3-Chloro-2-methylpropene

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3-Chloro-2-methylpropene

Description

Product Name: 3-Chloro-2-methylpropene
CAS No.: 563-47-3
Chemical Name: 3-Chloro-2-methylpropene
Synonyms: METHALLYL CHLORIDE;Mac;3-chloro-2-methylprop-1-ene;3-CHLORO-2-METHYL-1-PROPENE;Isobutenyl chloride;beta-methylallylchloride;Methylallyl chloride;BETA-METHALLYL CHLORIDE;1-CHLORO-2-METHYL-2-PROPENE;NCI-C54820
CBNumber: CB9402043
Molecular Formula: C4H7Cl
Formula Weight: 90.55
MOL File: 563-47-3.mol

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3-Chloro-2-methylpropene Property

Melting point:: -80 °C (lit.)
Boiling point:: 71-72 °C (lit.)
Density: 0.925 g/mL at 20 °C (lit.)
vapor density: 3.12 (vs air)
vapor pressure: 102 mm Hg ( 20 °C)
refractive index: n20/D 1.427(lit.)
Flash point:: 9 °F
storage temp.: 2-8°C
solubility: H2O: insoluble
form: Liquid
color: Clear
explosive limit: 2.2-10.4%(V)
Water Solubility: 0.5 g/L (20 ºC)
Merck: 14,2148
BRN: 878160
CAS DataBase Reference: 563-47-3(CAS DataBase Reference)
IARC: 2B (Vol. 63, 115) 2018
NIST Chemistry Reference: 1-Propene, 3-chloro-2-methyl-(563-47-3)
EPA Substance Registry System: 3-Chloro-2-methyl-1-propene (563-47-3)

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Safety

Hazard Codes: F,C,N
Risk Statements: 11-20/22-34-43-51/53
Safety Statements: 9-16-29-36/37/39-45-61-26
RIDADR: UN 2554 3/PG 2
WGK Germany: 2
RTECS: UC8050000
Autoignition Temperature: 899 °F
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29032900
Hazardous Substances Data: 563-47-3(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.05905
Product name: 3-Chloro-2-methyl-1-propene
Purity: for synthesis
Packaging: 100mL
Price: $45.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.05905
Product name: 3-Chloro-2-methyl-1-propene
Purity: for synthesis
Packaging: 500mL
Price: $77.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 108030
Product name: 3-Chloro-2-methyl-1-propene
Purity: technical grade, 90%
Packaging: 100ml
Price: $47
Updated: 2024/03/01

Sigma-Aldrich

Product number: 108030
Product name: 3-Chloro-2-methyl-1-propene
Purity: technical grade, 90%
Packaging: 1l
Price: $72
Updated: 2024/03/01

TCI Chemical

Product number: C0209
Product name: 3-Chloro-2-methyl-1-propene
Purity: >98.0%(GC)
Packaging: 25mL
Price: $21
Updated: 2024/03/01

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3-Chloro-2-methylpropene Chemical Properties,Usage,Production

Description

3-Chloro-2-methylpropene is used as an intermediate to produce carbofuran, herbicides, plastics, pharmaceuticals and other organics. It is also used as an additive in textile and perfumes. It was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate and cationic polymerization of 3-Chloro-2-methylpropene with AICI3 and AIBr3 as initiators. It is also the reactant for the synthesis of cyclobutanone.

Chemical Properties

clear liquid

Uses

In organic synthesis.

Uses

3-Chloro-2-methylpropene has been used as reactant in the synthesis of cyclobutanone. It is used as an intermediate in the production of plastics, pharmaceuticals and other organic chemicals.

Uses

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI₃ and A₃IBr, as initiators.

Definition

ChEBI: 3-Chloro-2-methylpropene is an organochlorine compound.

Biological Functions

MAC is a valuable index for clinical anesthesia, but it is seldom employed without taking other factors into consideration. For example, inhibiting movement in only 50% of patients is not acceptable. Consequently, if an inhalational agent were being used alone—that is, without the administration of other anesthetics or analgesic drugs—the anesthesiologist would employ a multiple of its MAC value to ensure immobility.MAC is frequently multiplied by a factor of 1.3 to achieve nearly 100% clinical efficacy. On the other hand, useful clinical results may be achieved with doses of anesthetics below MAC levels. For example, mild analgesia and amnesia often occur with doses of inhalational agents that are near 0.5 MAC. In this state, it may even be possible to communicate with patients intraoperatively, while their recall is limited.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 824, 1981 DOI: 10.1021/jo00317a041

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0°F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.

Air & Water Reactions

Highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. . Insoluble in water.

Reactivity Profile

3-Chloro-2-methylpropene is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. 3-Chloro-2-methylpropene is incompatible with strong bases. 3-Chloro-2-methylpropene may react with water at elevated temperatures. .

Hazard

Irritant; poison; anesthetic; questionable carcinogen; toxic.

Health Hazard

Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

Carcinogenicity

3-Chloro-2-methylpropene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Toxics Screening Level

The initial risk screening level (IRSL) is 0.03μg/m3 with an annual averaging time.

3-Chloro-2-methylpropene Preparation Products And Raw materials

Raw materials

Isobutylene Oleic acid

Preparation Products

2,3-Dihydro-2,2-dimethyl-7-benzofuranol 3-METHYL-3-BUTEN-1-OL BISPHENOL A DIMETHACRYLATE 2,2,4,6,7-Pentamethyldihydrobenzofuran-5-sulfonyl chloride Carbofuran 2-[(2-METHYL-2-PROPENYL)OXY]-PHENOL Fenbutatin oxide 2,2,4,6,7-Pentamethyldihydrobenzofuran 2-METHYL-2-PROPENE-1-SULFONIC ACID SODIUM SALT Neophyl chloride

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View Lastest Price from 3-Chloro-2-methylpropene manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 3-Chloro-2-methylpropene 563-47-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-20

Hebei Weibang Biotechnology Co., Ltd

Product: 3-Chloro-2-methylpropene 563-47-3
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-13

Hebei Chuanghai Biotechnology Co,.LTD

Product: 3-Chloro-2-methylpropene 563-47-3
Price: US $50.00-20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-19

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