ChemicalBook > CAS DataBase List > Cypermethrin

Cypermethrin

Description Uses Toxicology References

Product Name: Cypermethrin
CAS No.: 52315-07-8
Chemical Name: Cypermethrin
Synonyms: beta-Cypermethrin;ZETA-CYPERMETHRIN;CYPERMETRIN;POR;cypermethrine;cyrux;CIS-CYPERMETHRIN;Cypermethrin (technical);FURY;ardap
CBNumber: CB9397556
Molecular Formula: C22H19Cl2NO3
Formula Weight: 416.3
MOL File: 52315-07-8.mol

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Cypermethrin Property

Melting point:: 60-80°C
Boiling point:: 170-195°C
Density: 1.12
vapor pressure: 2.5×10^-7 Pa (20 °C)
refractive index: n20/D 1.57
Flash point:: 100 °C
storage temp.: −20°C
solubility: Chloroform: Slightly Soluble,Methanol: Slightly Soluble
form: Viscous Liquid
Specific Gravity: 1.23 (20℃)
color: Brown
Water Solubility: insoluble
BRN: 8444118
Stability:: Stable. Incompatible with bases, strong oxidizing agents.
EPA Substance Registry System: Beta Cypermethrin (52315-07-8)

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Safety

Hazard Codes: Xn,N,F
Risk Statements: 20/22-37-50/53-43-37/38-22-36-20/21/22-11-52/53
Safety Statements: 24-36/37/39-60-61-2-36-26-16-36/37
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
RTECS: GZ1250000
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29269090
Hazardous Substances Data: 52315-07-8(Hazardous Substances Data)
Toxicity: LD50 in 8 day old rats, adult male rats (mg/kg): 14.9, 250.0 orally (Cantalamessa)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H317May cause an allergic skin reaction

H332Harmful if inhaled

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 36128
Product name: Cypermethrin
Purity: mixture of isomers
Packaging: 100mg
Price: $83.12
Updated: 2025/07/31

Sigma-Aldrich

Product number: 239900
Product name: Cypermethrin-CAS52315-07-8-Calbiochem
Purity: SynthetictypeIIpyrethroid.Potentinhibitorofcalcineurin(proteinphosphata
Packaging: 10mg
Price: $148
Updated: 2025/07/31

Sigma-Aldrich

Product number: 45835
Product name: Cypermethrin solution
Purity: mixture of isomers
Packaging: 2ml
Price: $53.6
Updated: 2022/05/15

Cayman Chemical

Product number: 24117
Product name: Cypermethrin
Purity: ≥95%
Packaging: 50mg
Price: $32
Updated: 2024/03/01

Cayman Chemical

Product number: 24117
Product name: Cypermethrin
Purity: ≥95%
Packaging: 100mg
Price: $61
Updated: 2024/03/01

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Cypermethrin Chemical Properties,Usage,Production

Description

Cypermethrin is a synthetic pyrethroid derivative of natural pyrethrins with a good insecticidal action. In vertebrates and invertebrates, cypermethrin acts mainly on the nervous system. It is both a stomach poison and a contact insecticide. Cypermethrin is used as an insecticide in large-scale commercial agricultural applications as well as in consumer products for domestic purposes. Cypermethrin is used to control pests in soybean, leeks, onions, carrots, turnips, swedes, parsnips, viola spp., spinach, black currant, gooseberries, sunflowers, linseeds, groundnuts, barley, and mushrooms.

Uses

Cypermethrin is a synthetic pyrethroid which is highly used pesticide in agriculture, household and animal husbandry mainly to crack, crevice and spot treatment for control of insects.
Cypermethrin is commonly used to kill household insect pests. In California, it is the fourth most commonly-used insecticide: only chlorpyrifos, pyrethrins, and diazinon have more reported applications.
It is also used in agriculture to control cotton, fruit and vegetable pests. About 90% of cypermethrin is manufactured for cotton crops (WHO, 1998).

