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Fenbutatin oxide

Product Name
Fenbutatin oxide
CAS No.
13356-08-6
Chemical Name
Fenbutatin oxide
Synonyms
bendex;OSADAN;TORQUE;VENDEX;hexakis;osdaran;sd14114;ent27738;Neostanox;Vandex[R]
CBNumber
CB5294952
Molecular Formula
C60H78OSn2
Formula Weight
1052.68
MOL File
13356-08-6.mol
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Fenbutatin oxide Property

Melting point:
142-145°C
Boiling point:
235-240 °C(Press: 0.05 Torr)
Density 
0.42 g/cm3
vapor pressure 
8.5×10-8 Pa (20 °C)
Flash point:
100 °C
storage temp. 
Sealed in dry,Room Temperature
form 
solid
Water Solubility 
0.005 mg l-1 (23 °C)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
13,3991
EPA Substance Registry System
Fenbutatin oxide (13356-08-6)
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Safety

Hazard Codes 
Xn;N,N,Xn,T+
Risk Statements 
21-36/38-50/53-26
Safety Statements 
28-36/37-45-60-61
RIDADR 
UN 2811
WGK Germany 
3
RTECS 
JN8770000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
Hazardous Substances Data
13356-08-6(Hazardous Substances Data)
Toxicity
LD50 in rats, rabbits (mg/kg): >2000 orally; >2000 percutaneously (Zweig)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
34342
Product name
Fenbutatin oxide
Purity
PESTANAL
Packaging
250mg
Price
$31.9
Updated
2021/03/22
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Fenbutatin oxide Chemical Properties,Usage,Production

Chemical Properties

White crystalline solid or powder. Mild odor

Uses

Fenbutatin Oxide is an organotin pesticide. Fenbutatin Oxide is widely used as an aracacide in the control of mites, in particular spider mites.

Uses

Acaricide.

Uses

Fenbutatin oxide is a non-systemic acaricide used to control a wide range of phytophagous mites on deciduous fruits, citrus, vines, selected nut crops, bananas, glasshouse crops and ornamentals.

General Description

White crystalline solid with a mild odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Fenbutatin oxide is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.

Agricultural Uses

Insecticide, Miticide: A U.S. EPA restricted Use Pesticide (RUP). A selective miticide for deciduous pome and stone fruits, citrus fruits, grapes, vegetables, berry fruit, nut crops (selected), ornamentals and greenhouse crops.

Trade name

BENDEX®; NEOSTANOX®; OSDARAN®; SD-14114®; SHELL SD-14114®; TORQUE®; VENDEX®

Potential Exposure

Organotin/phenyltin insecticide and selective miticide for deciduous pome and stone fruits, citrus fruits, grapes, vegetables, berry fruit, nut crops (selected), ornamentals, and greenhouse crops. A United States Environmental Protection Agency Restricted Use Pesticide (RUP)

Environmental Fate

Chemical/Physical. Reacts with moisture forming tris(2-methyl-2-phenylpropyl)tin hydroxide (Worthing and Hance, 1991).

Metabolic pathway

Fenbutatin oxide is quite stable to hydrolytic degradation. Metabolism in soils, plants and animals is minimal. The extensive and irreversible adsorption/binding to cationic and organic matter is the primary dissipation mechanism in the soil environment. Cleavage of the neophenyl-tin linkages is the primary degradation and metabolic pathway (Scheme 1). Transformation of the neophenyl moiety has not been observed. Most of the information reported below was obtained from experiments using 119mSlna belhg conducted by DuPont.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Degradation

Fenbutatin oxide (1) dissociates slowly in water to the corresponding hydroxide [tris(2-methyl-2-phenylpropyl)tin hydroxide 21. The neophenyl moiety of fenbutatin oxide was stable at pH 5, 7, and 9 at 25 °C with minimal degradation occurring after 30 days (Home, 1987a).
The photodegradation of fenbutatin oxide in pH 7 buffer solution was a significant degradation process with a DT50 of approximately 51 days following continuous exposure to simulated sunlight at 25 °C (Home, 1987b). Fenbutatin oxide underwent hydrolysis with a loss of two moles of the 2-methyl-2-phenylprop yl moiety, yielding dlhydroxy-bis(2-methyl- 2-phenylpropyl)stannane (3), accounting for ca. 23% of the initial concentration after 15 days of continuous irradiation. Fenbutatin oxide and its metabolites react reversibly with water to form the analogous oxide/hydroxide compounds (Gray et a1 ., 1995).

Incompatibilities

May form explosive mixture with air. Decomposes above 230C. Contact with water causes slow decomposition. Orgotin oxides can be strongly basic and will react, possibly dangerously, with acidic compounds and mixtures

Waste Disposal

Organic tin compounds may be disposed of in sealed containers in secured sanitary landfill. Chemical Treatability of tin; Concentration Process: Chemical precipitation; Chemical Classification: Metals; Scale of Study: Pilot scale; Type of Wastewater Used: Synthetic wastewater; Results of Study: At 600 ppm, 95.3% reduction with alum. At 500 ppm, 98% reduction with ferric chloride, 92% reduction with lime (three coagulants used: 200 mg of alum at pH = 6.4, 40 ppm of ferric chloride @ pH = 6.2, 41 ppm of lime @ pH = 11.5 Chemical coagulation was followed by dual media filtration). Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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Fenbutatin oxide Suppliers

Jiangxi Huaxing Chemical Co., Ltd
Tel
--
Fax
--
Email
sales@jxhxchem.com;sales@jxhxchem.com
Country
China
ProdList
19
Advantage
50
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202- ; ;
Email
jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com
Country
China
ProdList
43255
Advantage
64
BEST-REAGENT
Tel
400-1166-196;028-84555506- ;028-84555506-
Email
cdhxsj@163.com;1955352637@qq.com;cdhxsj@163.com
Country
China
ProdList
11718
Advantage
57
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
Fax
021 51613951
Email
vivian.zhu@3wpharm.com
Country
China
ProdList
9879
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
028-85911938-
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9750
Advantage
55
ChemStrong Scientific Co.,Ltd
Tel
0755-66853366-
Email
sales@chem-strong.com
Country
China
ProdList
26596
Advantage
56
Hunan HuaTeng Pharmaceutical Co., Ltd.,
Tel
Fax
0731-82251112
Email
sales@huatengsci.com
Country
China
ProdList
6621
Advantage
58
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-87396432-
Fax
0571-87396431
Email
sales@jhechem.com;
Country
China
ProdList
13965
Advantage
53
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View Lastest Price from Fenbutatin oxide manufacturers

qingdao trust agri chemical co.,ltd
Product
Fenbutatin oxide 13356-08-6
Price
US $4.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
20tos
Release date
2021-01-25
Shaanxi Dideu Medichem Co. Ltd
Product
Fenbutatin oxide 13356-08-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
500 tons
Release date
2020-04-27
career henan chemical co
Product
Fenbutatin oxide 13356-08-6
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-20

13356-08-6, Fenbutatin oxideRelated Search:


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  • FUNGICIDE