Chloro(1,5-cyclooctadiene)rhodium(I) dimer

ChemicalBook > CAS DataBase List > Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Reaction

Product Name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
CAS No.: 12092-47-6
Chemical Name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Synonyms: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;Chloro(1,5-cyclooctadiene)rhodiuM(I);Rhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-;1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer;rhodium(1+);[Rh(C8H12)Cl]2;[Rh(1,5-cod)Cl]2;bis(chlororhodium);Chloro(1,5-cycloocta;Di-mu-chlorobis(1,5-cyclooc
CBNumber: CB9406940
Molecular Formula: C16H24Cl2Rh2
Formula Weight: 493.08
MOL File: 12092-47-6.mol

Less

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Property

Melting point:: 243 °C (dec.) (lit.)
Density: 1.94[at 20℃]
vapor pressure: 0Pa at 25℃
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form: Crystals or Crystalline Powder
color: Orange to orange-brown
Water Solubility: 1.56g/L at 20℃
Sensitive: Air Sensitive & Hygroscopic
Exposure limits: ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Stability:: hygroscopic
LogP: 3.16 at 20℃
NIST Chemistry Reference: Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System: Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
F: 3
TSCA: Yes
HS Code: 28439000

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 227951
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Purity: 98%
Packaging: 5g
Price: $3830
Updated: 2024/03/01

TCI Chemical

Product number: B1045
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
Purity: >98.0%(T)
Packaging: 1g
Price: $523
Updated: 2024/03/01

TCI Chemical

Product number: B1045
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
Purity: >98.0%(T)
Packaging: 100mg
Price: $89
Updated: 2024/03/01

Alfa Aesar

Product number: 010466
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Packaging: 250mg
Price: $137
Updated: 2023/06/20

Alfa Aesar

Product number: 010466
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Packaging: 1g
Price: $480
Updated: 2023/06/20

Less

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chemical Properties,Usage,Production

Reaction

Catalyst for coupling 1,3-dienes with activate methylene compounds.
Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
Rhodium source for asymmetric reductive aldol reaction.
Cis-hydroboration of terminal alkynes.
Rhodium source for [5 + 2] additions.
Highly enantioselective for [2+2+2] carbocyclization reactions.
Enantioselective hydroboration of cyclopropenes.

Chemical Properties

orange crystals

Uses

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Uses

Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]₂) can be:

Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.

General Description

This product has been enhanced for catalytic efficiency.

Flammability and Explosibility

Not classified

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Ethyl acetate 1,5-Cyclooctadiene

Preparation Products

Less

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Suppliers

Americas 1 Belgium 3 Brazil 1 China 255 Europe 1 France 2 Germany 9 India 17 Japan 7 South Korea 1 Switzerland 3 United Kingdom 6 United States 35 Global 341

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2409
Advantage: 58

Shaanxi Rock New Materials Co., Ltd.

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com
Country: China
ProdList: 310
Advantage: 62

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: (5)02557626880
Email: cb6@aikonchem.com
Country: China
ProdList: 15494
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 18112977050
Email: cb6@aikonchem.com
Country: China
ProdList: 16684
Advantage: 50

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 67216634
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 278
Advantage: 64

Shandong Carbene New Material Technology Co., Ltd

Tel: 183-6607-2789 13305403391
Email: sdcarbene@163.com
Country: China
ProdList: 327
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 251
Advantage: 64

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11655
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11707
Advantage: 57

skychemical Co.Ltd

Tel: 021-20958197 20965099
Fax: 021-20960837
Email: sales@skychemical.com
Country: China
ProdList: 1183
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 021-51613915-820 13611835272
Fax: 021 51613951
Email: mmwang@sunwaypharm.cn
Country: China
ProdList: 9734
Advantage: 57

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1931
Advantage: 57

Hangzhou Yuhao Chemical Technology Co., Ltd

Tel: 0571-82693216
Fax: +86-571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 9387
Advantage: 52

Shanghai Sphchem Co., Ltd.

Tel: 21-21-56491756 13512199871
Fax: 021-5649-1756
Email: sales@panhongchem.com
Country: China
ProdList: 4000
Advantage: 55

Wuhan Fortuna Chemical Co., Ltd

Tel: 027-59207852 13308628970
Fax: QQ3130921841
Email: buy@fortunachem.com
Country: China
ProdList: 2866
Advantage: 58

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9458
Advantage: 58

NCE Biomedical Co.,Ltd.

Tel: 4000-027-021 |24 +86-13986109188 | +86-15623472865 | +81-08033611988
Fax: +86-27-87599188
Country: China
ProdList: 1493
Advantage: 55

Nanjing Norris-Pharm Technology Co., Ltd

Tel: 13901585132
Fax: +86-25-52131256
Email: 799750417@qq.com
Country: China
ProdList: 8878
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Bsisun HK Imoprt And Export Company Limited

Tel: +86-18068513926
Fax: 0086-519-85153711
Country: China
ProdList: 1277
Advantage: 55

Shanghai Yolne Chemical Co., Ltd.

Tel: 021-62960152
Fax: 021-52212593
Email: 934678158@qq.com
Country: China
ProdList: 9899
Advantage: 55

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7865
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8026
Advantage: 55

Aloespharm Co., Ltd.

Tel: 021-20960837
Fax: 021-20960837
Email: market@aloespharm.com
Country: China
ProdList: 1302
Advantage: 55

Beijin Yangguang Furui Chemical co.,Ltd.