Toxicology

Cypermethrin is a moderately toxic material by dermal absorption or ingestion. Symptoms of high dermal exposure include numbness, tingling, itching, burning sensation, loss of bladder control, incoordination, seizures, and possible death. Pyrethroids like cypermethrin may adversely affect the central nervous system. Symptoms of high-dose ingestion include nausea, prolonged vomiting, stomach pains, and diarrhea which progresses to convulsions, unconsciousness, and coma. Cypermethrin is a slight skin or eye irritant, and may cause allergic skin reactions. The oral LD50 for cypermethrin in rats is 250 mg/kg (in corn oil) or 4123 mg/kg (in water). EPA reports an oral LD50 of 187 to 326 mg/kg in male rats and 150 to 500 mg/kg in female rats. The oral LD50 varies from 367 to 2000 mg/kg in female rats, and from 82 to 779 mg/kg in mice, depending on the ratio of cis/trans- isomers present. This wide variation in toxicity may reflect different mixtures of isomers in the materials tested. The dermal LD50 in rats is 1600 mg/kg and in rabbits is greater than 2000 mg/kg.

References

[1] DeeAn Jones, Environmental Fate of Cypermethrin [2] http://www.inchem.org [3] http://npic.orst.edu

Description

Cypermethrin is a type II pyrethroid insecticide. It prolongs opening of sodium channels resulting in membrane depolarization and a conductance block of the insect nervous system, and point mutations in sodium channels induce cypermethrin-resistance in house flies, cockroaches, and mosquitos. Cypermethrin (1-1.5 mg) reduces survival of ticks (H. anatolicum) in vitro in a concentration-dependent manner. Topical administration of cypermethrin reduces the number of ticks on infested cattle. Cypermethrin (5 and 10 ppm) reduces survival of lice (D. ovis) in sheep fleece and prevents re-infestation in contact-challenged sheep for 7 and 19 weeks, respectively. It induces developmental neurotoxicities in zebrafish, increasing mortality and edema and inducing body-axis curvature when used at concentrations ranging from 50 to 200 μg/L. Cypermethrin (15 mg/kg twice weekly for 24 weeks) also induces Parkinson''s disease-like neurodegeneration in rats, decreasing locomotor activity, dopamine production, and the number of tyrosine hydroxylase positive (TH⁺) neurons in the substantia nigra.

Description

Form: Odorless crystals (pure); yellow-brown viscous semisolid at ambient temperatures (technical grade).
Cypermethrin is a pyrethroid insecticide. It was first synthesized in 1974.
Cypermethrin is a synthetic chemical similar to the pyrethrins in pyrethrum extract (which comes from the chrysanthemum plant). Pyrethroids, including cypermethrin were designed to be effective longer than pyrethrins.

Chemical Properties

Viscous Semisolid

Chemical Properties

Thick, yellow-brown liquid or semisolid mass (technical product).

Uses

A potent inhibitor of calcineurin

Uses

Zeta-cypermethrin is used for the control of Lepidoptera, beetles and aphids in cotton, fruit, vegetables, field crops, ornamentals and forestry. It is also used in public health.

Uses

Synthetic pyrethroid insecticide, usually exists as a mixture of cis and trans isomers. Ectoparasiticide

Definition

ChEBI: A carboxylic ester resulting from the formal condensation between 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid and the alcoholic hydroxy group of hydroxy(3-phenoxyphenyl)acetonitrile.

Agricultural Uses

Insecticide: A U.S. EPA restricted Use Pesticide (RUP) used to control a variety of insects on cotton, fruit and vegetable crops. Also used in commercial and residential settings, ships, laboratories and food processing plants.

