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Furfuryl mercaptan

Product Name
Furfuryl mercaptan
CAS No.
98-02-2
Chemical Name
Furfuryl mercaptan
Synonyms
2-Furfurylthiol;2-FURANMETHANETHIOL;FURFURYL THIOL;Furfural mercaptan;usafb-58;NSC 41142;USAF B-58;FEMA 2493;Coffee mercaptan;FUFURYL MERCAPTAN
CBNumber
CB9387119
Molecular Formula
C5H6OS
Formula Weight
114.17
MOL File
98-02-2.mol
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Furfuryl mercaptan Property

Melting point:
157.5 °C
Boiling point:
155 °C(lit.)
Density 
1.132 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.531(lit.)
FEMA 
2493 | FURFURYL MERCAPTAN
Flash point:
113 °F
storage temp. 
Flammables area
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
pka
9.59±0.10(Predicted)
form 
Liquid
color 
Clear colorless to pale yellow
Odor
at 0.10 % in dipropylene glycol. sulfury roasted coffee oily fatty burnt smoky
Odor Type
coffee
Water Solubility 
insoluble
Sensitive 
Air Sensitive
JECFA Number
1072
BRN 
383594
Stability:
Air Sensitive
LogP
1.73
CAS DataBase Reference
98-02-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Furanmethanethiol(98-02-2)
EPA Substance Registry System
2-Furanmethanethiol (98-02-2)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
10-36/37-20/21/22
Safety Statements 
23-24/25-16-36-26-7/9
RIDADR 
UN 3336 3/PG 3
WGK Germany 
3
RTECS 
LU2100000
10-13-23
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29321900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W249311
Product name
Furfuryl Mercaptan
Purity
natural, 98%, FG
Packaging
100g
Price
$683
Updated
2024/03/01
Sigma-Aldrich
Product number
W249311
Product name
Furfuryl Mercaptan
Purity
natural, 98%, FG
Packaging
500g
Price
$2800
Updated
2024/03/01
Sigma-Aldrich
Product number
W249300
Product name
Furfuryl Mercaptan
Purity
≥97%, FG
Packaging
1kg
Price
$205
Updated
2024/03/01
Sigma-Aldrich
Product number
W249300
Product name
Furfuryl Mercaptan
Purity
≥97%, FG
Packaging
2.5kg
Price
$479
Updated
2024/03/01
Sigma-Aldrich
Product number
F20408
Product name
2-Furanmethanethiol
Purity
98%
Packaging
25g
Price
$58.4
Updated
2024/03/01
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Furfuryl mercaptan Chemical Properties,Usage,Production

Description

Furfuryl mercaptan has a characteristic unpleasant odor. It is prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfide in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina. Furfuryl mercaptan tends to polymerize when heated in the presence of mineral acids.

Chemical Properties

clear colorless to pale yellow liquid

Chemical Properties

2-Furylmethanethiol is an important constituent of the aroma of roasted coffee. It is a liquid with an unpleasant odor, which becomes like coffee when diluted.

Chemical Properties

Furfuryl mercaptan has a characteristic unpleasant odor.

Occurrence

Reported found in raw and roasted chicken, cooked beef, grilled pork, sesame seed oil, coffee and popcorn; tends to polymerize when heated in the presence of mineral acids

Uses

Furfuryl Mercaptam is a volatile flavor component of corn tortilla chips.

Definition

ChEBI: 2-Furanmethanethiol is a heteroarene.

Preparation

Furfuryl mercaptan is prepared from furfuryl alcohol, thiourea, and hydrogen chloride.The resulting S-furfurylisothiouronium chloride is cleaved with sodium hydroxide to give furfuryl mercaptan.

Aroma threshold values

Detection: 0.005 to 0.01 ppb; aroma characteristics at 0.01%: intense sulfurous onion impact, lacrimator, slightly skunk-like with a dairy nuance and a hint of savory and coffee-like notes.

Taste threshold values

Taste characteristics at 0.2 to 1 ppb: sulfureous, roasted, onion, garlic and coffee.

General Description

Darkens on storage

Safety Profile

Poison by intraperitoneal route. Experimental reproductive effects. Used as a flavoring in chocolate, fruit, nuts, and coffee. When heated to decomposition it emits toxic fumes of SOx. See also MERCAPTANS.

Synthesis

Prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfde in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina.

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View Lastest Price from Furfuryl mercaptan manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Furfuryl mercaptan 98-02-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2023-03-10
Hebei Mojin Biotechnology Co., Ltd
Product
Furfuryl mercaptan 98-02-2
Price
US $100.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-15
Shijiazhuang tongyang Import and Export Co., LTD
Product
Furfuryl mercaptan 98-02-2
Price
US $0.00/g
Min. Order
1g
Purity
99%
Supply Ability
50ton
Release date
2021-08-11

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