Tel: 010-57495520 13521095525
Email: zhw512@foxmail.com
Country: China
ProdList: 488
Advantage: 55

Nanjing Pharmaluxury Co., Ltd.

Tel: 025-83726959 15851816062
Fax: 025-8666-0986
Email: goodsalejs@163.com
Country: China
ProdList: 128
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41462
Advantage: 60

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 0371-13526885213 15637198702
Fax: 0371-63709726
Email: xpkchem@163.com
Country: China
ProdList: 3978
Advantage: 58

Beijing Guofang Dingsheng Technology Co., Ltd.

Tel: 18610472091 18610472091
Fax: 010-59092859
Email: gfdskj@163.com
Country: China
ProdList: 494
Advantage: 58

Less

View Lastest Price from Chloro(1,5-cyclooctadiene)rhodium(I) dimer manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-13

Hebei Weibang Biotechnology Co., Ltd

Product: Chloro(1.5-cyclooctadiene)rhodium(I) Dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-28

Hebei Weibang Biotechnology Co., Ltd

Product: Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-11-11

12092-47-6, Chloro(1,5-cyclooctadiene)rhodium(I) dimerRelated Search:

Cyproterone acetate Chlorocyclohexane FLUOROLUBE GREASE, GR-362 Polyvinyl chloride Sodium chloride Thionyl chloride DILINOLEIC ACID 1,3-CYCLOOCTADIENE POLY(ETHYLENE) Cyclopentyl chloride Choline chloride Potassium chloride Rhodium Ammonium chloride Calcium chloride 1,5-Cyclooctadiene Tris(triphenylphosphine)rhodiu Dichloro(1,5-cyclooctadien)ruthenium(II) polymer

Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium

Bis(cycloocta-1,5-diene)dichlorodirhodium

Chloro(1,5-cyclooctadiene)rhodium dimer

Dichloro-bis-1,5-cyclooctadiene dirhodium

Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium

di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu

Rhodium 1,5-cyclooctadiene chloride dimer

Rhodium chloro(cycloocta-1,5-diene) dimer

Rhodium, di-mu-chlorobis(1,5-cyclooctadiene)di-

Rhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-

RHODIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER

1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimmer,98%

(1,5-Cyclooctadiene)rhodiumchloridedimer

Chloro(1,5-cycloocta

Chloro-(15-cyclooctadiene)-rhodiuM(I)-diMer ([Rh(COD)CI]2

Chloro(1,5-cyclooctadiene)rhodiuM(I)

Chloro(1,5-cyclooctadiene)rhodiuM (I) diMer ,98% [C% : 38.62%-39.22%]

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, Min. 40.8% Rh 500MG

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,98% [Rh(COD)Cl]2

Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride 1,5-Cyclooctadiene Rhodium(I) Chloride Dimer

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer/ Bis(1,5-cyclooctadienerhodiuM chloride)

RhodiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-

Dichlorobis(1,5-cyclooctadiene)rhodiuM(I) diMer

Chloro(1,5-cyclooctadiene)rhodium(Ⅰ) dimer

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, 41% Rh, Product of UMicore

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,[Rh(COD)Cl]2

Chloro(1,5-cyclooctadiene)rhodiuM(Ⅰ) diMer, 41% Rh, Product of UMicore

1,5-CYCLOOCTADIENE RHODIUM(I) CHLORIDE DIMER

DI-MU-CHLOROBIS[(1,2,5,6-N)-1,5-CYCLOOCTADIENE]DIRHODIUM

DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIRHODIUM

DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)RHODIUM (I)]

CHLORO(1,5-CYCLOOCTADIENE)RHODATE (I) DIMER

CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER

Bis(1,5-cyclooctadienerhodium chloride)

BIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I) DICHLORIDE

BIS(1,5-CYCLOOCTADIENE)-MU,MU'-DICHLORO DIRHODIUM

di-mu-chloro-bis(hapto-1,5-cyclooctadiene)dirhodium(I)

CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DI&

Chloro(1,5-cyclooctadiene)rhodium(I), dimer, 99.9%

DI-CHLORO-BIS-(CYCLOOCTA-1,5-DIENE)DIRHODIUM(I)

Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium

Chloro(1,5-cyclooctadiene)rhodium(I) dimer, min. 40.8% Rh

4-cycloocta-1,5-diene)dirhodium(I)

RhodiuM, di-M-chlorobis[(1,2,5,6-h)-1,5-cyclooctadiene]di-

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer 98%

Chloro(1,5-cyclooctadiene)rhodium(I)dimer,98%

di- mu -chlorobis[(1,2,5,6- eta)-1,5-cyclooctadiene]di-rhodiu chloro(1,5-cyclooctadiene)rhodium(i) dimer

DICHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER

bis((1z,5z)-cycloocta-1,5-diene)

bis(chlororhodium)

[Rh(C8H12)Cl]2

Bis((1,5-cyclooctadiene)(chloro)rhodium)

Chloro(1,5-cyclooctadiene) rhodium(I) dimmer

hloro(1,5-cyclooctadiene)rhodium(I) dimer

[Rh(1,5-cod)Cl]2

Bis(cyclooctadiene)dichlorodirhodium

Di-mu-chlorobis(1,5-cyclooc