Trade name

AMMO®; AGROTHRIN®; ARDAP®; ARRIVO®; AVICADE®; BARRICADE®; CCN52®; CNN 52®; CYMBUSH® 2E; CYMBUSH® 3E; CYMPERATOR®; CYNOFF®; CYPERCARE®; CYPERSECT®; CYPERKILL®; CYRUX®; DEMON®; DORSAN-C® (+cypermethrin); DYSECT®; FASTAC®; FLECTRON®; FMC® 30980; FMC 45497; FMC® 45806; FOLCORD®; IMPERATOR®; JF 5705 F®; KAFIL® SUPER; KENCIS®; NAGATA®; NRDC 149®; NRDC 160®; NRDC 166®; NURELLE; POLYTRIN®; PERMASECT C®; PP383®; PREVAIL®; RALO 10®; RIPCORD®; ROCYPER®; RYCOPEL®; SHERPA®; SIPERIN®; STOCKADE®; SUPERSECT®; TOPCLIPPARASOL®; USTAAD®; WL 43467®; WRDC149®

Biological Activity

Type II synthetic pyrethroid insecticide; an extremely potent, cell-permeable inhibitor of calcineurin.

Contact allergens

Pyrethroids, also called pyrethrinoids, are neurotoxic synthetic compounds used as insecticides, with irritant properties. Cypermethrin and fenvalerate have been reported as causing positive allergic patch tests, but only fenvalerate was relevant in an agricultural worker.

Potential Exposure

Pyrethroid insecticide used to control pests on cotton, fruit, and vegetable crops. Also used in commercial and residential settings, ships, laboratories, and food-processing plants. A United States Environmental Protection Agency Restricted Use Pesticide (RUP).

Environmental Fate

Soil. The major soil metabolite was reported to be 3-phenoxybenzoic acid (Hartley and Kidd, 1987).
The typical half-life of cypermethrin in the soil is 30 days, although it can range from two to eight weeks (6, 9). Soil microbes rapidly break down cypermethrin.
Cypermethrin has an extremely low potential to move in the soil. It is unlikely to contaminate groundwater because it binds tightly to soil particles. Cypermethrin is stable in sunlight.
The average half-life of cypermethrin on foliage is 5 days.
United States Environmental Protection Agency. (1989). Cypermethrin Pesticide Fact Sheet. Washington, D.C.
Knisel, W.G. (Ed.). (1993). Groundwater Loading Effects of Agricultural Management Systems. (Version 2.10). [Online]. Tifton, Georgia: United States Department of AgricultureAgricultural Research Service. [Online]. http://www.arsusda.gov/ rsml/ppdb.html

Metabolic pathway

In cabbage plants, (1R)-cis- and (1R)-trans-isomers of cypermethrin undergo epimerization to (1S)-isomers, cis=trans isomerization, ester bond cleavage, hydroxylation of the phenoxy group in the alcohol moiety or the geminal methyl group in the acid moiety, hydration of the cyano group to an amido group with subsequent hydrolysis to the carboxylic acid, and the conjugation of the carboxylic acid, and alcohols with sugars.

storage

+4°C

Shipping

UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Degradation

Zeta-cypermethrin is stable as a solid but it is readily hydrolysed at alkaline pH. Its half-lives at pH values 7 and 9 (25 °C) were 188-635 and 3 days (PM). By analogy with cypermethrin, the major products should be 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylica cid (2, DCVA), 3-phenoxybenzaldehyde (9, 3PBAl) and a-carbamoyl-3- phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate (the amide 3); minor products expected are the a-carboxy analogue of 3 (4) and 3-phenoxybenzoic acid (10,3PBA) (see cypermethrin, Schemes la and lb).
Photodecomposition would be expected to be similar to that of cypermethrin. In aqueous solution the DTSo was reported to be 20-36 days (PM).

Toxicity evaluation

Acute oral LD₅₀ for rats: 250-4,150 mg/kg (pure); 7,180 mg/kg (technical grade)

Incompatibilities

May react violently with strong oxidi- zers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate.

