ChemicalBook > CAS DataBase List > METHYL ALPHA-CHLOROACRYLATE

METHYL ALPHA-CHLOROACRYLATE

Product Name
METHYL ALPHA-CHLOROACRYLATE
CAS No.
80-63-7
Chemical Name
METHYL ALPHA-CHLOROACRYLATE
Synonyms
METHYL 2-CHLOROACRYLATE;METHYL 2-CHLORO-2-PROPENATE;Methyl 2-chloro-2-propenoate;Acryli;METHYL CHLOROACRYLATE;METHYL-A-CHLOROACRYLATE;chloro-2acrylatedemethyle;Methyl 2-chloropropenoate;METHYL ALPHA-CHLOROACRYLATE;methyl2-chloro-2-propenoate
CBNumber
CB9436196
Molecular Formula
C4H5ClO2
Formula Weight
120.53
MOL File
80-63-7.mol
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METHYL ALPHA-CHLOROACRYLATE Property

Melting point:
-37 °C
Boiling point:
52 °C (50 mmHg)
Density 
1.189
refractive index 
1.442-1.444
Flash point:
33 °C
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
form 
Liquid
color 
Clear colorless to slightly brown
InChI
InChI=1S/C4H5ClO2/c1-3(5)4(6)7-2/h1H2,2H3
InChIKey
AWJZTPWDQYFQPQ-UHFFFAOYSA-N
SMILES
C(OC)(=O)C(Cl)=C
EPA Substance Registry System
Methyl 2-chloroacrylate (80-63-7)
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Safety

Hazard Codes 
T+
Risk Statements 
34-26-24/25-10
Safety Statements 
45-38-36/37/39-26-16
RIDADR 
2927
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
29161995
Hazardous Substances Data
80-63-7(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P320Specific treatment is urgent (see … on this label).

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P361Remove/Take off immediately all contaminated clothing.

P363Wash contaminated clothing before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M296468
Product name
Methyl2-Chloroacrylate
Packaging
5g
Price
$85
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0327969
Product name
METHYL-2-CHLOROACRYLATE
Purity
95.00%
Packaging
5MG
Price
$498.63
Updated
2021/12/16
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METHYL ALPHA-CHLOROACRYLATE Chemical Properties,Usage,Production

Description

Methyl 2-chloroacrylate is a colorless liquid.Molecular weight = 120.54; Boiling point = 52℃ at51 mmHg. Hazard Identification (based on NFPA-704 MRating System): Health 3, Flammability 3, Reactivity 0.Slightly soluble in water; solubility 5 ,1 mg/mL at 22℃.

Chemical Properties

clear colorless to pale yellow liquid

Chemical Properties

Methyl 2-chloroacrylate is a colorless liquid.

Uses

Methyl 2-Chloroacrylate is used as a reagent in various coupling reactions.

General Description

Colorless liquid. Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers (e.g., aircraft glazing).

Air & Water Reactions

Insoluble in water.

Reactivity Profile

METHYL ALPHA-CHLOROACRYLATE is sensitive to prolonged exposure to light, moisture and heat. METHYL ALPHA-CHLOROACRYLATE is incompatible with oxidizers and polymerizers.

Health Hazard

METHYL ALPHA-CHLOROACRYLATE is a skin, eye, and lung irritant. The least trace on skin raises large blisters. It is also a respiratory poison; breathing the vapors can cause pulmonary edema.

Fire Hazard

Flash point data for METHYL ALPHA-CHLOROACRYLATE are not available; however, METHYL ALPHA-CHLOROACRYLATE is probably combustible.

Potential Exposure

Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers e.g., aircraft glazing). Corrosive. Lacrimator.

First aid

If this chemical gets into the eyes, remove any con-tact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medi-cal attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin res-cue breathing (using universal precautions, including resusci-tation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit. Medical observation isrecommended for 24- -48 h after breathing overexposure, aspulmonary edema may be delayed. As first aid for pulmonaryedema, a doctor or authorized paramedic may consideradministering a corticosteroid spray.

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Prior to working with this chemical youshould be trained on its proper handling and storage. Storein tightly closed containers in a cool, well-ventilated areaaway from oxidizers and reducing agents. Where possible,automatically pump liquid from drums or other storage containers to process containers.

Shipping

UN2929 Toxic liquids, flammable, organic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, Technical Name Required.

Incompatibilities

apor may form explosive mixture with air. May hydrolyze upon contact with moisture. Incompatible with nitrates. Methyl 2-chloroacrylate is sensitive to prolonged exposure to light, moisture and heat. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and polymerizers. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). May be a polymerization hazard

METHYL ALPHA-CHLOROACRYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL ALPHA-CHLOROACRYLATE Suppliers

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View Lastest Price from METHYL ALPHA-CHLOROACRYLATE manufacturers

Career Henan Chemical Co
Product
METHYL ALPHA-CHLOROACRYLATE 80-63-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1000KG
Release date
2019-08-07

80-63-7, METHYL ALPHA-CHLOROACRYLATERelated Search:


  • METHYL-A-CHLOROACRYLATE
  • METHYL ALPHA-CHLOROACRYLATE
  • METHYL CHLOROACRYLATE
  • METHYL 2-CHLORO-2-PROPENATE
  • METHYL 2-CHLOROACRYLATE
  • Methyl alpha-chloroacrylate, stabilized with hydroquinone, 98+%
  • Methyl alpha-chloroacrylate, 98+%, stabilized with hydroquinone
  • Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 25GR
  • Methyl 2-Chloroacrylate (stabilized with HQ)
  • Methyl alpha-chloroacrylate, 99%, stabilized
  • α-Chloroacrylic acid methyl ester
  • Methyl alpha-chloroacrylate,99%,stabilized with hydroquinone
  • Acryli
  • Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99%
  • 2-chloro-2-propenoicacid,methylester
  • 2-chloro-2-propenoicacimethylester
  • 2-Chloroacrylic acid, methyl ester
  • 2-chloroacrylicacid,methylester
  • 2-chloro-acrylicacimethylester
  • 2-Chloropropenoic acid, methyl ester
  • 2-Propenoic acid, 2-chloro-, methyl ester
  • Acrylic acid, 2-chloro-, methyl ester
  • chloro-2acrylatedemethyle
  • Methyl 2-chloro-2-propenoate
  • Methyl 2-chloropropenoate
  • methyl2-chloro-2-propenoate
  • Methylester kyseliny 2-chlorakrylove
  • methylesterkyseliny2-chlorakrylove
  • methylesterkyseliny2-chlorakrylove(czech)
  • Methyl 2-Chloroacrylate (stabilized with HQ) &gt
  • Methyl 2-chloroprop-2-enoate
  • alpha-Chloroacrylic Acid Methyl Ester
  • Methyl 2-Chloroacrylate (stabilized with hydroquinone)
  • 80-63-7 METHYL ALPHA-CHLOROACRYLATE
  • methyl ester 2-Chloroacrylicacid
  • 80-63-7
  • monomer