine

6-BROMO-IMIDAZO[1,2-A]PYRIDIN-8-AMINE

6-bromoH-imidazo[1,2-a]pyridine-8-carboxylic acid

6-Bromoimidazo[1,2-a]pyridin-8-ylamine

Imidazo[1,2-a]pyridin-8-amine, 6-bromo-

676371-00-9

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