Ethyl 2-acetylcaprylate

ChemicalBook > CAS DataBase List > Ethyl 2-acetylcaprylate

Ethyl 2-acetylcaprylate

Aroma Uses in Perfume

Product Name: Ethyl 2-acetylcaprylate
CAS No.: 29214-60-6
Chemical Name: Ethyl 2-acetylcaprylate
Synonyms: GELSONE;JESSATE;gelsone (IFF);jasmin acetoacetate;JESSATE 05366, QUEST;ethyl2-acetyloctanoate;ethyl2-acetylcaprylate;Ethyl-2-acetyloctanoat;N-HEXYLETHYLACETOACETATE;ETHYL-3-HEXYLACETOACETATE
CBNumber: CB9386460
Molecular Formula: C12H22O3
Formula Weight: 214.3
MOL File: 29214-60-6.mol

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Ethyl 2-acetylcaprylate Property

Boiling point:: 149 °C / 25mmHg
Density: 0.94
refractive index: 1.4320 to 1.4360
FEMA: 4459 | ETHYL 2-ACETYLOCTANOATE
pka: 11.89±0.59(Predicted)
form: clear liquid
color: A colourless slightly oily liquid.
Odor: at 100.00 %. methyl dihydrojasmonate fruity jasmin waxy herbal
Odor Type: floral
JECFA Number: 1958
LogP: 3.72
CAS DataBase Reference: 29214-60-6(CAS DataBase Reference)
EPA Substance Registry System: Octanoic acid, 2-acetyl-, ethyl ester (29214-60-6)

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Safety

RTECS: RH0352500
HS Code: 2918.30.9000
Toxicity: Both the acute oral LD₅₀ value in rats and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Shelanski, 1973).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: H0129
Product name: Ethyl 2-Hexylacetoacetate
Purity: >95.0%(GC)
Packaging: 25mL
Price: $122
Updated: 2024/03/01

Matrix Scientific

Product number: 080549
Product name: Ethyl 2-acetyloctanoate
Packaging: 500mg
Price: $126
Updated: 2021/12/16

Matrix Scientific

Product number: 080549
Product name: Ethyl 2-acetyloctanoate
Packaging: 1g
Price: $158
Updated: 2021/12/16

AK Scientific

Product number: U821
Product name: Ethyl-2-n-hexylacetoacetate
Packaging: 25mL
Price: $441
Updated: 2021/12/16

Matrix Scientific

Product number: 080549
Product name: Ethyl 2-acetyloctanoate
Packaging: 5g
Price: $483
Updated: 2021/12/16

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Ethyl 2-acetylcaprylate Chemical Properties,Usage,Production

Aroma

Oily-herbaceous, somewhat winey odor with distinctly green-herbal notes, reminiscent of undertones in Jasmin complex.

Uses in Perfume

Ethyl 2-acetylcaprylate has found some use in perfume compositions, mainly as an ingredient in Jasmin bases, occasionally in other floral bases where the green-winey-herbaceous and fresh ethereal note may be desirable.

Physical properties

Colorless slightly oily liquid. Very slightly soluble in water, soluble in akohol, miscible with oils.

Occurrence

Has apparently not been reported to occur in nature.

Preparation

By the alkylation of ethyl acetoacetate with hexyl bromide or by any other suitable method. Uses: In public use since the 1950s. Use in fragrances in the USA amounts to approximately 10001b/yr.

Production Methods

Ethyl 2-acetylcaprylate can be produced by condensation of Ethyl acetate and Hexyl acetate, using Sodium ethoxide catalyst.

Synthesis Reference(s)

Journal of the American Chemical Society, 64, p. 580, 1942 DOI: 10.1021/ja01255a035

Ethyl 2-acetylcaprylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl 2-acetylcaprylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Ethyl 2-acetylcaprylate 29214-60-6
Price: US $45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-12-10

Shanghai Biolang Biotechnology Co., Ltd.

Product: Ethyl 2-acetylcaprylate 29214-60-6
Price: US $99.99-77.77/g
Min. Order: 10g
Purity: 99.99%HPLC.USP42
Supply Ability: 1000kgs
Release date: 2022-02-23

Career Henan Chemical Co

Product: Ethyl 2-acetylcaprylate 29214-60-6
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000KG
Release date: 2019-08-31

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29214-60-6