Waste Disposal

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40 CFR 165, follow recommendations for the disposal of pes- ticides and pesticide containers.

References

[1] HALL C A. THE EFFICIENCY OF CYPERMETHRIN (NRDC 149) FOR THE TREATMENT AND ERADICATION OF THE SHEEP LOUSE DAMALINIA OVIS[J]. Australian Veterinary Journal, 1978, 54 10: 471-472. DOI: 10.1111/j.1751-0813.1978.tb00289.x
[2] MUHAMMAD S SAJID. In vitro and in vivo efficacies of ivermectin and cypermethrin against the cattle tick Hyalomma anatolicum anatolicum (Acari: Ixodidae).[J]. Parasitology Research, 2009, 105 4: 1133-1138. DOI: 10.1007/s00436-009-1538-2
[3] ZHAONONG HU . A sodium channel mutation identified in Aedes aegypti selectively reduces cockroach sodium channel sensitivity to type I, but not type II pyrethroids[J]. Insect Biochemistry and Molecular Biology, 2011, 41 1: Pages 9-13. DOI: 10.1016/j.ibmb.2010.09.005
[4] ANAND KUMAR SINGH. A current review of cypermethrin-induced neurotoxicity and nigrostriatal dopaminergic neurodegeneration.[J]. Current Neuropharmacology, 2012, 10 1: 64-71. DOI: 10.2174/157015912799362779
[5] AMY DEMICCO. Developmental neurotoxicity of pyrethroid insecticides in zebrafish embryos.[J]. Toxicological Sciences, 2010, 113 1: 177-186. DOI: 10.1093/toxsci/kfp258

Cypermethrin Preparation Products And Raw materials

Raw materials

Chloral Petroleum crude oil 3-Phenoxybenzaldehyde Benzyltriethylammonium chloride Permethric acid Sodium cyanide 3-Phenoxybenzyl alcohol 3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride Thionyl chloride

Preparation Products

Cypermethrin EC Cypermethrin Fenvalerate+Omethoate,E.C theta-Cypermethrin Sanitary pesticide

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View Lastest Price from Cypermethrin manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Cypermethrin 52315-07-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-25

Hebei Chuanghai Biotechnology Co,.LTD

Product: Cypermethrin 52315-07-8
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-15

Shaanxi Dideu Medichem Co. Ltd

Product: Cypermethrin 52315-07-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 500 tons
Release date: 2020-04-27

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(R,S)-.alpha.-Cyano-3-phenoxybenzyl(1R,S)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

(rs)-alpha-cyano-3-phenoxybenzyl(1rs)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dim

2-dichloroethenyl)-2,2-dimethylcycloptopane-cyano(3-phenoxyphenyl)methyl3-(

3-(2,2-dichloroethenyl)-2,2-dimethyl-cyclopropanecarboxylicacicyano(3-phe

3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylicacid,cyano(3-phenox

3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylicacidcyano(3-phenox

3-(2,2-Dichloro-vinyl)-2,2-dimethyl-cyclopropanecarboxylicacid,cyano(3-phenoxy-phenyl)methylester

agrothrin

ambushc

antiborer3767

ardap

barricade(insecticide)

chinmix

cnn52

Cyclopropanecarboxylicacid,3-(2,2-dichloroethenyl)-2,2-dimethyl-,cyano(3-phenoxyphenyl)methylester

cypermethrin(stereochemistryunspecified)

cypermethrin(zeta)

cypermethrin-25ec

cypermethrine

cypermetryna

cypersect

cypor

cyrux

demon

dimethylcyclopropanecarboxylate

dysect

ectopor

exp5598

fastac

fenom

fmc45497

fmc45806

hilcyperin

imethylcyclopropanecarboxylate

jf5705f

kalifsuper

necarboxylate

nrdc160

nrdc166

nurele

opropanecarboxylate

ru27998

rycopel

sf06646

sherpa

siperin

supercypermethrin

supercypermethrinforte

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