ChemicalBook > CAS DataBase List > 4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE

4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE

Product Name
4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE
CAS No.
343788-69-2
Chemical Name
4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE
Synonyms
4-Amino-1-Boc-4-methylpip...;TERT-BUTYL-4-AMINO-4-METHYLPIP;1-Boc-4-AMino-4-Methylpiperidine;4-Amino-1-Boc-4-methylpiperidine;N-Boc-4-amino-4-methylpiperidine;4-AMINO-4-METHYL-1-BOC-PIPERIDINE;1-BOC-4-AMINO-4-METHYL PIPERADINE;4-AMINO-4-METHYL-N-BOC-PIPERIDINE;4-Amino-1-N-boc-4-methyl-piperidine;butyl 4-aMino-4-Methylpiperidine-1-carboxylate
CBNumber
CB9441604
Molecular Formula
C11H22N2O2
Formula Weight
214.3
MOL File
343788-69-2.mol
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4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE Property

Boiling point:
283℃
Density 
1.017
Flash point:
125℃
storage temp. 
2-8°C(protect from light)
pka
9.77±0.20(Predicted)
Appearance
Colorless to light yellow Solid-Liquid Mixture
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Safety

HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H341Suspected of causing genetic defects

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
A3491
Product name
tert-Butyl 4-Amino-4-methylpiperidine-1-carboxylate
Purity
min. 95.0 %
Packaging
1G
Price
$141
Updated
2025/07/31
TRC
Product number
B415188
Product name
tert-Butyl4-Amino-4-methylpiperidine-1-carboxylate
Packaging
250mg
Price
$90
Updated
2021/12/16
AK Scientific
Product number
W5593
Product name
1-Boc-4-Amino-4-methylpiperidine
Packaging
1g
Price
$122
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA148944
Product name
4-Amino-1-N-butoxycarbonyl-4-methyl-piperidine
Packaging
500mg
Price
$125
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA148944
Product name
4-Amino-1-N-butoxycarbonyl-4-methyl-piperidine
Packaging
250mg
Price
$80
Updated
2021/12/16
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4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE Chemical Properties,Usage,Production

Chemical Properties

White powder

Synthesis

236406-14-7

343788-69-2

General procedure for the synthesis of tert-butyl 4-amino-4-methylpiperidine-1-carboxylate from the compound (CAS: 236406-14-7): a mixture of the compound of formula LE (2.48 g, 7.11 mmol) with 10% palladium carbon (200 mg, Sigma-Aldrich) in methanol (20 mL) was subjected to an atmosphere of hydrogen at about 250 °C The reaction was stirred for 16 hours. Upon completion of the reaction, the Pd/C catalyst was removed by filtration and the filtrate was concentrated under reduced pressure to give 1.37 g of the compound of formula LF as a light-colored viscous oil (90.2% yield). The structure of tert-butyl 4-amino-4-methylpiperidine-1-carboxylate, compound of formula LF, was confirmed using 1H NMR. The 1H NMR data of compound LF were as follows: δH (400 MHz, CDCl3): 3.47-3.49 (4H, m), 1.47-1.61 (4H, m), 1.46 (9H, s), 1.31-1.42 (2H, m), 1.15 (3H, s).

References

[1] Patent: WO2008/89201, 2008, A2. Location in patent: Page/Page column 234-235
[2] Journal of Medicinal Chemistry, 2012, vol. 55, # 12, p. 5901 - 5921
[3] Patent: WO2006/38006, 2006, A2. Location in patent: Page/Page column 26-27
[4] Patent: WO2009/116067, 2009, A2. Location in patent: Page/Page column 139

4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE Suppliers

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View Lastest Price from 4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE manufacturers

Career Henan Chemical Co
Product
4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE 343788-69-2
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200
Release date
2018-12-23

343788-69-2, 4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINERelated Search:

4-Amino-1-Boc-2-methylpiperidine 4-AMINO-1-BOC-PIPERIDINE-4-CARBOXYLIC ACID 4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE 4-(9H-FLUOREN-9-YLMETHOXYCARBONYLAMINO)-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER 4-TERT-BUTOXYCARBONYLAMINO-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER 1-Boc-4-amino-4-piperidineacetic acid TERT-BUTYL 4-[ACETYL(METHYL)AMINO]-4-PHENYLPIPERIDINE-1-CARBAMATE 4-AMINO-1-BOC-PIPERIDINE-4-CARBOXAMIDE TERT-BUTYL 4-AMINO-4-CYANOPIPERIDINE-1-CARBOXYLATE 1-T-BOC-PIPERIDINE-4-SPIRO-5'-HYDANTOIN 4-AMINO-1-N-BUTOXYCARBONYL-4-ETHYL-PIPERIDINE 1-T-BOC-PIPERIDINE-4-SPIRO-5'-[1',3'-BIS-T-BOC]-HYDANTOIN (4-FMOC-AMINO-1-BOC-PIPERIDIN-4-YL)-ACETIC ACID 1-BOC-4-[4-(METHYLSULFONYL)-2-NITROPHENYL]PIPERIDIN-4-AMINE 4-AMINO-PIPERIDINE-1,4-DICARBOXYLIC ACID 1-TERT-BUTYL ESTER 4-METHYL ESTER 4-BENZYLOXY-CARBONYL-AMINO-1-N-BUTOXY-CARBONYL-4-METHYL PIPERIDINE 4-BENZYLOXYCARBONYLAMINO-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER BOC-3-CARBOXYMETHYL-1-PHENYL-1,3,8-TRIAZASPIRO[4 5]DECAN-4-ONE

  • 4-Amino-1-Boc-4-methylpiperidine
  • 4-Amino-1-Boc-4-methylpip...
  • 1-Boc-4-AMino-4-Methylpiperidine
  • 1-Piperidinecarboxylic acid, 4-aMino-4-Methyl-, 1,1-diMethylethyl ester
  • 1-(tert-Butoxycarbonyl)-4-amino-4-methylpiperidine
  • N-Boc-4-amino-4-methylpiperidine
  • 4-AMino-4-Methyl-1-piperidinecarboxylic acid tert-butyl ester
  • butyl 4-aMino-4-Methylpiperidine-1-carboxylate
  • 1-BOC-4-AMINO-4-METHYL PIPERADINE
  • TERT-BUTYL 4-AMINO-4-METHYLPIPERIDINE-1-CARBOXYLATE
  • 4-AMINO-4-METHYL-1-BOC-PIPERIDINE
  • 4-AMINO-1-N-TERT-BUTYLOXYCARBONYL-4-METHYL-PIPERIDINE
  • 4-Amino-1-N-boc-4-methyl-piperidine
  • TERT-BUTYL-4-AMINO-4-METHYLPIP
  • 4-AMINO-4-METHYL-N-BOC-PIPERIDINE
  • 4-AMINO-1-N-BUTOXYCARBONYL-4-METHYL-PIPERIDINE
  • 343788-69-2
  • 43788-69-2