4-BROMOMETHYLBIPHENYL

Product Name: 4-BROMOMETHYLBIPHENYL
CAS No.: 2567-29-5
Chemical Name: 4-BROMOMETHYLBIPHENYL
Synonyms: NSC 86143;Bromoethylbiphenyl;4-Bromoethylbiphenyl;4-BROMOMETHYLBIPHENYL;p-Phenylbenzyl bromide;4-PHENYLBENZYL BROMIDE;Bromoethylbiphenyl 98%;4-Biphenylmethylbromide;4-(BroMoMethyl)diphenyl;4-Bromomethylbiphenyl >
CBNumber: CB9463381
Molecular Formula: C13H11Br
Formula Weight: 247.13
MOL File: 2567-29-5.mol

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4-BROMOMETHYLBIPHENYL Property

Melting point:: 83-86 °C
Boiling point:: 140 °C / 10mmHg
Density: 1.341±0.06 g/cm3(Predicted)
Flash point:: >110℃
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform, Methanol
form: Powder
color: Pale yellow to beige
InChI: InChI=1S/C13H11Br/c14-10-11-6-8-13(9-7-11)12-4-2-1-3-5-12/h1-9H,10H2
InChIKey: HZQLUIZFUXNFHK-UHFFFAOYSA-N
SMILES: C1(C2=CC=CC=C2)=CC=C(CBr)C=C1
CAS DataBase Reference: 2567-29-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-34
Safety Statements: 37/39-26-45-36/37/39
RIDADR: 3261
HazardClass: IRRITANT
HS Code: 29029090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B1847
Product name: 4-Bromomethylbiphenyl
Packaging: 5G
Price: $96
Updated: 2025/07/31

TCI Chemical

Product number: B1847
Product name: 4-Bromomethylbiphenyl
Packaging: 25G
Price: $292
Updated: 2025/07/31

TRC

Product number: B685295
Product name: 4-(Bromomethyl)biphenyl
Packaging: 1g
Price: $50
Updated: 2021/12/16

TRC

Product number: B685295
Product name: 4-(Bromomethyl)biphenyl
Packaging: 5g
Price: $80
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19258
Product name: 4-(Bromomethyl)biphenyl
Packaging: 1g
Price: $37.8
Updated: 2021/12/16

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4-BROMOMETHYLBIPHENYL Chemical Properties,Usage,Production

Chemical Properties

Pale yellow to beige powder

Uses

4-(Bromomethyl)biphenyl is a biphenyl derivative used in the preparation of various pharmaceutical compounds such as protein tyrosine phosphatase 1B inhibitors. 4-(Bromomethyl)biphenyl is useful as as atom transfer radical polymerization initiator.

Synthesis

3597-91-9

2567-29-5

General procedure for the synthesis of 4-bromomethylbiphenyl from 4-biphenylmethanol: Carbon tetrabromide (8.99 g, 27.1 mmol) and triphenylphosphine (7.11 g, 27.1 mmol) were sequentially added to a solution of dichloromethane (100 mL) containing biphenyl-4-ylmethanol (5.00 g, 27.1 mmol) at room temperature with continuous stirring. The reaction mixture was stirred at room temperature for 1.5 h before the solvent was removed by distillation under reduced pressure. The resulting crude product was purified by silica gel column chromatography with an eluent ratio of 1:20 ether/cyclohexane, resulting in 4-bromomethylbiphenyl (6.37 g, 95% yield) as a white solid.1H NMR (400 MHz, CDCl3) data were as follows: δ 7.60 (4H), 7.45 (4H), 7.35 (1H), 4.55 (2H).

References

[1] Organic Letters, 2013, vol. 15, # 9, p. 2210 - 2213
[2] Patent: WO2005/26120, 2005, A1. Location in patent: Page/Page column 21
[3] Patent: WO2004/110974, 2004, A1. Location in patent: Page 22
[4] Organic Letters, 2012, vol. 14, # 21, p. 5428 - 5431,4
[5] Organic Letters, 2018, vol. 20, # 10, p. 3061 - 3064

4-BROMOMETHYLBIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMOMETHYLBIPHENYL Suppliers

Americas 1 Belgium 2 Canada 1 China 160 Europe 1 Germany 3 India 12 Japan 5 Lithuania 2 Spain 1 Switzerland 1 United Kingdom 12 United States 30 Global 231

Henan Violet Technology Co., Ltd

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Shijiazhuang Sdyano Fine Chemical Co., Ltd.

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View Lastest Price from 4-BROMOMETHYLBIPHENYL manufacturers

Career Henan Chemical Co

Product: 4-Bromomethyl biphenyl 2567-29-5
Price: US $9.80/KG
Min. Order: 1g
Purity: ＞98%
Supply Ability: 20 tons
Release date: 2020-02-10

Career Henan Chemical Co

Product: 4-BROMOMETHYLBIPHENYL 2567-29-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-02

2567-29-5, 4-BROMOMETHYLBIPHENYLRelated Search:

4-BROMOMETHYLBIPHENYL 4'-BROMOMETHYLBIPHENYL-2-CARBOXYLIC 5-(4'-Bromomethyl-1,1'-biphenyl-2-yl)-1-triphenylmethyl-1H-tetrazole 4,4'-Bis(bromomethyl)biphenyl METHYL-(4-BROMOMETHYLBIPHENYL-2-YL)CARBOXYLATE,4-BROMOMETHYLBIPHENYL-2-CARBONYLATE,4'-Bromomethylbiphenyl-2-carboxylate 4-Bromomethyl-2-cyanobiphenyl 3-BROMOMETHYLBIPHENYL 4'-(Bromomethyl)biphenyl-2-carboxamide 4-BROMOMETHYLBIPHENYL-2'-CARBOXYLIC ACID 5-[4'-(Bromomethyl)-[1,1'-biphenyl]-2-yl]-2-(triphenylmethyl)-2H-tetrazole 8-BROMOMETHYLFLUORANTHENE 2-CYANO-4-BROMO METHYL BIPHENYL N-Triphenylmethyl-5-(4'-bromomethylbiphenyl)-2-Tetrazole t-Butyl-4'(bromomethyl)-biphenyl-2-carboxylate 4'-BROMOMETHYL-3'-CHLORO-1,1'-BIPHENYL-2-CARBONITRILE 4-bromomethylbiphenyl-2'-carboxylic acid t-butyl ester 4-bromomethylbiphenyl-2-formic acid methyl ester 2-phenyl-(5-(bromomethyl)phenyl)methanamine

4-BROMOMETHYLBIPHENYL

4-PHENYLBENZYL BROMIDE

p-Phenylbenzyl bromide

4-(Bromomethyl)biphenyl,96%

4-Bromoethylbiphenyl

Bromoethylbiphenyl

1,1-Biphenyl, 4-(bromomethyl)-

Bromoethylbiphenyl 98%

4-BROMOMETHYLBIPHENYL 98+%

4-Biphenylmethylbromide

4-Biphenylylmethyl bromide

4-(BroMoMethyl)biphenyl, 96% 25GR

4-(BroMoMethyl)biphenyl, 96% 5GR

4-(BroMoMethyl)-1-phenylbenzene

4-(BroMoMethyl)-4-biphenyl

4-(BroMoMethyl)diphenyl

NSC 86143

1-(bromomethyl)-4-phenylbenzene

4-Bromomethylbiphenyl &gt

4-(Bromomethyl)-1,1'-biphenyl

2567-29-5

2569-29-5

Benzene series