METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
Uses Synthesis- Product Name
- METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
- CAS No.
- 33689-29-1
- Chemical Name
- METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
- Synonyms
- Methyl 1-Hydroxycyclopropane-1-carboxylate;Methyl 1-Hydroxycyclopropanecarboxylate;METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90;1-Hydroxycyclopropanecarboxylic Acid Methyl Ester;Methyl 1-hydroxy-1-cyclopropane carboxylate, 90% 5GR;Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester;1-hydroxy-Cyclopropanecarboxylic acid methyl ester (8CI 9CI ACI);Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester (8CI, 9CI, ACI)
- CBNumber
- CB9502042
- Molecular Formula
- C5H8O3
- Formula Weight
- 116.12
- MOL File
- 33689-29-1.mol
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Property
- Boiling point:
- 70°C/13mmHg
- Density
- 1.346±0.06 g/cm3(Predicted)
- Flash point:
- 17℃
- storage temp.
- Sealed in dry,2-8°C
- solubility
- Dichloromethane, Methanol
- form
- Liquid
- pka
- 13.14±0.20(Predicted)
- color
- Clear yellow
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- H825150
- Product name
- 1-HydroxycyclopropanecarboxylicAcidMethylEster
- Packaging
- 1g
- Price
- $395
- Updated
- 2021/12/16
- Product number
- 114023
- Product name
- Methyl 1-hydroxy-1-cyclopropanecarboxylate
- Purity
- 95%
- Packaging
- 1g
- Price
- $449
- Updated
- 2021/12/16
- Product number
- CS-W005559
- Product name
- Methyl1-hydroxycyclopropanecarboxylate
- Purity
- ≥97.0%
- Packaging
- 5g
- Price
- $150
- Updated
- 2021/12/16
- Product number
- 2229-1-63
- Product name
- Methyl 1-hydroxycyclopropane-1-carboxylate
- Purity
- 97.0%
- Packaging
- 1g
- Price
- $190
- Updated
- 2021/12/16
- Product number
- JK623387
- Product name
- Methyl1-hydroxy-1-cyclopropanecarboxylate
- Purity
- 90%
- Packaging
- 1g
- Price
- $192
- Updated
- 2021/12/16
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Chemical Properties,Usage,Production
Uses
1-Hydroxycyclopropanecarboxylic Acid Methyl Ester is a compound useful in organic synthesis.
Synthesis
Methyl 1-aminocyclopropylcarboxylate (3.41g, 29.6mmol, 1.0eq) was dissolved in 40ml of sulfuric acid aqueous solution A (prepared by adding 1.62mL of 98% concentrated sulfuric acid to water, the molar equivalent of sulfuric acid was 1.0eq), ice The bath was cooled to 0-5° C., 10 ml of sodium nitrite (2.25 g, 32.6 mmol, 1.1 eq) aqueous solution was added to the reaction solution, and the mixture was stirred at room temperature for 1 hour. Then, the above reaction was added dropwise to 100 ml of refluxing sulfuric acid aqueous solution B (prepared by adding 1.62 mL of 98% concentrated sulfuric acid to water, and the molar equivalent of sulfuric acid was 1.0 eq). After the dropwise addition was completed, the heating was stopped, cooled to room temperature, and the reaction was detected by TLC, extracted three times with ethyl acetate (3*100 mL), the organic phases were combined, dried with anhydrous magnesium sulfate, filtered, and the organic phase was concentrated to obtain 1-hydroxyl -Methyl 1-cyclopropanecarboxylate (2.57 g, 22.1 mmol), colorless oily liquid, yield 74.8%.
Chemical Properties
Clear yellow liquid
Uses
1-Hydroxycyclopropanecarboxylic Acid Methyl Ester (cas# 33689-29-1) is a compound useful in organic synthesis.
Synthesis Reference(s)
Tetrahedron Letters, 25, p. 1269, 1984 DOI: 10.1016/S0040-4039(01)80131-3
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 manufacturers
- Product
- methyl 1-hydroxycyclopropane-1-carboxylate 33689-29-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-26
- Product
- METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE 33689-29-1
- Price
- US $6.60/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg -1000kg
- Release date
- 2020-01-02