Uses Synthesis
ChemicalBook > CAS DataBase List > METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90

METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90

Uses Synthesis
Product Name
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
CAS No.
33689-29-1
Chemical Name
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
Synonyms
Methyl 1-Hydroxycyclopropane-1-carboxylate;Methyl 1-Hydroxycyclopropanecarboxylate;METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90;1-Hydroxycyclopropanecarboxylic Acid Methyl Ester;Methyl 1-hydroxy-1-cyclopropane carboxylate, 90% 5GR;Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester;1-hydroxy-Cyclopropanecarboxylic acid methyl ester (8CI 9CI ACI);Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester (8CI, 9CI, ACI)
CBNumber
CB9502042
Molecular Formula
C5H8O3
Formula Weight
116.12
MOL File
33689-29-1.mol
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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Property

Boiling point:
70°C/13mmHg
Density 
1.346±0.06 g/cm3(Predicted)
Flash point:
17℃
storage temp. 
Sealed in dry,2-8°C
solubility 
Dichloromethane, Methanol
form 
Liquid
pka
13.14±0.20(Predicted)
color 
Clear yellow
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Safety

Risk Statements 
11
Safety Statements 
16
RIDADR 
3277
HS Code 
29162090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
H825150
Product name
1-HydroxycyclopropanecarboxylicAcidMethylEster
Packaging
1g
Price
$395
Updated
2021/12/16
Matrix Scientific
Product number
114023
Product name
Methyl 1-hydroxy-1-cyclopropanecarboxylate
Purity
95%
Packaging
1g
Price
$449
Updated
2021/12/16
ChemScene
Product number
CS-W005559
Product name
Methyl1-hydroxycyclopropanecarboxylate
Purity
≥97.0%
Packaging
5g
Price
$150
Updated
2021/12/16
SynQuest Laboratories
Product number
2229-1-63
Product name
Methyl 1-hydroxycyclopropane-1-carboxylate
Purity
97.0%
Packaging
1g
Price
$190
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK623387
Product name
Methyl1-hydroxy-1-cyclopropanecarboxylate
Purity
90%
Packaging
1g
Price
$192
Updated
2021/12/16
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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Chemical Properties,Usage,Production

Uses

1-Hydroxycyclopropanecarboxylic Acid Methyl Ester is a compound useful in organic synthesis.

Synthesis

Methyl 1-aminocyclopropylcarboxylate (3.41g, 29.6mmol, 1.0eq) was dissolved in 40ml of sulfuric acid aqueous solution A (prepared by adding 1.62mL of 98% concentrated sulfuric acid to water, the molar equivalent of sulfuric acid was 1.0eq), ice The bath was cooled to 0-5° C., 10 ml of sodium nitrite (2.25 g, 32.6 mmol, 1.1 eq) aqueous solution was added to the reaction solution, and the mixture was stirred at room temperature for 1 hour. Then, the above reaction was added dropwise to 100 ml of refluxing sulfuric acid aqueous solution B (prepared by adding 1.62 mL of 98% concentrated sulfuric acid to water, and the molar equivalent of sulfuric acid was 1.0 eq). After the dropwise addition was completed, the heating was stopped, cooled to room temperature, and the reaction was detected by TLC, extracted three times with ethyl acetate (3*100 mL), the organic phases were combined, dried with anhydrous magnesium sulfate, filtered, and the organic phase was concentrated to obtain 1-hydroxyl -Methyl 1-cyclopropanecarboxylate (2.57 g, 22.1 mmol), colorless oily liquid, yield 74.8%.

Chemical Properties

Clear yellow liquid

Uses

1-Hydroxycyclopropanecarboxylic Acid Methyl Ester (cas# 33689-29-1) is a compound useful in organic synthesis.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 1269, 1984 DOI: 10.1016/S0040-4039(01)80131-3

METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
methyl 1-hydroxycyclopropane-1-carboxylate 33689-29-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-26
Career Henan Chemical Co
Product
METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE 33689-29-1
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

33689-29-1, METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90Related Search:

4'-Hydroxyacetophenone Methyl 1,2,4-triazole-3-carboxylate Cyclopropane METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 ETHYL 1-HYDROXYCYCLOPROPANECARBOXYLATE, 90 1-Hydroxy-1-cyclopropanecarboxylic acid CPCCOET

  • METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
  • 1-Hydroxycyclopropanecarboxylic Acid Methyl Ester
  • Methyl 1-hydroxy-1-cyclopropane carboxylate, 90% 5GR
  • Methyl 1-Hydroxycyclopropane-1-carboxylate
  • Methyl 1-Hydroxycyclopropanecarboxylate
  • Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester
  • Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester (8CI, 9CI, ACI)
  • 1-hydroxy-Cyclopropanecarboxylic acid methyl ester (8CI 9CI ACI)
  • 33689-29-1
  • Miscellaneous Reagents